Poly 4-methyl-1-pentene resin composition, film, and die for manufacturing electronic component seal
A technology of resin composition, pentene resin, which is applied to in-use molds to achieve the effect of good mold release, excellent heat resistance and mold release, and high value
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Embodiment 1
[0078] (Preparation of solid catalyst components)
[0079] 750g of anhydrous magnesium chloride, 2800g of decane and 3080g of 2-ethylhexanol were heated at 130°C for 3 hours to form a uniform solution, and then 220mL of 2-isobutyl-2-isopropyl was added to the solution Yl-1,3-dimethoxypropane, and then stirred and mixed at 100°C for 1 hour. The homogeneous solution thus obtained was cooled to room temperature, and then 3000 mL of the homogeneous solution was added dropwise to 800 mL of titanium tetrachloride kept at -20°C under stirring, and the addition was completed in 45 minutes. After the dripping was completed, the temperature of the mixed solution was increased to 110°C in 4.5 hours, and when it reached 110°C, 5.2 mL of 2-isobutyl-2-isopropyl-1,3-dimethoxypropane was added, And keep this temperature and stir for 2 hours. After the completion of the reaction for 2 hours, the solid part was collected by hot filtration, the solid part was resuspended in 1000 mL of titanium tetra...
Embodiment 2
[0087] Except for adjusting the polymerization amount of the first stage polymerization and the second stage polymerization so that the mass ratio of polymer (A) to polymer (B) is polymer (A) / polymer (B)=5 / 95, the same as in Example 1 The polymerization is carried out in the same manner, and the obtained powder is melt-kneaded to obtain pellets. The MFR of the obtained pellets was 25 g / 10 minutes. Then, the film was formed, and the evaluation results of the physical properties of the film are shown in Table 1.
Embodiment 3
[0089] Except for adjusting the polymerization amount of the first stage polymerization and the second stage polymerization, so that the mass ratio of polymer (A) to polymer (B) is polymer (A) / polymer (B)=50 / 50, the same as in Example 1. The polymerization is carried out in the same manner, and the obtained powder is melt-kneaded to obtain pellets. The MFR of the obtained pellets was 25 g / 10 minutes. Then, the film was formed, and the evaluation results of the physical properties of the film are shown in Table 1.
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