Organic electroluminescent device comprising a polymer layer containing a polyimide having triphenylamine derivative unit
An electroluminescence and triphenylamine technology, applied in the field of organic electroluminescence devices, can solve the problem of difficulty in controlling the thickness of a thin conjugated polymer intermediate layer, and achieve excellent mechanical strength and thermal stability, good film forming performance, good Effects of Lifetime Characteristics
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[0071] Embodiment 1: the synthesis of compound (1)
[0072] Synthesis of N,N'-diphenyl-N,N'-bis(4-aminophenyl)-1,1-biphenyl-4,4'-diamine
[0073] In a 100mL three-necked flask, dissolve 1.56g 4,4'-dibromobiphenyl, 2.30g 4-nitrodiphenylamine, 1.44g tert-butoxide sodium and 0.51g tris(dibenzylidene) in 50mL p-xylene acetone) dipalladium, followed by adding 0.3 mL of tri-tert-butylphosphine to the resulting mixture, resulting in a reaction at about 150° C. in a nitrogen atmosphere for about 16 hours. After the reaction was completed, the resulting solution was filtered to remove solid matter, and dissolved in excess chloroform. The salt was filtered with distilled water, and the resulting solution was concentrated. Then, purification was carried out by column chromatography and recrystallization to obtain 1.2 g of powdery N,N'-diphenyl-N,N'-bis(4-nitrophenyl)-1,1-biphenyl - 4,4'-diamine. The obtained powder was dissolved in 50 mL of ethanol, 1.5 mL of hydrazine monohydrat...
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