High thermal conductive and high air-tightness packaging material of film and preparation method
A thin-film packaging and high-air-tight technology, which is applied in chemical instruments and methods, semiconductor/solid-state device manufacturing, electrical components, etc., can solve the problems of poorer thermal conductivity and gas barrier properties than the latter, and achieve high visible light transmittance, Low thermal expansion coefficient and the effect of maintaining visible light transmittance
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Embodiment 1
[0020] Clean the surface of the polyimide PI film with acetone and deionized water in an ultrasonic cleaner, put it into a plasma-enhanced chemical vapor deposition system (PECVD), and pass CH 4 Gas, carry out plasma enhanced chemical vapor deposition reaction, take it out after 15 minutes, during this process, the following process parameters should be controlled: RF source frequency 13.56MHz, RF source power range 50~150W, pressure less than 7.5×10 -5 Torr, gas flow rate range 20 ~ 80sccm. That is, a dense DLC film (type A) is formed on the PI substrate with a film thickness of about 200nm. The thermal conductivity of the formed PI composite film is about 180% higher than that of PI without DLC, and the oxygen transmission rate and water vapor transmission rate are reduced by 100 times. This high thermal conductivity and air-tight film packaging material encapsulates a multilayer organic thin film display containing a cathode, a hole transport layer, a light-emitting layer,...
Embodiment 2
[0022] Others are as in Example 1, the organic thin film diode is packaged, and compared with the device prepared under the same conditions and the same process with PI without DLC coating as the packaging material, the luminous life of the device is extended by about 110%.
Embodiment 3
[0024] The deposition on the surface of the polymer PI thin film is as in Example 1, and the side where the DLC is deposited is the same as in Example 1, and then plasma-enhanced chemical vapor deposition is carried out to prepare a B-type sandwich with a dense DLC film on both sides of the PI substrate. Composite thin film packaging material, the film thickness is about 200nm. Compared with PI without DLC coating, the thermal conductivity of this B-type sandwich material increases by about 190%, and the oxygen transmission rate and water vapor transmission rate decrease by 800 times. This extremely high thermal conductivity and airtight thin film packaging material is used to package thin film displays. Compared with the device made of PI without DLC coating as the packaging material under the same conditions and the same process, the luminous life of the device is extended by about 135%. .
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