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Waste sagger tundish coating material and use method thereof

A technology of tundish and smearing materials, which is applied in the field of comprehensive utilization of waste resources, can solve the problems of high maintenance costs, pollution, and large investment in facilities, and achieve the effects of reduced facility occupation, fast sintering, and resource conservation

Inactive Publication Date: 2022-07-12
HENAN MECHANICAL & ELECTRICAL VOCATIONAL COLLEGE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, in the discarded saggers during the firing process of producing lithium battery electrode materials such as lithium iron phosphate, there are mainly mullite-bonded high-alumina materials, magnesium-aluminum spinel-bonded magnesia materials, and magnesium-aluminum spinel-bonded caskets. The content of MgO in the bowl is as high as 65%, and MgO and Al 2 o 3 Magnesia saggar materials with a total content higher than 90%, mullite combined with Al in high alumina 2 o 3 The content is as high as 75% or more, but these lithium-ion battery electrode materials are fired and discarded. Because they contain soluble salts (phosphorus, lithium) and heavy metal ions such as cobalt, there are water and soil pollution problems in landfill storage and open-air stacking. Shed memory There are problems of large investment in facilities and high maintenance costs. If we can invent a tundish alkaline smear that can use the full value, high value, and harmless of this abandoned sagger, it will help save the tundish alkaline smear The consumption of forsterite, the reduction of waste saggers storage land, or the occupation of facilities, and the reduction of other negative effects on environmental protection have positive economic, environmental, and social significance.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Example 1: The present invention uses waste saggars to prepare converter charging materials for 100t tundish alkaline smears. The waste saggers are magnesia-aluminum spinel combined with magnesia saggars, and MgO and Al in the magnesia saggars 2 O 3 The sum of the content is higher than 92%, and the MgO content is higher than 70%; the plasticizing material is light-burned magnesia powder, the fineness of light-burned magnesia powder is not greater than 0.075, and the particle size composition of the crushed and sieved waste saggar materials 1~2mm content is 25%, 0.35mm-1.0mm content is 40%, the balance is waste saggar sand with particle size less than 0.35mm, and the quality of light-burned magnesia sand powder in tundish alkaline coating material The content is 5%.

[0023] The method that the present invention uses in embodiment one is:

[0024] Step 1: crush and sieve the waste saggar to make the waste saggar segment sand;

[0025] Step 2: Homogenize and mix the w...

Embodiment 2

[0029] Embodiment 2: The present invention uses waste saggar to prepare converter charging material for 100t tundish alkaline smear material, the waste saggar is mullite combined with high-alumina saggar, and the mullite and Al in the magnesia saggar are 2 O 3 The sum of the content is 91%, Al 2 O 3 The content is 76%; the plasticizing material is bentonite powder, the fineness of the bentonite powder is not more than 0.075, the particle size composition of the crushed and sieved saggar material is 1~2mm, the content is 30%, and the content is 0.35mm-1.0mm In the 40% waste saggar section sand with the balance of particle size less than 0.35mm, the mass content of bentonite powder in the tundish alkaline coating material is 5%.

[0030] The method that the present invention uses in embodiment two is:

[0031] Step 1: crush and sieve the waste saggar to make the waste saggar segment sand;

[0032] Step 2: Homogenize and mix waste saggar section sand and bentonite powder to m...

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Abstract

The invention provides a waste sagger tundish coating material and a use method thereof. The waste sagger tundish coating material comprises a waste sagger material and a plasticizing material. The purpose of preparing the tundish coating from the waste saggar is achieved, and the effect and purpose of full-value, high-value and harmless utilization of the waste saggar are achieved; the low-melting-point substance in the waste saggar has the effects of high sintering speed and short baking time, the phases in the waste saggar material mainly comprise homogeneous multi-time sintered MgO particles and magnesium aluminate spinel (or mullite and Al2O3 particles), and the magnesium aluminate spinel is superior to traditional forsterite in thermal shock resistance and mechanical shock resistance. The thermal shock resistance and the mechanical shock resistance of mullite are superior to those of traditional high aluminum or corundum. The service life of the coating material is slightly longer than that of a traditional coating material made of similar materials. The method disclosed by the invention has economic, environment-friendly and social positive significance in reducing the cost, saving resources, reducing the occupation of waste saggar stockpiling land and facilities or reducing other environment-friendly negative effects and the like.

Description

technical field [0001] The invention belongs to the technical field of comprehensive utilization of waste resources, in particular to a waste saggar tundish smear and a use method. Background technique [0002] At present, the waste saggars in the firing process for preparing lithium battery electrode materials such as lithium iron phosphate are mainly mullite-bonded high-alumina materials, magnesium-aluminum-spinel-bonded magnesia materials, and magnesium-aluminum-spinel-bonded saggers. The content of MgO in the bowl is as high as 65% or more, and MgO and Al 2 O 3 Magnesium saggar material whose sum of content is higher than 90%, mullite combined with Al in high alumina 2 O 3 The content is as high as 75% or more, but the saggars discarded by the firing of these lithium-ion battery electrode materials contain soluble salts (phosphorus, lithium) and heavy metal ions such as cobalt. There are problems of large investment in facilities and high maintenance costs. If we can...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B41/87C09D1/00C09D5/18
CPCC04B41/009C04B41/5037C04B41/87C09D5/18C09D1/00C04B35/66C04B41/5036C04B41/5031C04B41/0072Y02E60/10
Inventor 王振峰
Owner HENAN MECHANICAL & ELECTRICAL VOCATIONAL COLLEGE
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