Preparation method of anti-static biodegradable packaging film
A biodegradable, packaging film technology, applied in biological packaging, sustainable packaging industry, sustainable manufacturing/processing, etc., can solve the problems of reduced mechanical properties of films, affecting the appearance of films, and frictional electrification of plastic films, and achieve excellent mechanical properties. and water resistance, good biodegradability, simplified formulation effect
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Embodiment 1
[0027] (1) Add water to the high-amylose cornstarch to make starch milk with a mass concentration of 12%, and then heat it to 90-95° C. and stir for gelatinization for 30 minutes to obtain a gelatinized liquid;
[0028] (2) Add potassium carbonate to the gelatinized liquid, stir to dissolve and start to drop 3-bromopropane-1,1,1-triethyl tricarboxylate, high amylose, 3-bromopropane-1,1,1- The molar ratio of triethyl tricarboxylate and potassium carbonate is 3:1:1.02, and the molar weight of high amylose is calculated by the molar weight of hydroxymethyl groups contained in it. During the dropping process, it is heated to 75-80°C and stirred for reaction. After the addition is complete, continue the heat preservation reaction until the reaction of triethyl 3-bromopropane-1,1,1-tricarboxylate is complete, filter with suction, wash with water, dry, and pulverize to obtain modified starch;
[0029] (3) Add polyvinyl alcohol and calcium stearate to the modified starch, stir evenly,...
Embodiment 2
[0033] (1) Add water to the high-amylose cornstarch to make starch milk with a mass concentration of 10%, then heat it to 90-95° C. and stir for gelatinization for 30 minutes to obtain a gelatinized liquid;
[0034] (2) Add potassium carbonate to the gelatinized liquid, stir to dissolve and start to drop 3-bromopropane-1,1,1-triethyl tricarboxylate, high amylose, 3-bromopropane-1,1,1- The molar ratio of triethyl tricarboxylate and potassium carbonate is 4:1:1, and the molar weight of high amylose is based on the molar weight of hydroxymethyl groups contained in it. During the dropping process, it is heated to 75-80°C and stirred for reaction. After the addition is complete, continue the heat preservation reaction until the reaction of triethyl 3-bromopropane-1,1,1-tricarboxylate is complete, filter with suction, wash with water, dry, and pulverize to obtain modified starch;
[0035] (3) Add polyvinyl alcohol and ethylene bisoleic acid amide to the modified starch, stir evenly,...
Embodiment 3
[0039] (1) Add water to the high-amylose cornstarch to make starch milk with a mass concentration of 15%, then heat it to 90-95° C. and stir for gelatinization for 30 minutes to obtain a gelatinized liquid;
[0040] (2) Add potassium carbonate to the gelatinized liquid, stir to dissolve and start to drop 3-bromopropane-1,1,1-triethyl tricarboxylate, high amylose, 3-bromopropane-1,1,1- The molar ratio of triethyl tricarboxylate and potassium carbonate is 5:1:1, and the molar weight of high amylose is based on the molar weight of hydroxymethyl groups contained in it. During the dropping process, it is heated to 75-80°C and stirred for reaction. After the addition is complete, continue the heat preservation reaction until the reaction of triethyl 3-bromopropane-1,1,1-tricarboxylate is complete, filter with suction, wash with water, dry, and pulverize to obtain modified starch;
[0041] (3) Add polyvinyl alcohol and calcium stearate to the modified starch, stir evenly, the weight ...
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