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A kind of preparation method of high-strength and high-conductivity powder metallurgy copper-iron alloy

A copper-iron alloy and powder metallurgy technology, applied in the field of powder metallurgy, can solve the problems of high oxygen content of powder metallurgy copper-iron alloy, segregation of copper-iron alloy composition, difficult precipitation of iron phase, etc. fine grained effect

Active Publication Date: 2022-07-26
UNIV OF SCI & TECH BEIJING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to provide a high-strength and high-conductivity powder metallurgy copper-iron alloy with low oxygen content, fine crystal grains, uniform and fine iron phase distribution and good processing performance, so as to solve the problem of copper-iron alloy composition segregation and coarse crystal grains prepared by traditional smelting methods , poor processing performance, and the traditional powder metallurgy copper-iron alloy has high oxygen content, high sintering temperature and solid solution iron phase is difficult to precipitate, etc.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] a. Weigh 1607.1 g of water-atomized copper-iron alloy powder with an average particle size of 2 μm and 123.6 g of copper-phosphorus alloy powder with an average particle size of 10 μm (P content is 14wt.%), and put them into a V-type mixer for mixing , the mixing time is 4h, and a uniformly mixed powder is prepared, in which the mass fraction of Fe is 50% and the mass fraction of P is 1%.

[0024] b. Put the mixed powder into a silica gel package, the size of the inner cavity of the package is 150×100×25mm, and put it into a cold isostatic pressing machine. ×88 × 20mm green sheet.

[0025] c. Put the green sheet obtained by cold isostatic pressing into the vacuum sintering furnace, place a crucible with 1kg pure titanium powder in the furnace at the same time, and vacuumize for vacuum sintering, and the vacuum degree is 10 -3 Pa, the sintering temperature is 800°C, and the holding time is 6h to obtain a sintered slab of copper-iron alloy.

[0026] d. Hot rolling the s...

Embodiment 2

[0028] a. Weigh 4897.6g of water vapor combined atomized copper-iron alloy powder with an average particle size of 8μm and 29.6g of red phosphorus powder with an average particle size of 50μm, put them into a V-type mixer for mixing, and the mixing time is 4h, A uniformly mixed powder was prepared, in which the mass fraction of Fe was 35% and the mass fraction of P was 0.6%.

[0029] b. Put the mixed powder into a rubber cover, the size of the inner cavity of the package is 200×150×30mm, and put it into a cold isostatic pressing machine. 142×26mm green sheet.

[0030] c. Put the green sheet obtained by cold isostatic pressing into the vacuum sintering furnace, place a crucible with 1kg pure titanium powder in the furnace at the same time, and vacuumize for vacuum sintering, and the vacuum degree is 10 -2 Pa, the sintering temperature is 920°C, and the holding time is 2h to obtain a sintered slab of copper-iron alloy.

[0031] d. The sintered slab is hot-rolled, the hot-rolli...

Embodiment 3

[0033] a. Weigh 13769.4 g of gas atomized copper-iron alloy powder with an average particle size of 100 μm and 99.1 g of copper-phosphorus alloy powder with an average particle size of 20 μm (P content is 14wt.%), put them into a V-type mixer for mixing , the mixing time is 4h, and a uniformly mixed powder is prepared, in which the mass fraction of Fe is 15% and the mass fraction of P is 0.1%.

[0034] b. Put the mixed powder into the silica gel package, and the size of the inner cavity of the package is After packaging, put it into a cold isostatic pressing machine, the cold isostatic pressing pressure is 400MPa, and the pressure holding time is 300s. of green bars.

[0035] c. Put the bar blank obtained by cold isostatic pressing into a vacuum sintering furnace, and place a crucible with 1kg pure titanium powder in the furnace at the same time, and vacuumize for vacuum sintering, and the vacuum degree is 10 -1 Pa, the sintering temperature is 1000° C., and the holding ...

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Abstract

The invention relates to the field of powder metallurgy, and provides a preparation method of high-strength and high-conductivity powder metallurgy copper-iron alloy. The process steps include mixing atomized copper-iron alloy powder and copper-phosphorus alloy powder, and preparing strip and rod-like copper-iron alloy through cold isostatic pressing, vacuum sintering and subsequent deformation processing. The purpose of the present invention is to provide a high-strength and high-conductivity powder metallurgy copper-iron alloy with low oxygen content, fine grain size, fine iron phase, uniform distribution and good processing performance, so as to solve the problem of component segregation and coarse grains in the preparation of copper-iron alloy by traditional smelting method. , poor processing performance, and traditional powder metallurgy copper-iron alloys with high oxygen content, high sintering temperature and difficulty in precipitation of solid solution iron phase. The technology of the invention is easy to realize large-scale industrial production, and has important application prospects in the fields of 5G communication, 3C electronic products and rail transportation.

Description

technical field [0001] The invention belongs to the field of powder metallurgy, and relates to a method for preparing a high-strength and high-conductivity copper-iron alloy by adopting a powder metallurgy process. Background technique [0002] In recent years, with the rapid development of electronic communication, rail transportation and automobile industries, the conductive materials are required to have higher strength and conductivity. Copper-based alloys are widely used in the above fields due to their high electrical conductivity and high thermal conductivity. Among them, copper-iron alloys have both high strength, high conductivity and excellent electromagnetic wave shielding properties, low raw material cost, environmental friendliness and no pollution, which have aroused great interest. [0003] At present, the main method for preparing copper-iron alloys is the traditional smelting method, that is, copper and iron are heated and melted into a mixed solution, pour...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C1/04C22C33/02C22F1/08C21D6/00
Inventor 陈存广张陈增孙春芳李学成杨芳郭志猛李杨李沛
Owner UNIV OF SCI & TECH BEIJING