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Lithium battery composite electrode active material and application thereof

An active material and composite electrode technology, applied in battery electrodes, non-aqueous electrolyte battery electrodes, lithium batteries, etc., can solve the problems of poor cycle performance, severe volume expansion and contraction, structural collapse, etc., to achieve high energy density, high fast charging effect of ability

Pending Publication Date: 2022-03-25
YINLONG ENERGY CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The theoretical capacity of graphite is 372mAh / g, which is cheap and environmentally friendly. It occupies the main market of lithium-ion batteries, but at the same time, there is a risk of thermal runaway of the battery due to lithium precipitation; although the theoretical specific capacity of lithium titanate is only 175mAh / g, However, due to the stable charge and discharge structure, long cycle life, high rate performance charge and discharge, and performance can still be maintained in extreme temperature environments, it also has an advantage in some specific scenarios; The pursuit of density is getting higher and higher, silicon-based and tin-based will be the next research and development focus
[0004] At present, the main reason why silicon-based and tin-based materials cannot be commercialized is because silicon-based and tin-based materials undergo severe volume expansion and contraction during charging and discharging, and are prone to structural collapse and material crushing, resulting in poor cycle performance.

Method used

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  • Lithium battery composite electrode active material and application thereof
  • Lithium battery composite electrode active material and application thereof
  • Lithium battery composite electrode active material and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] Example 1: Preparation of a lithium-ion battery natural graphite / lithium titanate / tin disulfide composite electrode and its button battery

[0039] First weigh 15.3g of PVDF and add it to 860g of NMP and stir for 3 hours to obtain a colorless and transparent glue solution, then add 200g of natural graphite, 400g of lithium titanate, 400g of tin disulfide negative electrode active material and 5.1g of conductive agent acetylene black, first Stir slowly for 1 hour, then stir rapidly for 3 hours; measure the viscosity with a viscometer, add 10 g of water to adjust the viscosity at 4200 cps; finally, the ratio of active material: binder: conductive agent is 98:1.5:0.5, and the solid content is 54%.

[0040] Coat the electrode paste obtained in the above steps on a 6 μm thick copper foil, and dry it in an oven at 55°C; roll and punch it to the size of the pole piece required by the 2032 button battery.

[0041] Packaging of button cell: stack the pole piece, lithium piece, a...

Embodiment 2

[0042] Example 2: Preparation of a lithium-ion battery natural graphite / lithium titanate / tin disulfide composite electrode and its button battery

[0043] Referring to the method of Example 1, the difference is that the composition of the active material is 300g of natural graphite, 400g of lithium titanate, and 300g of tin disulfide.

Embodiment 3

[0044] Example 3: Preparation of a lithium-ion battery natural graphite / lithium titanate / tin disulfide composite electrode and its button battery

[0045] Referring to the method of Example 1, the difference is that the composition of the active material is 300g of natural graphite, 300g of lithium titanate, and 400g of tin disulfide.

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PUM

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Abstract

The invention relates to the technical field of lithium batteries, and discloses a lithium battery composite electrode active material and application thereof. The electrode active material is composed of a graphite material, lithium titanate and tin disulfide. According to the lithium titanate / tin disulfide / carbon composite electrode active material provided by the invention, through the composite action of the three components, the defects can be mutually compensated, so that the prepared battery has high energy density and fast charge capacity at the same time, and the preparation process is close to the existing lithium ion battery production process, and is suitable for batch production.

Description

technical field [0001] The present application relates to the technical field of lithium batteries, in particular to a lithium battery composite electrode active material and its application. Background technique [0002] Today, lithium-ion batteries play an important role in energy storage in everyday life. However, in different scenarios, people have different requirements for energy storage devices. For example, in new energy vehicles, not only high energy density but also high power density are required; in addition, due to the use of high-nickel materials, although in terms of capacity It can be improved, but it is also accompanied by safety and other issues. To sum up all the issues, people still need to continue to in-depth research on the power, battery life, and life of lithium-ion batteries. For lithium-ion battery anode materials, we hope to obtain higher theoretical specific capacity, better rate performance, and enhanced safety and stability. [0003] The curr...

Claims

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Application Information

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IPC IPC(8): H01M4/58H01M4/13H01M10/052
CPCH01M4/58H01M4/13H01M10/052Y02E60/10
Inventor 陈柏桦张凯何海平苏丽云黄超詹世英李海军
Owner YINLONG ENERGY CO LTD
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