Double-sided pressure-sensitive adhesive tape or sheet for wiring circuit board and wiring circuit board

a technology of pressure-sensitive adhesive tape and wiring circuit board, which is applied in the direction of film/foil adhesives without carriers, laminating printed circuit boards, natural mineral layered products, etc. it can solve the problems of deficient pressure-sensitive adhesive layer, low working ability, and inability to fine-perforation processes, etc., to suppress or prevent the self-adhesion of the cut surface, good adhesiveness, excellent anti-repulsion

Inactive Publication Date: 2009-04-16
NITTO DENKO CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0006]Accordingly, an object of the present invention is to provide a double-sided pressure-sensitive adhesive tape or sheet for wiring circuit board, which has an electrically conducting property. Another object of the present invention is to provide a double-sided pressure-sensitive adhesive tape or sheet for wiring circuit board, which has a high adhesiveness as well as an excellent anti-repulsion property even being subjected to a high-temperature step. Further, another object of the present invention is to provide a double-sided pressure-sensitive adhesive tape or sheet for wiring circuit board, which is able to suppress or prevent the self-adhesion of the cut surfaces after a cutting process and has an excellent fine processing property. Further, another object of the present invention is to provide a wiring circuit board in which the double-sided pressure-sensitive adhesive tape or sheet for wiring circuit board is used.
[0007]In order to achieve the above-mentioned objects, the present inventors have carried out intensive investigations and found that, when a pressure-sensitive adhesive layer is formed by a pressure-sensitive adhesive composition which contains an acrylic polymer as a base polymer and an electrically conductive filler in a specific amount, the double-sided pressure-sensitive adhesive tape or sheet suitably used for a wiring circuit board, which has a good adhesiveness to a wiring circuit board and reinforcing plate and exerts an electrically conducting property, can be obtained. Further, the present inventors have found that, when a solvent-insoluble fraction of the pressure-sensitive adhesive layer in the initial stage and a solvent-insoluble fraction after a solder reflow step under specific heat treatment conditions with respect to the solvent-insoluble fraction in the initial stage are adjusted to a specific range, an excellent anti-repulsion property can be achieved even being subjected to a high-temperature step by a solder reflow step and thus a good adhesiveness can be retained even when used to the part where repulsion takes place. Further, the present inventors have found that, when the tape has the above-mentioned specific pressure-sensitive adhesive layers on both surfaces of a substrate, the self-adhesion of the cut surfaces after a cutting process is suppressed or prevented and thus fine processing property is improved. The present invention has been accomplished based on these findings.
[0031]Since the double-sided pressure-sensitive adhesive tape or sheet for wiring circuit board according to the present invention has the above-mentioned constitution so as to have an electrically conducting property, it is useful for removing static electricity of the wiring circuit board. Further, it has a good adhesiveness and, even after being subjected to a high-temperature step, it can exert an excellent anti-repulsion property. Further, it is possible to suppress or prevent the self-adhesion of the cut surfaces after a cutting process and it is also excellent in fine processing property.

Problems solved by technology

However, since the double-sided pressure-sensitive adhesive tape or sheet without substrate has no substrate, it is not suitable for fine perforating process.
Moreover, there is a problem in the conventional double-sided pressure-sensitive adhesive tape or sheet that, especially under the conditions of high temperature and high humidity, the cut surfaces are adhered again (self-adhesion) after being perforated whereby working ability lowers.
Further, in the worst case, it sometimes happens that, in detaching the perforated product, a part where a pressure-sensitive adhesive layer is deficient is resulted.
Although it has been attempted that, in the pressure-sensitive adhesive layer, matters insoluble in a solvent are increased for preventing the self-adhesion of the cut surfaces (refer to JP-A-2001-40301), there is a problem that, when the matters insoluble in a solvent are increased, the pressure-sensitive adhesive layer is peeled off from the adherend when it is adhered to a part of the adherend on which repulsive force it applied.
On the other hand, in wiring circuit board such as FPC, there are some cases where a high-temperature step such as a solder reflow step is conducted but, when the pressure-sensitive adhesive layer is adhered to a part of an adherend on which a repulsive force is applied after the solder reflow step, a problem that the pressure-sensitive adhesive layer is peeled off from the adherend arises in some cases.

Method used

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  • Double-sided pressure-sensitive adhesive tape or sheet for wiring circuit board and wiring circuit board
  • Double-sided pressure-sensitive adhesive tape or sheet for wiring circuit board and wiring circuit board
  • Double-sided pressure-sensitive adhesive tape or sheet for wiring circuit board and wiring circuit board

Examples

Experimental program
Comparison scheme
Effect test

example 1

[0209]In 210 parts by weight of ethyl acetate, 90 parts by weight of 2-ethylhexyl acrylate and 10 parts by weight of acrylic acid were subjected to a solution polymerization treatment by stirring at 60 to 80° C. in the presence of 0.4 part by weight of 2,2′-azobisisobutyronitrile under substitution with nitrogen, to prepare an acrylic polymer solution (viscosity: about 120 poises; degree of polymerization: 99.2%; solid: 30.0% by weight).

[0210]With respect to 100 parts by weight (solid) of this acrylic polymer solution, 35 parts by weight of nickel filler (trade name: “4SP-400”, produced by NOVAMET Specialty Products Corp.) as an electrically conductive filler, 20 parts by weight of terephenol resin as a tackifier resin having chain transfer property (trade name: “YS POLYSTER S145”, softening point: 145° C., produced by YASUHARA CHEMICAL CO.,LTD.), 0.05 parts by weight of a multifunctional epoxy-type cross linking agent (trade name: TETRAD-C, produced by MITSUBISHI GAS CHEMICAL COMPA...

example 2

[0212]Using the same pressure-sensitive adhesive composition as in Example 1, a pressure-sensitive adhesive layer of a thickness of 16 μm was formed on each of both surfaces of a copper thin film having a thickness of 18 μm (produced by FUKUDA METAL FOIL & POWDER Co., LTD.) in the same manner as in Example 1, whereby a double-sided pressure-sensitive adhesive tape or sheet where the total thickness was 50 μm was prepared.

example 3

[0213]Using the same adhesive composition as in Example 1, a pressure-sensitive adhesive layer of a thickness of 50 μm was formed on the same release liner as in Example 1, whereby a double-sided pressure-sensitive adhesive tape or sheet having no substrate where the total thickness (thickness from one surface of the pressure-sensitive adhesive layer to the other surface of the pressure-sensitive adhesive layer) was 50 μm was prepared.

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Abstract

The present invention provides a double-sided pressure-sensitive adhesive tape or sheet for wiring circuit board, which includes a pressure-sensitive adhesive layer formed by a pressure-sensitive adhesive composition, wherein the pressure-sensitive adhesive composition contains an acrylic polymer as a main component and further contains an electrically conductive filler in a proportion of 5 to 100 parts by weight with respect to 100 parts by weight of a total solid in the pressure-sensitive adhesive composition except the electrically conductive filler. The double-sided pressure-sensitive adhesive tape or sheet is excellent in adhesiveness, electrically conducting property and anti-repulsion property, and thus can be advantageously used for wiring circuit board.

Description

FIELD OF THE INVENTION[0001]The present invention relates to a double-sided pressure-sensitive adhesive tape or sheet for wiring circuit board and a wiring circuit board.BACKGROUND OF THE INVENTION[0002]In electronic instruments, wiring circuit boards are used and, with regard to the wiring circuit board, a flexible printed circuit board (may be sometimes called “FPC”) has been widely used. Usually, wiring circuit boards such as FPC are used in a state of being adhered to a reinforcing plate (such as aluminum plate, stainless steel plate or polyimide plate) and, at that time, a double-sided pressure-sensitive adhesive tape or sheet (double-sided pressure-sensitive adhesive tape or sheet for wiring circuit board) is used. With regard to such a double-sided pressure-sensitive adhesive tape or sheet, a double-sided pressure-sensitive adhesive tape or sheet having a constitution of being formed only by adhesive layers (so-called “double-sided pressure-sensitive adhesive tape or sheet wi...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): H05K1/02B32B19/04C09J7/10
CPCC08K3/04Y10T428/24909C08K5/13C08K5/37C09J7/00C09J7/0217C09J7/045C09J9/02C09J11/04C09J11/06C09J11/08C09J133/02C09J2203/326C09J2205/102C09J2400/263C09J2433/00H05K3/0058C08K3/08C09J7/38C09J7/385C09J7/21C09J7/10C09J2301/408H05K3/20
Inventor NONAKA, TAKAHIRODAIGAKU, NORITSUGUNAKAYAMA, JUNICHI
Owner NITTO DENKO CORP
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