Photosensitive coating resin of auxiliary plates for drilling and application thereof
a technology of coating resin and auxiliary plates, applied in the field of resin composition, can solve the problems of lubricating resin coated on the cover having problems such as flowing over, residue, or even blocking holes, and drilling holes tipped,
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example 1
[0028]One mole of polyether amine (Huntsman JEFFAMINE® D-4000) is mixed with 1 mole of 1,2,4,5-Benzenetetracarboxylic dianhydride, and the mixture reacts at 20° C. for 12 hours to form the first polymer of formula (I), in which the reaction is shown as follows:
[0029]wherein n is an integer from 2 to 100, and m is an integer from 1 to 1000.
[0030]In addition, 1 moles of polyether amine (Huntsman JEFFAMINE® D-4000) and 2 mole of vinyl chloride react at 20° C. for 12 hours to form the second polymer of formula (II), in which the reaction is shown as follows:
[0031]wherein o is an integer from 2 to 100.
[0032]One unit of the first polymer of formula (I) and 1 unit of the second polymer of formula (II) are further mixed well with 3% of photoinitiator (1173) and 1% of photosensitizer (ITX) based on the second polymer to produce the resin composition of the present invention. Fifty micrometers in thickness of the resin composition is directly coated on aluminum foil (material: A1N30) with 100...
example 2
[0034]The first polymer of formula (I) and the second polymer of formula (II) are polymerized by the method of Example 1, and the product is coated and drilled under the same condition as Example 1. The composition comprises polymers of formula (I) and formula (II), wherein the proportion of the polymer of formula (I) and the polymer of formula (II) is 1:2, and the drilling auxiliary plate is made under the same condition of photoreaction as Example 1. The drilling results are shown in Table 1.
example 3
[0035]The polymers of formula (I) and formula (II) are polymerized by the method of Example 1, and the product is coated and drilled under the same condition as Example 1. The composition comprises polymers of formula (I) and formula (II), wherein the proportion of the polymer of formula (I) and the polymer of formula (II) is 2:1, and the drilling auxiliary plate is made under the same condition of photoreaction as Example 1. The drilling results are shown in Table 1.
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