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Mn-Zn ferrite material and its production tech.

A ferrite material and production process technology, applied in the field of ferrite materials, can solve the problems of large-scale industrial production difficulties, reduce production efficiency, increase overall cost, etc., achieve high saturation magnetic induction intensity and low hysteresis loss coefficient , than the effect of a smaller temperature coefficient

Active Publication Date: 2006-11-15
HENGDIAN GRP DMEGC MAGNETICS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For the MnZn ferrite material described in Chinese patent application 03115906.0, the Bs at 25°C reaches 520mT, but the Pcv at 100°C is 370kW / m 3 About, there is no power consumption value at 45-55°C
For the MnZn ferrite material described in Chinese patent application 03125523.x, the Pcv at 100°C is 280kW / m 3 around, but Bs and μ are not stated i The characteristics of magnetic parameters such as low Pcv alone cannot meet the requirements of miniaturization of devices
The material described in Chinese patent application 01112082.7, although the Pcv can be 230-260kW / m 3 between, but does not specify Bs and μ I Characteristics of other magnetic parameters
[0004] Chinese patent application 93114870.7 describes a method of improving the magnetic parameters such as magnetic permeability and Bs by finely grinding the sintered body, but it failed to achieve the ideal index after all, and the production cost was increased due to the long time of fine grinding , reducing production efficiency
For the MnZn ferrite described in Chinese patent application 02138280.8, although the Pcv drops to 240-260kW / m at 100°C 3 , Bs at 100°C reaches 410-430mT, but in this invention due to the addition of nano-scale Nb 2 o 5 、 Ta 2 o 5 , ZrO 2 , SnO 2 、TiO 2 , CaO and other auxiliary components increase the overall cost
This makes it difficult to realize large-scale industrial production, and limits the use of the ferrite
Although the Japanese patent application JP 2003-306376A discloses that the composition is similar to the composition of the present invention, but it contains a relatively high proportion of ZnO, resulting in that the high-temperature use properties of the ferrite cannot meet the needs

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0046] (1) Ingredients: ferric oxide (Fe 2 o 3 ) is 53.80 mol%, manganese oxide (MnO) is 40.10 mol%, and zinc oxide (ZnO) is 6.10 mol%. Subcomponents are expressed in weight percent, and the following oxides are added: CaO: 500ppm, Nb 2 o 5 : 200ppm, TiO 2 : 400ppm.

[0047] (2) Ball milling: dry strong mixing with a V-shaped mixer, and the mixing time is 0.7h;

[0048] (3) Vibration grinding: use a vibrating mill to vibrate and grind, and the vibration grinding time is 0.6h;

[0049] (4) Pre-burning: use an air kiln to directly pre-fire the powder, the temperature is 950 ° C, and the time is 2.5 hours;

[0050] (5) Sand milling: use a circulating sand mill for sand milling, the sand milling time is 2.5h; material: ball: water = 1:1:0.60; the average particle size of the powder after sand milling is 1.0-1.2 μm;

[0051] (6) Granulation: use a granulator for granulation, with an inlet temperature of 270°C and an outlet temperature of 130°C;

[0052] (7) Forming: It is c...

Embodiment 2

[0062] (1) Ingredients: ferric oxide (Fe 2 o 3 ) is 53.66 mol%, manganese oxide (MnO) is 40.34 mol%, and zinc oxide (ZnO) is 6.0 mol%. Subcomponents are expressed in weight percent, and the following oxides are added: CaO: 700ppm, Nb 2 o 5 : 200ppm, TiO 2 : 1500ppm.

[0063] (2) Ball milling: dry strong mixing with a V-shaped mixer, and the mixing time is 0.7h;

[0064] (3) Vibration grinding: use a vibrating mill to vibrate and grind, and the vibration grinding time is 0.6h;

[0065] (4) Pre-burning: use an air kiln to directly pre-fire the powder, the temperature is 950 ° C, and the time is 2.5 hours;

[0066] (5) Sand milling: use a circulating sand mill for sand milling, the sand milling time is 2.5h; material: ball: water = 1:1:0.60; the average particle size of the powder after sand milling is 1.0-1.2 μm;

[0067] (6) Granulation: use a granulator for granulation, with an inlet temperature of 270°C and an outlet temperature of 130°C;

[0068] (7) Forming: It is c...

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PUM

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Abstract

A Mn-Zn ferrite with low power consumption and high saturated magnetic flux density is prepared from iron oxide, zinc oxide, manganese oxide, calcium oxide, niobium oxide and titanium oxide through proportional mixing, ball grinding, vibration grinding, pre-calcining, sand grinding, granulating, shaping, sintering and grinding.

Description

technical field [0001] The invention relates to the technical field of ferrite materials, in particular to a Mn-Zn ferrite material with low power consumption and high saturation magnetic induction and a production process thereof. Background technique [0002] With the development of science and technology, people's living standards are improved, cars and computers are used more and more frequently, and families with cars are also rising sharply. The demand for magnetic core materials for automotive transformer coil products is great, and the requirements are gradually increasing. In order to To make it work under severe temperature conditions such as external temperature changes and engine room heating, it is required to maintain a high saturation magnetic flux density under high temperature conditions. Similarly, in order to be used under the high heating temperature conditions of liquid crystal displays, it is also required to maintain a high saturation magnetic flux den...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/26C04B35/622
Inventor 何时金邵顺中包大新金鑫
Owner HENGDIAN GRP DMEGC MAGNETICS CO LTD
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