Core/shell nano particle grinding agent polishing solution composition and method for preparing same

A technology of polishing liquid composition and nano-particles, which is applied in the direction of chemical instruments and methods, and other chemical processes, can solve problems such as high surface activity, polishing liquid failure, particle dispersion stability, etc., and achieve improved water dispersion stability, Improve the effect of polishing scratches and surface damage

Inactive Publication Date: 2005-08-17
SHANGHAI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, chemical mechanical polishing technology is generally used to polish the surface of hard disk substrates. Abrasives are the main components of chemical mechanical polishing fluids. The abrasives currently used are all selected from solid inorganic particles such as alumina, zirconia, diamond, and silicon oxide. , cerium oxide, titanium oxide, iron oxide, silicon nitride, etc., in the hard disk substrate polishing process, there are the following problems: first, the dispersion stability of the particles, due to the small particle size, large surface activity, the interaction between particles The force is stro...

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] Example 1: α-Al to be used as the core 2 O 3 The nanoparticle abrasive was surface-modified with acryloyl chloride, then placed in an acrylic acid solution, and emulsion polymerization occurred at a temperature of 80 °C, the reaction time was 12 hours, and the grafting ratio was 10% to obtain a surface-coated polyacrylic acid. Core / Shell α-Al 2 O 3 Nanoparticles; α-Al 2 O 3 The dosage of nanoparticles is 7wt%; α-Al 2 O 3 The average particle size of the nanoparticles is 2690 nm; under the condition of mechanical stirring, the core / shell α-Al 2 O 3 Nanoparticles are added to deionized water for dispersion and dilution, and then further ultrasonic dispersion is carried out; in the dispersed liquid, hydrogen peroxide, an oxidant, is added in an amount of 2wt%, and the pH value is adjusted to 1.98 with sulfuric acid. The final preparation into the desired polishing liquid.

Embodiment 2

[0020] Embodiment 2: The preparation process of this embodiment is basically the same as that of Embodiment 1, the difference is that the α-Al as the core 2 O 3 The average particle size of the nanoparticles is 1370nm; the pH value is adjusted to 1.90, and the desired polishing liquid is finally prepared.

Embodiment 3

[0021] Embodiment 3: The preparation process of this embodiment is basically the same as that of Embodiment 1, the difference is that the α-Al as the core 2 O 3 The average particle size of the nanoparticles is 350nm; the pH value is adjusted to 1.96, and the desired polishing liquid is finally prepared.

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PUM

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Abstract

The present invention relates to one kind of core-shell type nanometer particle abrasive polishing liquid composition and its preparation process, and belongs to the field of surface polishing technology. The polishing liquid includes abrasive, oxidant and water, and features the abrasive is core-shell type nanometer composite particle abrasive, which has traditional abrasive, such as superfine alumina, silica, zirconia, cerium oxide, titania, ferric oxide, diamond or silicon nitride, as inner core, and hydrophilic segment polymer or compound containing organic functional group as shell. The polishing liquid is suitable for chemical and mechanical polishing of memory hard disc chip and aluminum magnetic disc, and has the advantages of reduced surface roughness and waviness, reduced surface mechanical damage and effective elimination of micro default.

Description

technical field [0001] The invention relates to a core / shell type nanoparticle abrasive polishing liquid composition and a preparation method thereof. The polishing liquid is a chemical mechanical polishing liquid, which is mainly used in the polishing process of a memory hard disk substrate, and belongs to the surface polishing processing technology. field. Background technique [0002] In recent years, with the rapid increase in the capacity and density of memory hard disks, the flying height of computer magnetic heads has been reduced to about 10 nanometers, and it is expected that the next generation will be reduced to 7-8 nanometers. As the head and disk operate so close, the demands on the surface quality of the disk are also increasing. If the surface roughness and corrugation of the hard disk are too large, the magnetic head will collide with the surface of the magnetic disk during high-speed operation, which will damage the magnetic head or the magnetic medium on t...

Claims

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Application Information

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IPC IPC(8): C09K3/14
Inventor 雷红
Owner SHANGHAI UNIV
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