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Preparation method of high-strength and high-conductivity powder metallurgy copper-iron alloy

A technology of copper-iron alloy and powder metallurgy, which is applied in the field of powder metallurgy, can solve the problems of high oxygen content of powder metallurgy copper-iron alloy, segregation of copper-iron alloy composition, and difficult precipitation of iron phase, etc., and achieve high sintering density, uniform distribution of two phases, crystal grainy effect

Active Publication Date: 2022-04-08
UNIV OF SCI & TECH BEIJING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to provide a high-strength and high-conductivity powder metallurgy copper-iron alloy with low oxygen content, fine crystal grains, uniform and fine iron phase distribution and good processing performance, so as to solve the problem of copper-iron alloy composition segregation and coarse crystal grains prepared by traditional smelting methods , poor processing performance, and the traditional powder metallurgy copper-iron alloy has high oxygen content, high sintering temperature and solid solution iron phase is difficult to precipitate, etc.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] a. Weigh 1607.1g of water-atomized copper-iron alloy powder with an average particle size of 2 μm and 123.6 g of copper-phosphorus alloy powder (with a P content of 14wt.%) with an average particle size of 10 μm, and put them into a V-shaped mixer for mixing , the mixing time is 4h, and the uniformly mixed powder is prepared, wherein the mass fraction of Fe is 50%, and the mass fraction of P is 1%.

[0024] b. Put the mixed powder into a silica gel bag, the size of the inner cavity of the bag is 150×100×25mm, package it and put it in a cold isostatic press, the cold isostatic pressure is 100MPa, and the holding time is 90s to obtain 140 ×88×20mm plate green body.

[0025] c. Put the plate green body obtained by cold isostatic pressing into the vacuum sintering furnace, and place a crucible with 1kg of pure titanium powder in the furnace at the same time, vacuumize and carry out vacuum sintering, the vacuum degree is 10 -3 Pa, the sintering temperature is 800°C, and the...

Embodiment 2

[0028] a. Weigh 4897.6g of water-gas co-atomized copper-iron alloy powder with an average particle size of 8 μm and 29.6 g of red phosphorus powder with an average particle size of 50 μm, and put them into a V-shaped mixer for mixing. The mixing time is 4 hours. A uniformly mixed powder was prepared, wherein the mass fraction of Fe was 35%, and the mass fraction of P was 0.6%.

[0029] b. Put the mixed powder into a rubber sheath, the inner cavity size of the sheath is 200×150×30mm, package it and put it in a cold isostatic press, the cold isostatic pressing pressure is 200MPa, and the holding time is 10s to obtain 190× 142×26mm sheet blank.

[0030] c. Put the plate green body obtained by cold isostatic pressing into the vacuum sintering furnace, and place a crucible with 1kg of pure titanium powder in the furnace at the same time, vacuumize and carry out vacuum sintering, the vacuum degree is 10 -2 Pa, the sintering temperature is 920°C, and the holding time is 2h to obtain...

Embodiment 3

[0033] a. Weigh 13769.4g of gas-atomized copper-iron alloy powder with an average particle size of 100μm and 99.1g of copper-phosphorus alloy powder with an average particle size of 20μm (P content is 14wt.%), and put them into a V-shaped mixer for mixing , the mixing time is 4h, and the uniformly mixed powder is prepared, wherein the mass fraction of Fe is 15%, and the mass fraction of P is 0.1%.

[0034] b. Put the mixed powder into the silica gel bag, and the size of the inner cavity of the bag is Packaged and placed in a cold isostatic pressing machine, the cold isostatic pressing pressure is 400MPa, and the holding time is 300s, and the obtained bar blanks.

[0035] c. Put the bar billet obtained by cold isostatic pressing into a vacuum sintering furnace, and place a crucible with 1kg of pure titanium powder in the furnace at the same time, vacuumize for vacuum sintering, and the vacuum degree is 10 -1 Pa, the sintering temperature is 1000°C, and the holding time is...

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Abstract

The invention relates to the field of powder metallurgy, and provides a preparation method of a high-strength and high-conductivity powder metallurgy copper-iron alloy. The process comprises the following steps: mixing atomized copper-iron alloy powder and copper-phosphorus alloy powder, and preparing the plate-strip and rod-wire-shaped copper-iron alloy through isostatic cool pressing, vacuum sintering and subsequent deformation processing. The invention aims to provide the high-strength and high-conductivity powder metallurgy copper-iron alloy with low oxygen content, fine grains, fine iron phase, uniform distribution and good processability, so as to solve the problems of composition segregation, coarse grains, poor processability and low production cost of the copper-iron alloy prepared by the traditional smelting method. And the traditional powder metallurgy copper-iron alloy has the problems of high oxygen content, high sintering temperature, difficult precipitation of a solid-solution iron phase and the like. The technology provided by the invention is easy to realize large-scale industrial production, and has important application prospects in the fields of 5G communication, 3C electronic products, rail transit and the like.

Description

technical field [0001] The invention belongs to the field of powder metallurgy, and relates to a method for preparing a high-strength, high-conductivity copper-iron alloy by adopting a powder metallurgy process. Background technique [0002] In recent years, with the rapid development of electronic communication, rail transit and automobile industry, conductive materials require higher strength and conductivity. Copper-based alloys are widely used in the above fields due to their high electrical and thermal conductivity. Among them, copper-iron alloys have both high strength, high conductivity, excellent electromagnetic wave shielding properties, low raw material cost, environmental friendliness and no pollution, and have aroused great interest. [0003] At present, the main method of preparing copper-iron alloy is the traditional smelting method, that is, copper and iron are heated and melted into a mixed solution, which is poured and solidified to obtain a copper-iron all...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C1/04C22C33/02C22F1/08C21D6/00
Inventor 陈存广张陈增孙春芳李学成杨芳郭志猛李杨李沛
Owner UNIV OF SCI & TECH BEIJING