Method of forming electrically and thermally conductive polyolefin-perovskite nanomaterial composites having increased dielectric permittivity and breakdown-induced electrical and thermal conduction pathways
a technology of polyolefin and perovskite, which is applied in the direction of metal/metal-oxide/metal-hydroxide catalysts, chemical/physical processes, and chemical production of bulk chemical products, etc., can solve the problems of low electrical and thermal conductivity and disadvantageous other applications, and achieves the effect of increasing the dielectric permittivity
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[0068]Preparation of the Composite Block
[0069]A polyethylene / barium titanate nanoparticle composite was prepared by a ball milling process. First, barium titanate nanoparticles were manually premixed into polyethylene powder. The mixture consisted of 97 wt % of polyethylene with 3 wt % of barium titanate nanoparticles. The polyethylene was an additive free, low density polyethylene (LDPE) powder having a density of 0.922 g / cm3, melt flow index of 0.4 g / 10 min and a typical particle size distribution with 95% of particles less than 500 μm, purchased from Marplex Australia. The powder mixture was then ball milled in a high-energy shaker mill. Milling was performed in a zirconium oxide crucible with a weight ratio of balls to powder mixture of 10:1. Milling was performed in air at ambient temperature (23° C.) at a rotation rate of 1050 to 2000 rpm. Total milling time was 40 minutes. The obtained nanocomposites powder was press-molded to form thin blocks using a hot press and then, a sh...
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