Method for semiconductor selective etching and bsi image sensor
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example 1
[0042]1. Etching Solution Preparation
[0043]A P-type silicon substrate is provided. The silicon substrate has a resistivity in the range of 0.006 to 0.01 Ω·cm and is doped with a doping concentration higher than 1×1018 atoms / cm3. The silicon substrate is then submitted to marking, cleaning, back-grinding, flipping, chemical mechanical polishing, and the like. An HNA solution is sprayed onto the silicon substrate and evenly distributed on the surface of the silicon substrate through a low rotation speed (3, and CH3COOH in a volume ratio of 1:3:8, the mass concentration percentage of HF is 49%, the mass concentration percentage of HNO3 is 70%, and the mass concentration percentage of CH3COOH is 100%.
[0044]During the rotation, the proportion of HNO2 in the HNA solution gradually increases. The etching process stops when the etch rate reaches a stable value, and an etching solution is obtained from the HNA solution. A process for determining the etch rate can include measuring the thickn...
example 2
[0054]1. Etching Solution Preparation
[0055]A P-type silicon substrate is provided. The silicon substrate has a resistivity in the range of 0.01 to 0.02 Ω·cm and is doped with a doping concentration higher than 1×1017 atoms / cm3. The silicon substrate is then submitted to marking, cleaning, back-grinding, flipping, chemical mechanical polishing, and the like. An HNA solution is sprayed onto the silicon substrate and evenly distributed on the surface of the silicon substrate through a low rotation speed (3, and CH3COOH in a volume ratio of 5:1:4, the mass concentration percentage of HF is 49%, the mass concentration percentage of HNO3 is 70%, and the mass concentration percentage of CH3COOH is 100%. The etch rate can be determined using the same processes as described in Example 1 above and are denoted S3.
[0056]2. Testing the Etch Rate of the Etching Solution
[0057]The etch rates of the etching solution are measured using the same P-type silicon substrates. The P-type silicon substrates...
example 3
[0066]1. Etching Solution Preparation
[0067]An N-type silicon substrate is provided. The N-type silicon substrate has a resistivity in the range of 0.05 to 0.08 Ω·cm and is doped with a doping concentration higher than 1×1016 atoms / cm3. The N-type silicon substrate is then submitted to marking, cleaning, back-grinding, flipping, chemical mechanical polishing, and the like. An HNA solution is sprayed onto the silicon substrate and evenly distributed on the surface of the silicon substrate through a low rotation speed (3, and CH3COOH in a volume ratio of 3:5:2, the mass concentration percentage of HF is 30%, the mass concentration percentage of HNO3 is 60%, and the mass concentration percentage of CH3COOH is 80%. The etch rate can be determined using the same processes as described in Example 1 above and are denoted S5.
[0068]2. Testing the Etch Rate of the Etching Solution
[0069]The etch rates of the etching solution are measured using same N-type silicon substrates. The N-type silicon ...
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