Surface corrosion protection detergent compositions containing polyvalent metal compounds and high levels of low foaming, nonionic surfactants

Abstract

Automatic dishwashing detergent compositions and compositions of matter, having polyvalent metal compounds and high levels of low-foaming, nonionic surfactants, are provided for protecting glassware from corrosion.

Description

CROSS REFERENCE TO RELATED APPLICATION [0001] This application claims the benefit of U.S. Provisional Application No. 60 / 613,695, filed Sep. 28, 2004.FIELD OF THE INVENTION [0002] The present invention relates to protecting glassware surfaces from corrosion using automatic dishwashing detergent compositions. More particularly, the present invention relates to automatic dishwashing detergent compositions and compositions of matter, having polyvalent metal compounds and high levels of low-foaming, nonionic surfactants. BACKGROUND [0003] Most consumers agree that the corrosion of glassware from use of detergent compositions in automatic dishwashing (ADW) is one of their most serious unmet needs. The current consensus amongst manufacturers is that the glassware corrosion problem occurs during the washing cycle of an automatic dishwashing appliance and may be the result of two separate phenomena acting-silica hydrolysis and metal ion leaching. Iridescence and clouding of glassware surfac...

AI Technical Summary

Benefits of technology

[0074] Suitable particle sizes may range from about 10 micron to about 2000 microns. Alternatively, suitable particle sizes may range from about 100 microns to about 1500 microns, from about 200 microns

Problems solved by technology

The current consensus amongst manufacturers is that the glassware corrosion problem occurs during the washing cycle of an automatic dishwashing appliance and may be the result of two separate phenomena acting-silica hydrolysis and metal ion leaching.

Glassware surface damage also results when chelate / metal ions on the glassware surface are removed during the wash cycle by the presence of a builder in the wash liquor.

The removal of chelate / metal ions causes the surface to become less durable and less chemically resistant.

After several wash cycles in an ADW appliance, both phenomena can cause visible, unwanted damage to glassware in the form of cloudiness, abrasions, scratches, and streaks.

Although some manufacturers have tried to overcome these problems with the inclusion of corrosion protection agents in their ADW detergent compositions, the use of corrosion protection agents (such as, insoluble metal ions) may result in a number of manufacturing drawbacks.

These include: (a) an increased cost of manufacture; (b) the need for higher salt level formulations; (c) the thinning of gel detergent compositions by metal ion interactions with thickener materials; and (d) the reduction of cleaning performance for certain stains (e.g. tea) generated by negative interactions of the metal ions with bleach during the wash cycle.

Although some ADW detergent compositions containing metal ions and low levels of nonionic surfactants are known, the levels of these nonionic surfactants have been limited to less than 8% by weight of the composition.

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