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Methods and apparatus for controlling water hardness

Inactive Publication Date: 2010-10-21
ECOLAB USA INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0011]In still yet other aspects, the present invention relates to methods for reducing scale formation in an aqueous system comprising contacting the aqueous system with a composition consisting essentially of a substantially water insoluble resin material loaded with a plurality of multivalent cations, such that scale formation in the aqueous system is reduced.

Problems solved by technology

Hard water is known to reduce the efficacy of detergents, by forming films on surfaces, and reacting with detergent components making them less functional in the cleaning process.
Calcium is a divalent ion known to bind soils to surfaces, creating a film, and a making the soil more difficult to remove.
However, in many instances the water hardness exceeds the chelating capacity of the composition.
As a result, free calcium ions may be available to attack active components of the composition, to cause corrosion or precipitation, or to cause other deleterious effects, such as poor cleaning effectiveness or lime scale build up.
Further, chelators and sequestrants (e.g., phosphates and NTA) have been found to cause environmental or health issues.
When water softeners regenerate they produce a waste stream that contains significant amounts of chloride, including calcium and magnesium salts, creating a burden on the system, e.g., sewer system, in which they are disposed of, including a multitude of downstream water re-use applications like potable water usages and agriculture.
Further, traditional water softeners add to the salt content in discharge surface waters, which has become an environmental issue in certain locations.

Method used

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  • Methods and apparatus for controlling water hardness
  • Methods and apparatus for controlling water hardness
  • Methods and apparatus for controlling water hardness

Examples

Experimental program
Comparison scheme
Effect test

example 1

[0106]Three 1 pound resin samples were prepared by loading them with H+, Ca++, and Mg++. The magnesium loaded sample was prepared according to the following procedure. A weak acid cation resin, Lewatit S 8528 obtained from the Lanxess Company, was soaked is 500 grams of NaOH beads and 2500 ml of softened water for 24 hours. The pH was approximately 12-13. After soaking, the resin was then rinsed thoroughly with softened water three times until the pH of the rinse water was below 11. The resin was soaked in 2500 ml of softened water with 700 grams of a MgCl2.6H20 composition for 4 days.

[0107]The resin was thoroughly rinsed with softened water three times. The final pH of the rinse water was approximately 7.5-8.5.

[0108]To load the resin with Ca++, the same procedure was used as described above for the MG++ resin, only the resin was soaked with CaCl2 composition. The H+ form of the resin, was the resin itself, without any cations loaded onto it.

[0109]Water was then treated with each of...

example 2

[0112]Water with 17 grains of water hardness was treated with two pounds of Watts OneFlow media, commercially available from Watts, at a rate of about 5 gallons per minute. In addition, water with 17 grains of water hardness was treated with a magnesium loaded weak acid resin according to the present invention at the same conditions. An alkalinity source including 800 ppm of sodium carbonate was added to each of these water samples, as well as to a control sample of untreated water. The results are shown in FIG. 3. As can be seen from this Figure, both the control and the Watts treated water had a signification precipitation of water hardness. The water treated according to the present invention (shown as the right most beaker) showed no signs of a precipitate.

example 3

[0113]A test was run to measure the limescale build up control using various commercially available water treatment materials. Two separate tests were run. The first test was a 100 cycle dishmachine test. A door type dishmachine (Hobart AM-15) was used. The selected test apparatus was connected to the inlet water to the dishmachine so that all of the rinse water for the machine was treated. The inlet water had a hardness of 17 grains. Glassware was placed inside the dishmachine in a glassware rack. The machine was run normally for 100 cycles. No chemicals, e.g., detergents, rinse aids, other than the treatment apparatuses were used in this test. After the 100 cycles were complete, the glassware was removed and allowed to air dry. Photos of the glasses were taken. A light box was used to determine reflectance which is a direct correlation to the amount of scale present. The photos and light box scores were compared for the different water treatments tested. A light box score differin...

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Abstract

The present invention is related to methods, apparatuses, and compositions for controlling water hardness. The methods, apparatuses and compositions also reduce scale formation. The present invention includes substantially water insoluble resin materials. The resin materials may be loaded with a plurality of cations.

Description

RELATED APPLICATIONS[0001]This application claims priority and is related to U.S. Provisional Application Ser. No. 61 / 261,610 filed on Nov. 16, 2009 and entitled “Methods and Apparatus for Controlling Water Hardness.” The entire contents of this patent application are hereby expressly incorporated herein by reference including, without limitation, the specification, claims, and abstract, as well as any figures, tables, or drawings thereof.[0002]This application also claims priority and is related to U.S. Provisional Application Ser. No. 61 / 171,145 filed on Apr. 21, 2009 and entitled “Catalytic Water Treatment Method and Apparatus.” The entire contents of this patent application are hereby expressly incorporated herein by reference including, without limitation, the specification, claims, and abstract, as well as any figures, tables, or drawings thereof.[0003]This application is also related to U.S. patent application Ser. No. ______ (Attorney Docket Number 2580USU1), entitled “Catal...

Claims

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Application Information

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IPC IPC(8): C02F1/42C02F1/02B08B3/04C02F5/10
CPCC02F1/42C02F1/5236E03B7/074C02F2201/006C02F1/725C02F2001/425C02F5/02C02F5/10C02F2303/22
Inventor MONSRUD, LEE J.SUN, XINMILLS, KRISTEN A.PRIDEAUX, DOUGLAS J.BENSON, BETH E.SMITH, KIM R.OLSON, KEITH E.
Owner ECOLAB USA INC
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