Nucleic acid aptamer and application thereof in specific recognition of p-hydroxybenzyl hydrogen sulfite
A technology of p-hydroxybenzyl bisulfite and nucleic acid aptamer, which is applied in the field of biomedicine, can solve the problems of being unable to be widely used, and achieve the effect of high specificity and high affinity
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Embodiment 1
[0024] Example 1: Screening and secondary structure analysis of p-hydroxybenzyl bisulfite nucleic acid aptamers
[0025] 1. Using the magnetic bead-SELEX method to screen, immobilize the target p-hydroxybenzyl bisulfite on magnetic beads (DynabeadsMyOne Streptavidin C1 magnetic beads), and then incubate the target-magnetic bead complex with the oligonucleotide library, which can bind to the target The bound oligonucleotide will bind to the target-magnetic bead complex to form an oligonucleotide-target-magnetic bead complex, and finally the oligonucleotide-target-magnetic bead complex can be combined by the magnetic attraction of the magnetic frame The ssDNA enriched library with affinity and specificity for p-hydroxybenzyl bisulfite was obtained after multiple rounds of screening;
[0026] Each round adopts the method of SA magnetic bead immobilized library screening. After the library is enriched, the affinity of the secondary library is first verified by Q-PCR. If the affini...
Embodiment 2
[0039] Example 2: Using graphene oxide (GO) fluorescence method to detect the specificity of p-hydroxybenzyl bisulfite nucleic acid aptamer SEQ16
[0040] In this experiment, compounds p-hydroxybenzyl alcohol, p-hydroxybenzenesulfonic acid, gastrodin, p-hydroxybenzaldehyde, and barisenoside A, which are similar in structure to p-hydroxybenzyl bisulfite, were selected to verify the nucleic acid aptamer SEQ16 p-hydroxybenzylsulfite Hydrogen Specificity.
[0041] Add an appropriate amount of 100 μmol / L FAM-modified nucleic acid aptamer SEQ16 (synthesized by Shanghai Sangon Bioengineering Co., Ltd.) to 200 μL binding buffer (Tris-HCl buffer with pH=7.2) to make a final concentration of 200 nmol / L The nucleic acid aptamer solution was pre-denatured in a boiling water bath at 95°C for 10 minutes, then ice-bathed for 10 minutes, and placed at room temperature for 10 minutes; then 200 μL of 100 μg / mL graphene oxide aqueous solution was added and incubated at room temperature for 2 hou...
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