Hydrocracking process
A hydrocracking and solution technology, applied in the direction of hydrocarbon oil cracking, petroleum industry, etc., can solve the problem of small improvement of tail oil properties.
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Embodiment 1
[0017] 166 grams of USY molecular sieve (hydrothermal treatment method, silicon-aluminum molar ratio 5.07, unit cell constant 24.48A, crystallinity 76%, dry basis 70%), 133 grams of SB powder (pore volume 0.46ml / g, specific surface area 260m 2 / g, dry basis 30%) prepared binder, 32.4 gram of molybdenum oxide, 44 gram of nickel nitrate are put into roller compactor, grind to extrudable paste, extrusion, 110 ℃ of drying 4 hours, 500 ℃ of roasting 3 hours hours, catalyst C-1 was prepared.
Embodiment 2
[0019] 107 grams of US-SSY molecular sieve (after the ammonium fluorosilicate aqueous solution is treated with sodium ammonium Y molecular sieve, hydrothermal treatment, silicon-aluminum molar ratio 10.6, unit cell constant 24.37A, crystallinity 90%, dry basis 75%), 133 grams by SB Powder (pore volume 0.46ml / g, specific surface area 260m 2 / g, dry basis 30%) prepared adhesive, 62.8 grams of macroporous alumina powder (pore volume 0.92ml / g, specific surface area 270m 2 / g, dry basis 70%) put into a roller compactor, grind until extrudable paste, extrude, dry at 110°C for 4 hours, bake at 550°C for 3 hours, impregnate with ammonium metatungstate and nickel nitrate aqueous solution, 110°C Drying for 4 hours, followed by calcination at 500°C for 3 hours to prepare catalyst C-2. Catalyst containing WO 3 22.0w%, NiO 6.0w%.
Embodiment 3
[0021] 54.8 grams of NTY molecular sieves (prepared by hydrothermal treatment and acid treatment combination method, silicon-aluminum molar ratio 12.53, unit cell constant 24.38A, crystallinity 96%, dry basis 73%), 133 grams of SB powder (pore volume 0.46ml / g , specific surface area 260m 2 / g, dry basis 30%) prepared adhesive, 42.8 grams of macroporous alumina powder (pore volume 0.92ml / g, specific surface area 270m 2 / g, dry basis 70%), 45 grams of amorphous silicon-alumina are put into the roller compactor, rolled until the paste can be extruded, extruded, dried at 110°C for 4 hours, roasted at 550°C for 3 hours, and ammonium metatungstate, Catalyst C-3 was prepared by impregnating with nickel nitrate aqueous solution, drying at 110°C for 4 hours, and calcining at 500°C for 3 hours. Catalyst containing WO 3 24.5w%, NiO 6.5w%.
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