436 results about "Mechanochemistry" patented technology

Disclosed is an edge-functionalized graphitic material manufactured by using a mechanochemical process. The edge-functionalized graphitic material is manufactured by pulverizing graphite in the presence of a variety of atmospheric agents in the form of gas phase, liquid phase, or solid phase. The edge-functionalized graphitic material, which is a precursor applicable into various fields, is expected to replace the prior art oxidized graphite.

The invention discloses a fast organic pollutant removing method based on vulcanized zero-valence-iron-activated hydrogen peroxide. The method has the advantages that the surface of Fe0 is coated with crystal type FeS2 with excellent conductivity through a mechanical chemical process so as to replace a possibly-formed passive film (iron oxide), the generation and regeneration of Fe2+ in a system are accelerated, a pH environment needed by a Fenton system is provided by using FeS2 and H2O2 and reaction of the FeS2 and H2O2 with Fe3+, and accordingly target pollutants can be removed efficiently and fast; the materials needed by the method are wide in source and cheap, and the method is high in pollutant degrading drive force, fast, and high in reagent utilization efficiency; the method is high in universality, applicable to the treatment of various industrial wastewater and other polluted water and most organic pollutants in soil and underground environments, evident in economic, environment and social benefits and worthy of large-scale popularization and has no strict requirements on the initial pH condition of a target medium.

This invention uses nanoparticle mixtures to broaden the range of economic materials, improve performance across this broader range, and thereby lower costs of hydride and other storage systems. Nanoparticles can have dramatically different mechanical, chemical, electrical, thermodynamic, and/or other properties than their parent (precursor) materials. Because of this fundamental characteristic, nanophase materials can greatly improve the range of possibilities of materials selection, performance, cost, and practicality for hydride storage systems, advancing the early commerciality of such systems for hydrogen fuel cells or other applications. Among such hydrogen storage improvements are cheaper and better-performing metals, alloys, and/or compounds; lower weight; and reduced storage volumes.

A novel top-down procedure for synthesis of stable passivated nanoparticles uses a one-step mechanochemical process to form and passivate the nanoparticles. High-energy ball milling (HEBM) can advantageously be used to mechanically reduce the size of material to nanoparticles. When the reduction of size occurs in a reactive medium, the passivation of the nanoparticles occurs as the nanoparticles are formed. This results in stable passivated silicon nanoparticles. This procedure can be used, for example in the synthesis of stable alkyl- or alkenyl-passivated silicon and germanium nanoparticles. The covalent bonds between the silicon or germanium and the carbon in the reactive medium create very stable nanoparticles.

The preparation process of artificial PVC leather and synthetic PU leather to release negative ion effectively includes the following steps: treating tourmaline mineral through sorting, water selecting, eliminating impurity, airflow grinding, acid or alkali treating; mechanical and chemical compounding tourmaline powder with RE salt or oxide and nanometer semiconductor material to obtain nanometer composite tourmaline material; adding the nanometer composite tourmaline material in 1.5-20 wt% into the material for artificial PVC leather and synthetic PU leather; and conventional artificial leather preparing process. The present invention added the negative ion releasing function to artificial PVC leather and synthetic PU leather, and negative ion with powerful oxidizing property is utilized to destroy bacteria's activity and to deodorize through reaction with various bad smell, such as ammonia, benzene, formaldehyde, etc.

The invention discloses a method for preparing detonation nanometer diamond dispersion. The method comprises the following steps: preliminarily dispersing commercially available nanometer diamond in deionized water, and performing mechano-chemical deagglomeration and chemical modification; purifying the nanometer diamond subjected to deagglomeration to remove impurities, cleaning and grading, and preparing water-based dispersion; selectively adding a corresponding concentrating agent for concentration according to the polarity or non-polarity of a subsequent selected dispersing solvent, and removing the supernatant; adding a polar solvent into the prepared concentrate, or adding a surface group conversion agent and a non-polar solvent, removing an aqueous phase after the nanometer diamond is converted to enter the non-polar solvent, adding a dispersion stabilizer, a pH value regulator and the like, performing ultrasonic treatment or stirring and dispersing, and preparing the polar or non-polar medium detonation nanometer diamond dispersion which can be stably stored. The process is simple, the prepared product is high in purity, high in concentration and high in yield and can be prepared into paste and aerosol, drying is not needed in the process, and the dispersion can be stably dispersed in different liquid media.

The invention provides a method for synthesizing an efficient photocatalytic covalent organic framework material by using a mechanochemical method. The method is characterized by comprising the following steps: using the mechanochemical method, using melamine and 2,4,6-triformyl resorcinol as raw materials, distributing according to a certain mole ratio, using a planetary ball-milling device, acquiring sticky slurry at a room temperature through wet-process ball-milling, after washing and drying the sticky slurry, to obtain the stable covalent organic framework material. The method is simple in process, only less solvent is used in a grinding reaction process, the environment is protected, and production cost is reduced. Reaction time is only 1/36 of that of a hydrothermal method, a reaction condition is mild, and the method can be applied for large-scale production. In addition, the prepared stripping sheet-like structure powder material is wide in visible light absorption range, highin separation efficiency of a photon-generated carrier, capable of rapidly decomposing toxic organic substances in water, has excellent performance of treating organic wastewater, can be repeatedly used, and has good industrial application prospect.

The invention discloses a method for extracting functional ingredients from lucid ganoderma sporocarp. As a better implementation scheme, the method for extracting functional ingredients can comprises the following steps: lucid ganoderma sporocarp is firstly ground and then subjected to steam explosion treatment under the condition that the steam pressure is 0.6-2.4 Mpa for 60-210 seconds; after the steam explosion treatment, the lucid ganoderma sporocarp is extracted with water or an organic agent, filtered, concentrated and dried; and finally the active ingredients such as ganoderma lucidum polysaccharides and lucid ganoderma triterpenoid substances can be obtained. According to the method, a short-term steam explosion technology is adopted to pretreat the lucid ganoderma sporocarp, the thermal mechanochemistry action of steam explosion is utilized to break the cell wall of the lucid ganoderma sporocarp, the structure of the solid lucid ganoderma sporocarp is broken, so that the active ingredients of the lucid ganoderma sporocarp can be favorably dissolved out, the extraction time is shortened, the production cost is lowered, and the extraction rate of the functional ingredients is obviously improved compared with that of the conventional extraction method.

A layer stripping method for preparing nano-montmorillonite includes such steps as organic intercalating to Na-based montmorillonite by mechano-chemical method for modifying it, water washing, drying, and mechanical stripping by grinding.

The invention provides a forming method for nanometer beta' phase element and nanometer oxide composite reinforced Fe-based ODS alloy, and belongs to the field of metal dispersion reinforcement technology. A matrix element powder (Fe, Cr, Mo) and a beta' phase forming element powder (Ni, Al) and an oxide are formed into a component (Fe2O3, YH2 and Ti), and are pre-mixed uniformly, and then a high energy ball milling is carried out in Ar atmosphere with high purity, and a nanometer oxide dispersion phase is formed in situ by mechanical chemical reaction, thereby the nucleation energy barrier is reduced, and the oxide is nucleated uniformly. And then alloy powder after high energy ball milling is processed by SPS sintering or hot isostatic pressing densification. After solid solution and ageing heat treatment, the nanometer beta' phase element and the nanometer oxide composite reinforced Fe-based ODS alloy are obtained. According to the invention, two reinforced phases such as nanometer beta' phase and nanometer oxide are simultaneously introduced into the Fe-based ODS alloy, and the reinforced effects of the two nanometer precipitated phases are superposed, and the two precipitated phases has the advantages of very fine particle sizes, uniform distribution, high heat stability and substantial reinforcement effect, thereby further enlarging the usage temperature limit of the Fe-based ODS alloy.

The invention relates to the field of harmless fly ash treating, and provides a method and system for treating fly ash in a manner combining mechanochemistry and washing, with characteristics of high efficiency, low cost and zero harm. The system comprises a feed bin, a horizontal roller type ball mill, a stirring kettle and a plate-and-frame filter press, wherein the bottom of the feed bin is connected to a feed opening of the horizontal roller type ball mill; stainless steel milling balls are placed in a closed barrel body of the horizontal roller type ball mill; two ends of a discharge pipeline are connected to the bottom of the horizontal roller type ball mill and the upper part of the stirring kettle respectively; the upper part of the stirring kettle is connected with a water inlet pipeline, and the bottom of the stirring kettle is connected to the plate-and-frame filter press. According to the method and the system which are disclosed by the invention, the heavy metal solidification, the dioxin degradation and the chlorine removal of the fly ash can be realized at the same time in high efficiency, the treated fly ash is thoroughly harmless and has conditions of resource utilization, and the heavy metal solidification rate of the treated fly ash is more than 70%; an additive is not additionally added, so that the treating cost is low; the technological process is simple, the reaction conditions are mild, the treating process is environment friendly, and harmful by-products are not generated; the equipment investing cost and the operating cost are low, the treating effects are significant, and the technological process is simple to realize.

The invention relates to a method and system for converting sodium-containing and fluorine-containing compounds in a waste cathode carbon block of an aluminum electrolytic cell. The conversion methodcomprises the step that a conversion agent is used for converting the sodium-containing compound in the waste cathode carbon block of the aluminum electrolytic cell into a fluorine-free soluble sodiumcompound, converting the fluorine-containing compound into an insoluble and harmless mineral fluorine compound and converting a cyanide-containing compound into harmless N2 or NH3 and CO2 in an oxidized manner through a mechanochemical conversion reaction in a conversion mill, and therefore the hazards of fluoride and cyanide in the waste cathode carbon block of the aluminum electrolytic cell arecompletely eliminated. The conversion system comprises a waste cathode carbon block crushing device, a milling device, the conversion mill, a stirred reactor and a solid-liquid separation device which are sequentially connected in series, and the solid-liquid separation device is then directly connected with a concentration or crystallization device and a drying or heat treatment device, and thedrying or heat treatment device is connected to the crushing device. By means of the method and system, the process is simple, mass production is easy, the production cost is low, pollution of three wastes is avoided, and the method and system are environmentally friendly.

The invention relates to a hydrotalcite preparation method. Hydrotalcite is prepared in one step by adopting mechano-chemical process, the method includes uniformly mixing trivalent metal compound, divalent metal compound, solid base and carbonate, ball milling by a ball miller for 1-5 minutes, washing, and drying to obtain the required hydrotalcite. The invention has simple technological flow, less equipment investment, available main raw materials and low cost. The hydrotalcite obtained by the method has wide application for example, the hydrotalcite may be used as catalyst, catalyst precursor, ion exchanger or absorbent, medicine carrier, fire retardant and PVC heat stabilizer.

The invention relates to a method for preparing rod-shaped hydroxyapatite controllable in nanometer size by adopting a hydrothermal method. The method comprises the steps of preparing water-soluble chitosan quaternary ammonium salt from 2,3-epoxypropyltrimethylammonium chloride modified chitosan, taking the chitosan quaternary ammonium salt as a template and adopting the hydrothermal method to prepare nanometer rod-shaped hydroxyapatite. The method solves the defects that the prior precipitation method, hydrothermal method, mechanochemical method, sol-gel method and the like are difficult to control crystal textures in nanometer size scale, uncontrollable in morphology and poor in mechanical properties and biocompatibility. The method has the advantages of preparing crystal-type hydroxyapatite which is pure, controllable in morphology and size and uniform in size positioned in a nanometer range, improving the mechanical properties and biocompatibility of the hydroxyapatite and enabling the hydroxyapatite to be used for preparing inorganic toughening/reinforcing biodegradable osseous-tissue bracket material, along with simplicity, convenient operation and low manufacture cost.

The invention provides a process for selectively recovering lithium in waste lithium iron phosphate battery by means of a mechanochemical activation method, and belongs to a new solid waste reclamation technology in the field of environmental protection and resource comprehensive utilization. According to the process, the core principle is to carry out mechanical activation in the first place, sothat an excellent activation effect can be achieved through adding an inter-grinding agent; and then a composite leaching agent is used for selectively leaching the lithium in a positive electrode material of an lithium iron phosphate battery into a solution, at the moment, lithium and iron are completely separated while iron and phosphorus, together with carbon powder, enter leaching residue in the form of iron phosphate precipitate, so that in-situ recovery of iron and phosphorus is achieved. The process has the characteristics of short flow, simple operation, low energy consumption, environmental friendliness, no secondary pollution and a wide application prospect.

The invention relates to a rare earth/tourmaline composite material, as well as a preparation method and the application thereof, and aims to solve the difficult problem that quickly and efficiently removing various pollutants in water is difficult. The rare earth/tourmaline composite material is rare earth modified tourmaline obtained by adding tourmaline into a rare earth element solution with the concentration of 0.01-1.0 mol/L to be subjected to ultrasonic dispersion processing, and then performing stirring, solid-liquid separation as well as drying or calcining. The rare earth/tourmaline composite material provided by the invention has high mechanochemistry stability, has functions of composition, synergy and the like, can also reduce cost, improves the utilization ratio of the material, has the advantages of high adsorption speed, large capacity, wide applicable pH range, easiness in reutilization and the like, can improve operation efficiency and lower cost in the application of a water purification processing process, has a higher adsorption capacity, can realize sustainable use, and has high recycling rate and a good development prospect in the environmental field; the preparation process provided by the invention is simple; the modified tourmaline prepared according to the preparation process is good in dispersion.

The invention relates to a technology for synthesizing SrTiO3 nano-powder through a mechanochemical method. The technology at least comprises the following steps: 1, taking a proper amount of each of strontium oxide and titanium dioxide raw materials, respectively dumping the raw materials into beakers, putting the beakers in an oven, and drying for 12h; 3, uniformly mixing the above two powders with a molar ratio of 1:1; 3, adding the above obtained powder mixture and tungsten carbide balls to a pot, wherein the total volume of the powder mixture and the tungsten carbide balls does not exceed 2/3 of the total volume of the pot, and a mass ratio of the powder mixture to the tungsten carbide balls is 20:1; 4, turning on a power switch, and uncovering the cover of a high-energy ball mill; 5, operating according to the flow of a high-energy ball milling experiment; 6, setting parameters comprising a rotating speed of 200rpm and a cycle period of 30min; 7, clicking a start button for the working starting of the ball mill; 8, uncovering the cover of the high-energy ball mill and the cover of the ball milling pot 24h later, sampling, cleaning the ball milling pot with alcohol, and drying for later use; and 7, turning off the power switch. The SrTiO3 nano-powder synthesized in the invention has the characteristics of low energy consumption, high purity, small particle size, high automation degree, good quality consistency and repetitiveness, less pollutant emission and the like.

The invention discloses a recovery method for waste lithium ion battery anode materials based on a mechano-chemical method, and belongs to the field of waste lithium ion battery recycling. The waste lithium ion battery anode materials are ground into powder, the powder is sufficiently and evenly mixed with an activating agent and an organic reducing agent, the activating agent can generate activefree radicals, a mixture is obtained, the mixture is subjected to ball grinding, the waste lithium ion battery anode materials generate plastic deformation, lattice imperfection is generated in crystal particles, and the crystal particles generate crystal transfer or are not crystallized; and products obtained after ball grinding are added into deionized water, and valuable metal ions are leached.The method does not depend on high-concentration strong acid, strong base, strong oxidization reducing reagents, expensive organic acid and the like, the mechano-chemical reaction in a solid phase isadopted as a reaction body, and efficient leaching of valuable metal lithium, cobalt, nickel, manganese and the like in the waste lithium ion battery anode materials is achieved under the mild leaching environment.

The invention belongs to the technical field of heavy metal polluted soil treatment and in particular relates to a mechanochemical reduction remediation method for hexavalent chromium polluted soil. The method disclosed by the invention comprises the following steps: grinding naturally aired hexavalent chromium polluted soil in a mortar, sieving, carrying out a mechanochemical reaction on the sieved soil particles, reducing agents (such as ferrous sulfate, calcium polysulfides and the like) and zirconia in a ball mill tank according to a ratio, and transforming hexavalent chromium with high toxicity, easiness in migration and high bio-availability into trivalent chromium with low toxicity, easiness in precipitation and low bio-availability by virtue of mechanochemical reduction, thereby realizing harmless treatment of the hexavalent chromium polluted soil. The method disclosed by the invention has the characteristics of being high-efficiency, green and zero in secondary pollution and is a hexavalent chromium polluted soil remediation method with excellent application prospects.

The invention discloses a method of treating a waste lithium battery by adopting a mechanochemistry method, selectively recycling metal lithium and meanwhile directionally preparing a cobalt-based magnetic functional material, belonging to a new technology of treating solid wastes in the field of environmental protection and comprehensive utilization of resources. The method particularly comprises five procedures of discharging, splitting, ball milling, lithium recycling and calcining. The method is characterized in that a dry ball milling mode is adopted, so that materials and an assistant generate a solid phase reaction and no waste liquid is produced; by controlling the reaction process, the metal lithium is selectively recycled, and a magnetic material is directionally synthetized from metal cobalt. The method is simple and convenient to operate, low in cost, high in recovery rate, and mild in reaction condition, the assistant is cheap and easy to get, a prepared cobalt ferrite is excellent in magnetism, strong acids and strong oxidizers are not used all the way, and the method is a green and environment-friendly waste lithium battery recycling method.

The invention relates to composite cathode material for a lithium ion battery and a preparation method thereof, belonging to the chemical power source field. The invention aims to solve the problems that the first lithium ion insertion process of oxide cathode material performs an irreversible reaction, the first coulombic efficiency is low, etc. The preparation method comprises the following steps: using precursor MO, reducing agent metal lithium and a defined amount of organic solvent to perform wet mechanochemical in situ reduction and obtain power, heating the obtained power under vacuum atmosphere to remove organic solvent, and obtaining the composite material. The method of the invention has simple process, low cost and wide application range; and the first efficiency of the prepared composite cathode material is more than 80%, the maximum is more than 95%, and the composite cathode material also has good electrochemical cycle stability.

The invention discloses a mechanochemical preparation method for flavone compounds with a structure shown in a formula (II), which comprises the following steps: 1-(2'-hydroxy phenyl)-3-aryl-1, 3-propanedione with a structure shown in a formula (I) is taken as a raw material, hydrosulfate is taken as a catalyst, and silica gel is taken as a grinding aid to perform a ball grinding reaction in a closed ball grinding tank; and after the reaction is finished, a reaction mixture is separated and purified to obtain the flavone compounds with the structure shown in the formula (II). The method has the advantages of short reaction time, generally higher reaction yield, safe and reliable production, low production cost, simple post-treatment, small pollution and so on, and is the preparation method for the flavone compounds with better popularization and application prospects.

The invention discloses a method for preparing silica powder through a mechanical chemical method. The method includes the following steps that 1, silicon halide, metal hydride and grinding balls are added into a ball-milling tank in protecting atmosphere, and then the ball-milling tank is sealed, wherein the molar ratio of the silicon halide to the metal hydride is 1:2-1:6; 2, a ball-milling reaction is carried out on the silicon halide and the metal hydride under the conditions of the room temperature and the 100-rpm-to-500-rpm ball-milling rotating speed in the sealed ball-milling tank, and the ball-milling time is 1 h to 24 h; 3, after the ball-milling reaction is completed, hydrogen in the ball-milling tank is collected, and then powder in the ball-milling tank is taken out; 4, the powder is subjected to acid pickling and then washed till washing liquid is neutral; 5, the washed powder is dried and cooled, and the simple-substance silica powder is obtained. The method for preparing the silica powder has the advantages of being simple in technology, efficient and nontoxic, and facilitating industrialization implementing.

The invention provide a method and a device used for producing disilane through a chemical reaction of alloyed hydrogen-metal-silicon composition ammonium chloride in a liquid ammonia medium. According to the invention, hydrogen-metal-silicon composition and a corresponding alloying process are promoted; the composition is subjected to the chemical reaction with ammonium chloride in the liquid ammonia medium, such that monosilane and disilane are produced; monosilane is outputted under the control of a reflux monosilane absorption converter, and crude disilane is subjected to separation purification, such that high-yield disilane is prepared. The hydrogen-metal-silicon composition is composed of Si, H, and at least two components selected from: Mg, Ca, Sr, Ba, Li, Na, K, B, Al, Ti, Fe, and V. The composition is synthesized through a mechanical process, a thermo-mechanical process, or a mechanical chemical bonding process, and is subjected to heat treatment alloying, such that the composition can be utilized.