Antibacterial ES fiber for cool-feeling non-woven fabric and preparation method of antibacterial ES fiber

A non-woven fabric and fiber technology, applied in the fiber field, can solve the problems of ES fiber's weak antibacterial properties, inability to meet production requirements in different fields, and sultry products, and achieve the effects of good dispersion, excellent thermal conductivity, and not easy to agglomerate.

Pending Publication Date: 2022-08-09
江苏惠康特种纤维有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, most of the ES fibers on the market are not antibacterial, and the manufact

Method used

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  • Antibacterial ES fiber for cool-feeling non-woven fabric and preparation method of antibacterial ES fiber

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Step 1: Preparation of boron nitride grafted with Schiff base:

[0025] Preparation of Schiff base: take 12mmol of 2-hydroxyacetophenone, add dropwise 35ml of anhydrous methanol, 12mmol of 2-hydroxypropylamine, react at 77°C for 6h, cool for crystallization, filter, add 10ml of dimethylformamide, 10ml of anhydrous Methanol, cooling and crystallization, filtration, and drying to obtain Schiff base.

[0026] 10g of boron nitride was heated at 1000℃ for 2.5h, cooled to 26℃, washed with deionized water, filtered and dried to obtain hydroxylated nano-boron nitride; 1g of Schiff base was added, 20ml of deionized water was added, and at 45 The reaction was carried out at ℃ for 1.5 h to obtain boron nitride grafted with Schiff base.

[0027] Step 2: Preparation of L-arginine-grafted ZnO-MOFs:

[0028] Preparation of ZnO-MOFs: take 15g of zinc nitrate hexahydrate and 1000ml of deionized water, stir evenly to obtain a solution of zinc nitrate hexahydrate; take 8.2g of 2-methyli...

Embodiment 2

[0037] Step 1: Preparation of boron nitride grafted with Schiff base:

[0038] Preparation of Schiff base: take 12mmol of 2-hydroxyacetophenone, add dropwise 35ml of anhydrous methanol and 12mmol of 2-hydroxypropylamine, react at 75°C for 5.5h, cool for crystallization, filter, add 10ml of dimethylformamide, 10ml of Water methanol, cooling and crystallization, filtration and drying to obtain Schiff base.

[0039] 10g of boron nitride was heated at 980°C for 2h, cooled to 25°C, washed with deionized water, filtered and dried to obtain hydroxylated nanoboron nitride; 1g of Schiff base was added, 20ml of deionized water was added, and the temperature was 40°C. The reaction was continued for 1 h to obtain boron nitride grafted with Schiff base.

[0040] Step 2: Preparation of L-arginine-grafted ZnO-MOFs:

[0041] Preparation of ZnO-MOFs: take 15g of zinc nitrate hexahydrate and 1000ml of deionized water, stir evenly to obtain a solution of zinc nitrate hexahydrate; take 8.2g of ...

Embodiment 3

[0050] Step 1: Preparation of boron nitride grafted with Schiff base:

[0051] Preparation of Schiff base: take 12mmol of 2-hydroxyacetophenone, add dropwise 35ml of anhydrous methanol, 12mmol of 2-hydroxypropylamine, react at 80°C for 6.5h, cool for crystallization, filter, add 10ml of dimethylformamide, 10ml of Water methanol, cooling and crystallization, filtration and drying to obtain Schiff base.

[0052] 10g of boron nitride was heated at 1020℃ for 3h, cooled to 27℃, washed with deionized water, filtered and dried to obtain hydroxylated nano-boron nitride; 1g of Schiff base was added, 20ml of deionized water was added, and the temperature was 50℃. The reaction was continued for 2 h to obtain boron nitride grafted with Schiff base.

[0053] Step 2: Preparation of L-arginine-grafted ZnO-MOFs:

[0054] Preparation of ZnO-MOFs: take 15g of zinc nitrate hexahydrate and 1000ml of deionized water, stir evenly to obtain a solution of zinc nitrate hexahydrate; take 8.2g of 2-me...

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Abstract

The invention discloses an antibacterial ES fiber for a cool-feeling non-woven fabric and a preparation method of the antibacterial ES fiber. Taking superfine diatomite and stearic acid, uniformly stirring, adding polypropylene, a phosphite ester antioxidant and PE wax, and uniformly stirring to obtain a core layer mixture; taking superfine diatomite and stearic acid, uniformly stirring, adding polyethylene, a phosphite ester antioxidant and PE wax, and uniformly stirring to obtain a skin layer mixture; uniformly stirring the core layer mixture and the skin layer mixture, extruding, spinning, stretching, drying and cutting off to obtain ES fibers, soaking the ES fibers in a heat-conducting antibacterial solution for 50 minutes, taking out, and drying to obtain the antibacterial ES fibers for the cool-feeling non-woven fabric. The antibacterial solution is composed of ZnO-MOFs grafted with L-arginine and boron nitride grafted with Schiff base, so that the ES fiber fabric is endowed with good antibacterial property and heat-conducting property, heat energy can be rapidly taken away, and the ES fiber fabric can be applied to cool antibacterial non-woven fabrics.

Description

technical field [0001] The invention relates to the technical field of fibers, in particular to an antibacterial ES fiber for a cool feeling non-woven fabric and a preparation method thereof. Background technique [0002] ES fiber is a kind of composite fiber with functionality and high added value. It is extruded from two kinds of chips with different low melting points through a twin-screw spinning machine. Non-woven fabrics without adhesives can be formed, which can be used in clothing, carpets, industrial textiles and other fields. However, most of the ES fibers on the market have weak antibacterial properties, and the manufactured products are too hot to meet the production requirements of different fields. [0003] In order to solve the above problems, the present invention discloses an antibacterial ES fiber for a cool-feeling non-woven fabric and a preparation method thereof. SUMMARY OF THE INVENTION [0004] The purpose of the present invention is to provide a k...

Claims

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Application Information

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IPC IPC(8): D01F8/06D01F1/10D01D5/34
CPCD01F8/06D01F1/103D01F1/10D01D5/34Y02A50/30
Inventor 夏红卫
Owner 江苏惠康特种纤维有限公司
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