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Method for co-processing chromium-containing hazardous wastes and zinc-containing waste residues

A hazardous waste and co-processing technology, applied to the removal of solid waste, etc., can solve the problems of easy leaching of heavy metals and impact on environmental safety, and achieve the effects of improving reactivity, reducing mobility, and reducing the risk of environmental release

Active Publication Date: 2022-02-22
ZHEJIANG GONGSHANG UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to solve the short board that heavy metals are easy to leach after solidification of chromium-containing hazardous waste and zinc-containing waste slag, which affects environmental safety, and to provide a method for synergistic treatment of chromium-containing hazardous waste and zinc-containing waste slag

Method used

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  • Method for co-processing chromium-containing hazardous wastes and zinc-containing waste residues
  • Method for co-processing chromium-containing hazardous wastes and zinc-containing waste residues

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] In this example, the chromium-containing hazardous waste and the zinc-containing waste slag are co-processed, such as figure 1 As shown, the specific method is as follows:

[0033] The chromium-containing hazardous waste, zinc-containing waste residue and kyanite tailings are dried to reduce the moisture content of the chromium-containing hazardous waste, zinc-containing waste residue and kyanite tailings from 24%, 18% and 12% to below 3% respectively.

[0034] Mix the dried chromium hazardous waste, zinc-containing waste slag and kyanite tailings at a dry basis mass percentage of 12%: 20%: 68%, and add the mixed material to a vertical planetary ball mill for grinding for 6 hours at a speed of 650 rpm. After grinding, the obtained grinding product was put into a high-temperature furnace for high-temperature melting and solidification. The melting temperature was 1300° C. and the melting time was 9 minutes. After cooling, the solidified body A is obtained 1 .

[0035...

Embodiment 2

[0041] In this embodiment, the chromium-containing hazardous waste and the zinc-containing waste residue are co-processed, such as figure 1 As shown, the specific method is as follows:

[0042] The chromium-containing hazardous waste, zinc-containing waste residue and kyanite tailings are dried to reduce the moisture content of the chromium-containing hazardous waste, zinc-containing waste residue and kyanite tailings from 24%, 18% and 12% to below 3% respectively.

[0043] The dried chromium-containing hazardous waste, zinc-containing waste slag and kyanite tailings are mixed uniformly at a dry basis mass percentage of 8%: 20%: 72%, and the mixed material is added to a vertical planetary ball mill for grinding for 5.5 hours. 620 rpm. After grinding, the obtained grinding product was put into a high-temperature furnace for high-temperature melting and solidification. The melting temperature was 1250° C. and the melting time was 15 minutes. Solidified body B was obtained afte...

Embodiment 3

[0046] In this embodiment, the chromium-containing hazardous waste and the zinc-containing waste residue are co-processed, such as figure 1 As shown, the specific method is as follows:

[0047] The chromium-containing hazardous waste, zinc-containing waste residue and kyanite tailings are dried to reduce the moisture content of the chromium-containing hazardous waste, zinc-containing waste residue and kyanite tailings from 24%, 18% and 12% to below 3% respectively.

[0048] Mix the dried chromium hazardous waste, zinc-containing waste slag and kyanite tailings at a dry basis mass percentage of 18%: 12%: 70%, and add the mixed material to a vertical planetary ball mill for grinding for 6.5 hours at a speed of 650 rpm. After grinding, the obtained grinding product was put into a high-temperature furnace for high-temperature melting and solidification. The melting temperature was 1300° C. and the melting time was 10 minutes. Solidified body C was obtained after cooling.

[004...

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Abstract

The invention discloses a method for co-processing chromium-containing hazardous wastes and zinc-containing waste residues, and belongs to the field of harmless treatment of heavy metal wastes. The method comprises the following steps that by taking dried chromium-containing hazardous wastes, zinc-containing waste residues and kyanite tailings as raw materials, a spinel solid solution and a precursor are formed from a chromium component, a zinc component, an aluminum component, an iron component and a silicon component in the chromium-containing hazardous wastes, the zinc-containing waste residues and the kyanite tailings through a mechanochemical effect, the structural fixation and activation of part of heavy metal ions such as chromium and zinc are realized, then secondary solidification is performed through high-temperature rapid melting, the efficient and stable solidification of the chromium-containing hazardous wastes and the zinc-containing waste residues is further realized, and meanwhile, the kyanite tailings are utilized and disposed, so that the effect of harmless and resourceful co-treatment of various solid wastes is achieved.

Description

technical field [0001] The invention relates to the field of harmless treatment and disposal of heavy metal waste, in particular to a method for co-processing hazardous chromium-containing waste and zinc-containing waste residue. Background technique [0002] Chromium-containing hazardous waste and zinc-containing waste slag are typical hazardous wastes "involving heavy metals and non-ferrous metals". The heavy metals can migrate to soil, organisms or sediments with rainwater, surface water and groundwater, and then enter the food chain, causing serious environmental pollution, endangering human health and safety. How to safely dispose of chromium-containing hazardous waste and zinc-containing waste residue has always been a technical problem in the field of environmental engineering. [0003] In the prior art, the invention patent with application number CN201410855721.0 discloses a method and device for recovering zinc and chromium in heavy metal sludge. In this patent, h...

Claims

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Application Information

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IPC IPC(8): B09B3/00B09B3/30B09B3/35B09B3/38B09B3/70
CPCB09B3/00Y02P10/20
Inventor 金俊勋殷文静马凯徐颖杜晶黄涛宋东平
Owner ZHEJIANG GONGSHANG UNIVERSITY