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408 results about "Mechanochemistry" patented technology

Mechanochemistry or mechanical chemistry is the coupling of mechanical and chemical phenomena on a molecular scale and includes mechanical breakage, chemical behaviour of mechanically stressed solids (e.g., stress-corrosion cracking or enhanced oxidation), tribology, polymer degradation under shear, cavitation-related phenomena (e.g., sonochemistry and sonoluminescence), shock wave chemistry and physics, and even the burgeoning field of molecular machines. Mechanochemistry can be seen as an interface between chemistry and mechanical engineering. It is possible to synthesize chemical products by using only mechanical action. The mechanisms of mechanochemical transformations are often complex and different from usual thermal or photochemical mechanisms. The method of ball milling is a widely used process in which mechanical force is used to achieve chemical processing and transformations. The special issue of Chemical Society Review (vol. 42, 2013, Issue 18) is dedicated to the theme of mechanochemistry. Fundamentals and applications ranging from nano materials to technology have been reviewed. The mechanochemical approach has been used to synthesize metallic nanoparticles, catalysts, magnets, γ‐graphyne, metal iodates, nickel–vanadium carbide and molybdenum–vanadium carbide nanocomposite powders...

Method for optimized operation of a mill for mechano-chemical activation

The present invention relates to a method for mechano-chemical activation in a mill, wherein the method has at least two operating states, wherein in a first operating state a first energy input per mass of ground material takes place, wherein in a second operating state a second energy input per mass of ground material takes place, wherein the first energy input is higher than the second energy input, wherein the first operating state is selected when electrical energy is cheaper or more available than in the long-term average, wherein the second operating state is selected when electrical energy is more expensive or less available than in the long-term average.
Owner:SCHWENK ZEMENT GMBH & CO KG +2

Device and method for temperature-optimized mechano-chemical activation

The present invention relates to a device for the mechanical activation of a mineral material, wherein the device has a mill 10, wherein the mill 10 has a drive 20, wherein the device has at least a first temperature sensing element 30, wherein the first temperature sensing element 30 is arranged in or on the mill 10, wherein the device has a control device 40, wherein the device has a material feed 50 for feeding ground material to the mill 10, wherein the control device 40 is connected to the first temperature sensing element 30 for transmitting the detected temperature, wherein the control device 40 is connected to the drive 20 for regulating the drive power and to the material feed 50 for regulating the supplied quantity of ground material.
Owner:SCHWENK ZEMENT GMBH & CO KG +2

Mechano-chemical activation with heat coupling

The present invention relates to a device for the mechano-chemical activation of a moist starting material, the device comprising a drying device 10 and a mill 20, the drying device 10 and the mill 20 being connected for transferring the material dried in the drying device 10, the mill 20 and the drying device 10 being connected for transferring the waste heat of the mill 20 to the drying device 10.
Owner:SCHWENK ZEMENT GMBH & CO KG +2

Method for efficiently preparing ionic super-crosslinked polymer by mechanochemical method, product and application thereof

The invention discloses a method for efficiently preparing an ionic super-crosslinked polymer by a mechanochemical method as well as a product and application of the ionic super-crosslinked polymer, and belongs to the technical field of polymer material preparation. The preparation method comprises the following steps: adding a nitrogen-containing monomer, a cross-linking agent and a catalyst into a good solvent to obtain a reaction solution; carrying out planetary ball milling treatment on the reaction liquid, and carrying out a Friedel-Crafts alkylation reaction; and after the reaction is completed, recovering and purifying the product to obtain the ionic super-crosslinked polymer. The ionic super-crosslinked polymer prepared by the preparation method disclosed by the invention has a highly crosslinked and abundant pore structure, and meanwhile, the ionic super-crosslinked polymer has the performance advantages of good adsorption performance, excellent chemical stability and high thermal stability. The synthetic method of the ionic super-crosslinked polymer provided by the invention is efficient, energy-saving and environment-friendly, the product quality is high, and the method has wide popularization and application prospects.
Owner:JINGCHU UNIV OF TECH

Double-vacancy Fe0. 96S (at) MoS2 nano composite material as well as wet-type mechanochemical synthesis method and application thereof

The invention relates to the technical field of environmental chemistry, in particular to a double-vacancy Fe0. 96S (at) MoS2 nano composite material as well as a wet-type mechanochemical synthesis method and application thereof. The preparation method comprises the following steps: firstly carrying out co-ball milling by utilizing a wet mechanical chemical synthesis method to obtain a low-crystallinity Fe0. 96S (at) MoS2 precursor, and then carrying out further calcination treatment to accelerate the thermal reaction of the precursor, improve the crystallinity and remove redundant sulfur powder impurities, thereby obtaining the high-crystallinity Fe0. 96S (at) MoS2 nano composite material. Iron powder is introduced in the process of preparing MoS2 nanosheets from molybdenum powder and sulfur powder, the reaction activity of the molybdenum powder and the sulfur powder is improved and the formation energy of MoS2 is reduced by utilizing the characteristic of ball-milling heat release of the iron powder and the sulfur powder, the reaction barrier that MoS2 is difficult to prepare between Mo and S through a mechanical ball-milling process originally is broken, and the generation of the MoS2 nanosheets is promoted.
Owner:QILU UNIVERSITY OF TECHNOLOGY (SHANDONG ACADEMY OF SCIENCES)

Method for deeply extracting vanadium from vanadium-containing steel slag

The invention provides a method for deeply extracting vanadium from vanadium-containing steel slag, which comprises the following steps: mixing the vanadium-containing steel slag and an oxygen-containing microbubble ammonium bicarbonate solution, and carrying out mechanochemical ball milling activation to carry out leaching reaction to obtain a vanadium extracting solution. According to the method, advanced oxidation is cooperated with mechanochemical ball milling to activate and strengthen deep extraction of vanadium in the vanadium-containing steel slag, wrapping of substances such as calcium silicate and calcium titanium oxide on a vanadium-containing solid solution phase is destroyed through mechanical activation, and O2 microbubbles in an ammonium bicarbonate medium are promoted to generate active oxygen under excitation of mechanical activation energy; exposure reaction and deep oxidation extraction of a vanadium-containing phase under mild conditions are achieved, the content of V2O5 in tailings after vanadium extraction is smaller than or equal to 0.5%, and the vanadium extraction rate is 83% or above.
Owner:INSTITUTE OF PROCESS ENGINEERING CHINESE ACADEMY OF SCIENCES

Method for preparing active kaolinite-series clay through synergistic activation and application of active kaolinite-series clay as auxiliary cementing material

The invention discloses a method for preparing active kaolinite-series clay through synergistic activation and application of the active kaolinite-series clay as an auxiliary cementing material, and belongs to the technical field of auxiliary cementing material production.On the basis of thermal activation, the kaolinite-series clay is subjected to synergistic treatment in combination with mechanochemical activation, the advantages of thermal activation and mechanochemical activation are fully exerted, and the active kaolinite-series clay is prepared. The activity of clay minerals and non-clay minerals in the kaolinite series clay is improved to the maximum extent, low-carbon activation of the kaolinite series clay is achieved, and a technical guarantee is provided for preparation of auxiliary cementing materials (SCMs).
Owner:XI'AN UNIVERSITY OF ARCHITECTURE AND TECHNOLOGY

Materials for the capture of substances

Materials such as ion exchange materials for capturing substances, and associated methods and systems, are generally described. In some instances, adsorbent materials that can capture undesirable species from fluid mixtures such as waste streams are provided. The adsorbent material may include ceramic particles (e.g., as a resin) functionalized for effectively and / or selectively capturing species such as per- and poly-fluoroalkyl substances (PFAS) and / or metal or metalloid-containing ions (including heavy metals). Systems and methods for further treating species captured by the adsorbent material are also provided. For example, some embodiments are directed to mechanochemical treatment of captured species associated with the adsorbent material. Subjecting captured species such as PFAS to mechanochemical transformations can destroy potentially harmful contaminants in a relatively inexpensive and distributable manner.
Owner:MEMBRION INC

Mechanochemical grinding method for efficiently degrading PFAS

The invention discloses a mechanochemical grinding method for efficiently degrading PFAS, which comprises the following steps: adopting B4C as a ball milling aid, putting B4C and PFAS into a ball mill according to a mass ratio of (250-1000): 50, and grinding until B-C bonds in B4C are broken, C-F bonds in PFAS are broken and B-F bonds are formed, thereby completing the degradation of PFAS; according to the method, the grinding process is improved through B4C, free electrons can be generated in the grinding treatment process, then PFAS is degraded, and the method has the advantages of being low in cost, high in efficiency and free of secondary pollution.
Owner:CHINESE RES ACAD OF ENVIRONMENTAL SCI

Halide material production method and halide material

A halide material producing method according to the present disclosure includes (A) subjecting a material mixture containing a first compound containing Li, M1, and X1 and a second compound containing M2 to mechanochemical treatment, wherein each of M1 and M2 represents one type of element selected from a metal element and a metalloid element, and X1 represents at least one selected from the group consisting of F, Cl, Br, and I.
Owner:PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO LTD

Method for producing composite for secondary battery electrode

To provide a method for producing a composite for a secondary battery electrode having excellent electrical conductivity by precisely controlling the dispersion state of fibrous carbon on an active material.SOLUTION: A method for producing a composite for a secondary battery electrode containing an electrode active material and fibrous carbon includes a step of combining an electrode active material and a fibrous carbon dispersion in which the fibrous carbon is dispersed in a solvent in a non-slurry state by using a mechanochemical mixer, and a step of removing the solvent and drying the composite. The fibrous carbon dispersion contains fibrous carbon, a dispersant, and a solvent. The dispersant contains a copolymer A containing a nitrile-group-containing structural unit and an aliphatic hydrocarbon structural unit. The Mooney viscosity (ML1+4,100°C) of the copolymer A is 10 to 70, and the phase angle of the fibrous carbon dispersion at a frequency of 1 Hz measured by dynamic viscoelasticity measurement is 19° or more.SELECTED DRAWING: None
Owner:TOYO INK MFG CO LTD

Hybrid organic-inorganic perovskite compounds for metal ion sensing applications and process of preparation thereof

The present invention generally relates to a field of material science and chemistry. Specifically, the present invention relates to synthesis and characterization of lead-free hybrid organic-inorganic Perovskite compounds for metal ion sensing applications. More particularly, the present invention relates to lead-free low dimensional manganese (Mn)- and copper (Cu)- based hybrid organic-inorganic perovskites (HOIPs) for visual fluorometric Pb2+ ion detection. Further, the present invention relates to synthesis of lead-free low dimensional manganese (Mn)- and copper (Cu)-based hybrid organic-inorganic perovskites (HOIPs) via mechanochemical synthesis methodology.
Owner:COUNCIL OF SCI & IND RES

Nickel-based catalyst as well as preparation method and application thereof

ActiveCN120205161AHydrocarbonsMetal/metal-oxides/metal-hydroxide catalystsPtru catalystIncipient wetness impregnation
The invention discloses a nickel-based catalyst as well as a preparation method and application thereof, and belongs to the technical field of catalyst synthesis. The nickel-based catalyst is prepared by an equivalent-volume impregnation method, a mechanochemical method and a deposition-precipitation method, the operation is simple, the cost is low, and the used raw materials are few; the method for regulating and controlling the selectivity of the prepared nickel-based catalyst to C4 olefin is simple and easy to implement, and the waterproof performance is good. According to the nickel-based catalyst, niobium oxide is used as a carrier, nickel is loaded on the niobium oxide carrier to catalyze heterogeneous ethylene oligomerization reaction, no co-catalyst is needed, the dispersity of loaded metal is effectively increased, carbon deposition and blockage are not prone to occurring in the reaction process, and the catalytic stability of the nickel-based catalyst for catalyzing the ethylene oligomerization reaction is improved.
Owner:QUZHOU RES INST OF ZHEJIANG UNIV

Method of producing hydrogen

To provide a method of producing hydrogen capable of improving a production amount of hydrogen.SOLUTION: A method of producing hydrogen includes: pulverizing and mixing a material to be pulverized and a solvent using a planet ball mill device having a container housed with a pulverization medium to produce hydrogen by mechanochemical reaction. The solvent includes water, the material to be pulverized is at least one of a metal, or a metallic compound of the metal as a main constituent, a material of at least one of the container and the pulverization medium is a material capable of reducing an oxide and a hydroxide of a metal by mechanochemical reaction, and a speed of rotation of the planet ball mill device is 400 rpm or more.SELECTED DRAWING: Figure 10
Owner:HIROSHIMA UNIVERSITY

Single-step low-temperature calcium carbonate production through carbon dioxide sequestration of mineral materials to make concrete

The disclosure herein sets forth processes and compositions for producing carbonated materials comprising calcium carbonates through a mechanochemical process. The present disclosure concerns the production of calcium carbonate by sequestrating CO2. Certain processes herein include providing alkaline-rich mineral materials that include carbonatable solid wastes such as lime kiln dust, cement kiln dust, and coal combustion residues, and simultaneously fractioning the alkaline-rich mineral materials, while contacting the alkaline-rich mineral materials with a CO2-containing gas in carbonation reactor at low temperature and ambient pressure. In some embodiments, the alkaline-rich mineral materials are partially carbonated before being used in the processes disclosed herein. After contacting the alkaline-rich mineral materials with a CO2-containing gas in carbonation reactor at low temperature and ambient pressure, solid calcium carbonate is produced. In aqueous reactors, the solid calcium carbonate is filtered from a solution in which it precipitated, and the remaining solution includes hydroxide as well as alkaline metal ions. The solution filtered from the solid calcium carbonate can be sequentially contacted with a CO2-containing gas stream to precipitate additional calcium carbonate. The carbonated materials formed from these processes can be used in the form of a slurry, as a moist powder, as a dried powder, as a reactive filler or as a supplementary cementitious material in a mixture that is used to make concrete.
Owner:CARBONBUILT

Kaolin hemostatic material with anti-inflammatory function as well as preparation method and application thereof

The invention relates to the technical field of hemostatic materials, in particular to a kaolin hemostatic material with an anti-inflammatory function and a preparation method and application thereof. The invention relates to a kaolin hemostatic material with an anti-inflammatory function. The kaolin hemostatic material comprises kaolin loaded with CeO2 nanoparticles. The preparation method comprises the following steps: mixing kaolin with cerium chloride, sodium carbonate and sodium chloride according to a certain mass ratio, then carrying out ball milling to obtain a precursor, and roasting the precursor to obtain the kaolin hemostatic material with the anti-inflammatory function. According to the preparation method, kaolinite which is low in price and rich in reserves is adopted as a raw material, a conventional CeO2 raw material is selected, a CeO2-loaded kaolinite-based nano material is prepared through a mechanochemical synthesis method, and the CeO2 / K nano material with synergistic anti-inflammatory and hemostatic activity is prepared.
Owner:CENT SOUTH UNIV +1

Metal sulfide / biochar composite material based on mechanochemical method as well as preparation method and application of metal sulfide / biochar composite material

The invention discloses a metal sulfide loaded biochar demercuration adsorbent as well as a preparation method and application thereof. The preparation method comprises the following steps: carrying out mechanochemical grinding on a biomass raw material and metal sulfate through a high-energy ball mill to obtain a uniform precursor; and then performing one-step pyrolysis in an inert atmosphere, synchronously carbonizing the biomass and reducing the metal sulfate into metal sulfide, and finally preparing the metal sulfide nanoparticle and charcoal matrix strong coupling composite material. The method is simple in process, green and efficient, and avoids the defects of a traditional liquid phase method. The prepared adsorbent is high in active component dispersity, is firmly combined with a carrier, shows high adsorption capacity, high removal efficiency and good anti-interference stability for elemental mercury in flue gas, and has a wide application prospect in the field of mercury pollution control of coal-fired flue gas.
Owner:SHANDONG UNIV SHENZHEN RES INST

Pyrite-coated WS2 heterogeneous Fenton composite catalyst as well as preparation method and application thereof

The invention provides a pyrite-coated WS2 heterogeneous Fenton composite catalyst as well as a preparation method and application thereof, and belongs to the technical field of organic dye sewage treatment. The method comprises the following steps: carrying out mechanochemical ball milling on nano WS2 and pretreated pyrite to prepare pyrite coated WS2; wherein the mechanochemical ball milling technology can improve the industrial wastewater treatment efficiency and reduce secondary pollution. By controlling the contrast, pollutant concentration and pH value of the catalyst, the prepared composite catalyst shows excellent catalytic activity and stability. The invention provides an effective strategy for solving the self-repairing and recycling problems of the traditional Fenton catalyst in practical application, is expected to be widely applied to the field of industrial wastewater treatment, and promotes the development of an environment treatment technology.
Owner:GUANGXI UNIV FOR NATITIES +1

Method for treating household garbage incineration fly ash and preparing modified mineral powder and modified mineral powder

The invention discloses a method for treating household garbage incineration fly ash and preparing modified mineral powder and the modified mineral powder. The method comprises the following steps that S1, the household garbage incineration fly ash is subjected to low-temperature detoxification treatment, secondary countercurrent washing treatment and mechanochemical method treatment, and detoxified fly ash is obtained; and S2, drying the detoxified fly ash, and stirring and mixing the dried detoxified fly ash with the superfine slag powder to obtain the fly ash modified mineral powder. The method can solve the problems of degradation of dioxin in the fly ash and unqualified leaching of heavy metals, then the detoxified fly ash is compounded with the superfine slag powder, the excitation effect of fly ash minerals is fully played, the performance of mineral powder products is improved, meanwhile, the household garbage incineration fly ash is fully utilized, waste is turned into wealth, and the method is suitable for industrial production. The method has important significance for realizing'zero landfill of fly ash 'and promoting'waste-free city' construction.
Owner:BAOWU GRP ENVIRONMENTAL RESOURCES TECH CO LTD +1

Quantum cascade laser with barrel-shaped waveguide and preparation method thereof

The invention relates to a quantum cascade laser with a cylindrical waveguide and a preparation method thereof, and belongs to the field of photoelectron, the quantum cascade laser comprises a laminated structure, the laminated structure is provided with two waveguide grooves, a ridge waveguide is formed between the two waveguide grooves, the waveguide grooves are hyperbolic, and the ridge waveguide is cylindrical; the bottom and side wall areas of the waveguide groove are subjected to mechanochemical grinding treatment and filled with InP: Fe, then mechanochemical grinding is carried out again, and then an insulating film layer material is evaporated; due to the unique cylindrical shape of the ridge waveguide, the photon density can be effectively improved, and the output characteristic of laser is optimized; and meanwhile, the mode distribution of light can be better controlled, and excellent laser characteristics are realized by utilizing optical reflection and interference effects. According to the invention, before secondary epitaxy, a mechanochemical grinding method is adopted to carry out surface treatment on the double channels, so that waveguide loss after secondary epitaxy of InP: Fe can be effectively reduced, the threshold current density is further reduced, and the output power and the slope efficiency are increased.
Owner:Shandong Huaguang Optoelectronics Co. Ltd.

A method and system for efficiently detoxifying, improving and reusing waste incineration fly ash

The present invention relates to hazardous waste treatment technology, and aims to provide a method and system for efficient detoxification, quality improvement and reuse of fly ash from garbage incineration. The method utilizes a stirred ball mill reactor, a secondary water washing unit, a tertiary water washing unit and a fired-free brick preparation unit arranged in sequence, and couples a wet mechanochemical method with a carbonation, multi-stage water washing and fired-free pressing treatment process to achieve detoxification, quality improvement and reuse of fly ash from garbage incineration; before the flue gas is introduced to start the carbonation reaction, the fly ash is first subjected to a wet mechanical ball milling pretreatment, and a heavy metal composite stabilizer is added according to the characteristics of the reaction system, so that phosphate and tris-mercapto-s-triazine trisodium salt react with heavy metals respectively to stabilize the heavy metals in the solid phase medium. The present invention can improve the ability of fly ash to seal carbon dioxide, and the hardness of the obtained water washing liquid is lower than , and the heavy metal content is extremely low, which reduces the cost of the existing evaporation crystallization process; the risk of heavy metal leaching is low, the fly ash dechlorination efficiency is high, and the mechanical properties of the prepared fired-free bricks are better than those of the prior art.
Owner:CHONGQING UNIV +1

Plasma ball-milled bamboo-based hard carbon negative electrode material and preparation method and application thereof

The invention discloses a plasma ball-milled bamboo-based hard carbon negative electrode material as well as a preparation method and application thereof. The plasma ball-milled bamboo-based hard carbon negative electrode material is sequentially treated by the steps of pretreatment, pre-oxidation, plasma ball-milling and high-temperature carbonization. Natural regular hierarchical pore channels and rich cellulose components of the southern moso bamboos provide an ideal structural template for hard carbon preparation; through the synergistic effect of pre-oxidation and plasma ball milling, an oxygen-containing functional group is introduced in the pre-oxidation to guide ordered stacking of carbon layers, and the plasma ball milling removes ash and optimizes the conductivity of a carbon skeleton through a mechanochemical effect. The negative electrode prepared from a sample subjected to ball milling for 15 minutes can still keep the reversible specific capacity of 254.9 mAh.g <-1 > after being circulated for 150 times under the current density of 1.0 A.g <-1 >, and the capacity retention rate is as high as 88%; benefited from a structure regulation and control strategy, the bamboo-based hard carbon negative electrode material subjected to plasma ball milling treatment shows excellent sodium storage performance when being used as a negative electrode of a sodium-ion battery.
Owner:NINGDE NORMAL UNIV

Preparation method of single-component alkali slag-regenerated micropowder cement

The invention provides a preparation method of single-component alkali slag-regenerated micropowder cement. The method comprises the following steps: mixing regenerated micro powder, slag, nickel slag and a solid alkali activator, and carrying out ball milling to prepare the single-component alkali slag-regenerated micro powder cement. Potential volcanic ash activity in the regenerated micro powder is activated through two activation means of mechanochemistry and alkali excitation, the particle morphology is improved by adjusting the proportion of RBP and RCP in the regenerated micro powder, the alkalinity of a system is increased through nickel slag, the alkali excitation reaction process is promoted, and macroscopic performance is improved. The invention aims to realize resource utilization of the building solid waste regenerated micro powder, the regenerated micro powder is introduced, the mechanical property of the cement is improved, and greenization of a cementing material, an admixture and a production process is realized.
Owner:FUZHOU UNIV

Mechanical chemical synthesis method of N-heterocyclic carbene metal assembly

PendingCN119462703Aincrease reaction rateIncrease the ambient temperatureSilver organic compoundsChemical synthesisSolvent free
The invention discloses a mechanochemical synthesis method of an N-heterocyclic carbene metal assembly, and relates to the technical field of chemical synthesis. The method comprises the following steps: mixing N-heterocyclic carbene precursor salt, silver oxide and alkali, adding grinding balls, and carrying out ball milling; and dissolving in a solvent, centrifuging, concentrating under reduced pressure, adding into a precipitant, centrifuging and drying in vacuum to obtain the N-heterocyclic carbene metal assembly. The method is used for synthesizing various types of metal supramolecular assemblies through one-pot ball milling under the condition of no solvent at the ambient temperature, and is carried out under the condition that the method is simpler and milder than other synthesis processes, and the yield is higher. Compared with harsh reaction conditions of a solution method, the solid ball milling method is simple and convenient to operate and rapid in reaction, and generation of by-products formed by AgI ions and a polar solvent is avoided. The problems that in the prior art, the reaction condition for preparing the N-heterocyclic carbene metal assembly is harsh, and by-products are likely to be generated are solved.
Owner:NORTHWEST UNIV

Method for efficiently recycling platinum group metal in waste catalyst through photocatalysis and application of method

The invention belongs to the technical field of precious metal recovery, and provides a method for efficiently recovering platinum group metal in a catalyst through photocatalysis and application thereof, and the method comprises the following steps: mixing a waste catalyst crushed material and metal powder, carrying out mechanochemical treatment, adding an acid solution, and reacting to obtain a modified waste catalyst; the modified waste catalyst and the leaching solution are mixed to obtain suspension liquid, then the suspension liquid is irradiated through ultraviolet-visible light for a photocatalytic reaction, filtering is conducted, and platinum group metal leaching liquid and leaching residues are obtained; and regulating the pH value of the platinum group metal leachate, adding an oxidizing agent, and extracting and separating the transition metal chloride by using an extracting agent to obtain the platinum group metal solution. According to the method, the platinum group metal particles are regulated and controlled while mechanical and chemical treatment activation is adopted, so that the platinum group metal particles generate the plasma resonance effect, strong redox active species generated by a photocatalyst under the illumination condition are converted into soluble compounds through complexation, and efficient leaching and recycling are achieved.
Owner:SHANGHAI SECOND POLYTECHNIC UNIVERSITY

Mechanochemically activated materials and their uses

ActiveDE202025100114U1KaolinitePhysical chemistry
A mechanochemically activated material obtainable by a process for the mechanochemical activation of kaolinite-poor starting materials, the process comprising the following steps: a) providing a solid starting material comprising a phyllosilicate mineral, the starting material having a kaolinite content of less than 50 wt% as determined by XRD, preferably less than 20 wt%, more preferably less than 10 wt%; b) providing a gas; c) introducing the feedstock and the gas into a mechanical agitation unit; and d) subjecting the starting material to mechanical agitation in the presence of the gas in the mechanical agitation unit; wherein the phyllosilicate mineral is selected from the kaolinite group, serpentinite group, mica group, chlorite group and combinations thereof, wherein the mechanochemically activated material has a Strength Activity Index (SAI) at Day 28 of at least 110%, the SAI being determined in accordance with ASTM C311 / C311 M-22.
Owner:CARBON UPCYCLING TECH INC

Mechanochemical treatment method and application of high-entropy oxide

The invention provides a mechanochemical treatment method of a high-entropy oxide and application of the mechanochemical treatment method. The high-entropy oxide is an oxide composed of five or more transition metals (at least including iron, cobalt, manganese, zinc and nickel elements). The method comprises the following steps: adding the high-entropy oxide into activated carbon powder (including coconut shell powder, walnut shell powder, bamboo charcoal powder and the like) or directly carrying out mechanochemical treatment, carrying out grinding by mainly adopting a grinder or a ball mill in the mechanochemical treatment, controlling grinding conditions to prepare an active super-stable catalyst, and introducing the catalyst and ozone into pollutants of benzotriazole, and benzotriazole can be degraded. The high-entropy oxide subjected to high-temperature roasting is treated by a mechanochemical method to obtain the ozone catalyst with both activity and stability, and the ozone catalyst is used for a long time in an acid environment, less in metal ion leaching, high in catalytic activity and good in ozone catalyst efficiency.
Owner:NANJING TECH UNIV

Gallium-based liquid metal conductive paste with strain insensitive characteristic as well as preparation method and application of gallium-based liquid metal conductive paste

The invention provides gallium-based liquid metal conductive paste with a strain insensitive characteristic and a preparation method and application thereof, and belongs to the technical field of electronic circuits. The gallium-based liquid metal conductive paste is prepared by mixing inorganic particles containing lone pair electrons with liquid metal, enabling the inorganic particles and the liquid metal to generate mechanochemical action under strong shearing force, and the paste is in a liquid state, a semi-solid paste state or a solid powder state with low surface tension according to different adding proportions of the inorganic particles. According to the invention, the conductive slurry is applied to various substrates through different processes, and strain-insensitive stretchable conductors with stretchability and high conductivity, such as liquid metal sheath core microfibers and liquid metal ion gel, are prepared. According to the invention, the tensile conductor prepared by adopting the gallium-based liquid metal conductive paste has the resistance change rate change of less than 15% under 200% strain, and the initial resistance is less than 1 ohm.
Owner:WUHAN TEXTILE UNIV