Method for producing trimethylgallium and method for producing gallium nitride thin film
A technology of trimethyl gallium, manufacturing method, applied in chemical instruments and methods, gallium/indium/thallium compound, semiconductor/solid-state device manufacturing, etc.
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[0055] The present invention is explained by referring to the following examples and comparative examples, but the present invention should not be limited to these examples and comparative examples.
[0056] (analysis of crude TMA)
[0057] With respect to organosilicon compounds, crude TMA(1), TMA(2) and TMA(3) of different suppliers and grades were analyzed.
[0058] Dilute 11.3g TMA (1) with 143.6g xylene, and mix in the hydrolysis container that is filled with 80ml acid solution, this acid solution is the hydrochloric acid of 36% by weight diluted to half, drop into this TMA solution diluted through xylene To hydrolyze TMA, wherein the temperature of the hydrolysis solution is maintained at about -5 to -20° C. by cooling and adjusting the dropwise amount of TMA. Absorb the gas generated by hydrolysis with an absorption vessel filled with 30ml xylene. After the TMA addition was complete, the solution was stirred for about 10 minutes to complete the hydrolysis.
[0059] A...
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