Solutions of silicon metal and methods of making and using same
a technology of silicon metal and solutions, applied in the field of formulation, can solve the problems of unstable and inferior solutions in quality and character, inability to provide silicon in aqueous medium, and inability to meet the requirements of methods, so as to improve the oil recovery and increase the oil percentage
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example 1
The Preparation of the Stable, Aqueous Silicon Solution ERA-3
[0133]The stable, aqueous silicon solution ERA-3 was produced as follows:
[0134]a vessel having cone shaped bottom and containing commercially available base rock (approximately 97% pure) was provided;
[0135]water was place into the tank in such a manner as to provide intimate contact with the rock; NaOH solution was gradually added to the rock and water through the bottom of the vessel, thereby forming a reaction mixture; the reaction was allowed to run; the still hot solution was offloaded to a settling tank and the solution was allowed to settle; the solution was moved to a second settling tank for 10 days and then moved the to a bulk storage tank, which was open to sun light. The ratio of NaOH to silicon to water was 1:6:10. The resulting solution stable, aqueous, silicon solution, ERA-3, has been shown to have a SiO2:Na2O ratio of 3.94:1. ERA-3 has also been shown to be significantly less corrosive than silicon solution...
example 2
Comparison of Oil and Sand Separation Properties of ERA-3 to Another Commercially Available Product
[0136]ERA-3, a stable, aqueous silicon solution produced in accordance with the instant invention and having a SiO2:Na2O ratio of 3.94:1 was compared to the commercially available solution sodium disilicate solution PQ “N”, which has a SiO2:Na2O ratio of 3.33:1.
[0137]Equipment and materials used were as follows:
[0138]Syracuse tap water at 55° C.
[0139]Disposable 800 ml polypropylene sample beakers
[0140]A 1500 ml container set on a hot plate, for use as a constant temperature water bath.
[0141]An adjustable ring clamp
[0142]A Gerald Heller Co. type 150, 1 / 60 horsepower DC motor with variable speed control fitted with two mixing blades.
[0143]Kolorscope white playsand
[0144]SAE ND 30 motor oil
[0145]ERA-3
[0146]PQ “N”
[0147]Analyses were performed by Environmental Lab Services, North Syracuse, a New York State Department of Health certified analytical laboratory, according to the current EPA pro...
example 3
Oil Recovery Potential
[0163]Tests were performed to determine the oil recovery potential of the silicon solutions of the present invention. The tests were carried out in a flotation cell in a process modeled after actual water flooding used for bitumen recovery from the Athabaska tar sands. The tests were carried out in a 1-liter Denver flotation cell. 300 g of Aurora transition oil sand ore* was dispersed with 950 ml of 1.5% aqueous silicon solution at 50° C. under agitation of 1500 rpm. After slurry was conditioned for 5 minutes, the aeration was started. The bitumen froth was then collected for 15 minutes. The collected sample was then assayed. For the purpose of comparison, the same procedure was taken for a flotation using de-ionized (DI) water and tap water. TABLE 2 shows the results of the test.
TABLE 2Tests Recovery Grade Bitumen / Solid 1.5% Silicon solution78 21 2.1 DI water 92 8 0.5 Tap water 93 6.6 0.6TestsRecoveryGradeBitumen / Solid1.5% Silicon solution78212.1DI water9280.5...
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