Preparation method of writable thermo-sensitive paper
A heat-sensitive paper and heat-sensitive technology, applied in special paper, papermaking, paper, etc., can solve the problems of reduced ink absorption ability and roughness, and achieve the effects of smooth paper feeding, high image definition, and good coloring ability
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Embodiment 1
[0033] A preparation method of writable thermal paper, specifically by sequentially coating a pre-coating coating and a thermal coating on a base paper, wherein the base paper is thermal base paper, double-adhesive paper, writing paper, coated paper or white card Paper, the basis weight of paper is 100-200g / m 2 , the smoothness is greater than 30s, and the surface water absorption Cobb is less than 60g / m at 60s 2 ;in,
[0034] In parts by mass, the heat-sensitive coating comprises the following components:
[0035] 10 parts of heat-sensitive dye; 18 parts of heat-sensitive color developer; 9 parts of sensitizer; 28 parts of nano-silica; 12 parts of calcined kaolin; 7 parts of lubricant; 8 parts of polyvinyl alcohol; 0.5 part of dispersant; defoaming agent agent 0.5 powder; 1 part of wetting and leveling agent; coating weight 7g / m 2 ;
[0036] The dye is 2-(2-4-dimethylamino)-3-methyl-6-diethylaminofluoran;
[0037] The color developer is 2,4-dihydroxydiphenylsulfone or 4,...
Embodiment 2
[0048] A preparation method of writable thermal paper, specifically by sequentially coating a pre-coating coating and a thermal coating on a base paper, wherein the base paper is thermal base paper, double-adhesive paper, writing paper, coated paper or white card Paper, the basis weight of paper is 100-200g / m 2 , the smoothness is greater than 30s, and the surface water absorption Cobb is less than 60g / m at 60s 2 ;in,
[0049] In parts by mass, the heat-sensitive coating comprises the following components:
[0050] 10 parts of heat-sensitive dye; 18 parts of heat-sensitive color developer; 9 parts of sensitizer; 28 parts of nano-silica; 12 parts of calcined kaolin; 7 parts of lubricant; 8 parts of polyvinyl alcohol; 0.5 part of dispersant; defoaming agent agent 0.5 powder; 1 part of wetting and leveling agent; coating weight 7g / m 2 ;
[0051] The dye is 2-(2-4-dimethylamino)-3-methyl-6-diethylaminofluoran;
[0052] The color developer is 2,4-dihydroxydiphenylsulfone or 4,...
Embodiment 3
[0065] A preparation method of a writeable thermal paper, the same as in Example 2, the difference is that the preparation method of the nano-silica further comprises the following steps:
[0066] (3) Disperse the dried product obtained in step (2) in anhydrous toluene, add mercaptopropyltrimethoxysilane, heat up and reflux for 1-2h, separate the precipitate and wash with absolute ethanol, and dry to obtain The sulfhydrylation intermediate is prepared by adding the sulfhydrylation intermediate to methanol, adding hydrogen peroxide and concentrated sulfuric acid, stirring and reacting at room temperature for 2 hours, separating the precipitate, washing with absolute ethanol, and drying;
[0067] Wherein, the mass ratio of the dried product to the anhydrous toluene and mercaptopropyltrimethoxysilane is 1:0.3:8.7; the mass ratio of the thiolated intermediate to the methanol, hydrogen peroxide and concentrated sulfuric acid is 1 :7.9:32:0.48.
[0068] The PPS roughness tester was...
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