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Method of forming electrically and thermally conductive polyolefin-perovskite nanomaterial composites having increased dielectric permittivity and breakdown-induced electrical and thermal conduction pathways

a technology of polyolefin and perovskite, which is applied in the direction of metal/metal-oxide/metal-hydroxide catalysts, chemical/physical processes, and chemical production of bulk chemical products, etc., can solve the problems of low electrical and thermal conductivity and disadvantageous other applications, and achieves the effect of increasing the dielectric permittivity

Active Publication Date: 2021-09-30
PRINCE MOHAMMAD BIN FAHD UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The method results in a composite with enhanced thermal conductivity, electrical conductivity, and dielectric permittivity, suitable for electronics applications without compromising flexibility and toughness, by forming dendritic conductive channels within the polyolefin matrix.

Problems solved by technology

The same low electrical and thermal conductivity, however, is disadvantageous for use in certain electronics applications where higher values of these properties are desirable.
While the decrease in the dielectric permittivity may be advantageous for creating a highly insulating polyolefin material for insulating applications, this lower dielectric permittivity may be disadvantageous for other applications.

Method used

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  • Method of forming electrically and thermally conductive polyolefin-perovskite nanomaterial composites having increased dielectric permittivity and breakdown-induced electrical and thermal conduction pathways
  • Method of forming electrically and thermally conductive polyolefin-perovskite nanomaterial composites having increased dielectric permittivity and breakdown-induced electrical and thermal conduction pathways
  • Method of forming electrically and thermally conductive polyolefin-perovskite nanomaterial composites having increased dielectric permittivity and breakdown-induced electrical and thermal conduction pathways

Examples

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examples

[0068]Preparation of the Composite Block

[0069]A polyethylene / barium titanate nanoparticle composite was prepared by a ball milling process. First, barium titanate nanoparticles were manually premixed into polyethylene powder. The mixture consisted of 97 wt % of polyethylene with 3 wt % of barium titanate nanoparticles. The polyethylene was an additive free, low density polyethylene (LDPE) powder having a density of 0.922 g / cm3, melt flow index of 0.4 g / 10 min and a typical particle size distribution with 95% of particles less than 500 μm, purchased from Marplex Australia. The powder mixture was then ball milled in a high-energy shaker mill. Milling was performed in a zirconium oxide crucible with a weight ratio of balls to powder mixture of 10:1. Milling was performed in air at ambient temperature (23° C.) at a rotation rate of 1050 to 2000 rpm. Total milling time was 40 minutes. The obtained nanocomposites powder was press-molded to form thin blocks using a hot press and then, a sh...

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Abstract

A method of forming a polyolefin-perovskite nanomaterial composite which contains oriented electrically and thermally conductive pathways. The method involves milling a polyolefin with particles of a perovskite nanomaterial, molding to form a composite plate, and subjecting the composite plate to an AC voltage. The AC voltage forms oriented electrically and thermally conductive pathways by partial dielectric breakdown of the composite. The presence of the oriented electrically and thermally conductive pathways gives the polyolefin-perovskite nanomaterial electrical and thermal conductivity and dielectric permittivity higher than the polyolefin alone.

Description

BACKGROUND OF THE INVENTIONTechnical Field[0001]The present invention relates to a method of preparing a polyolefin-perovskite nanomaterial composite utilizing application of an AC voltage, and a polyolefin-perovskite nanomaterial composite made by the method, optionally having oriented electrically and thermally conductive pathways.Description of the Related Art[0002]The “background” description provided herein is for the purpose of generally presenting the context of the disclosure. Work of the presently named inventors, to the extent it is described in this background section, as well as aspects of the description which may not otherwise qualify as prior art at the time of filing, are neither expressly or impliedly admitted as prior art against the present invention.[0003]Polyolefins have a number of properties that are advantageous for applications in a wide variety of products and industries such as consumer goods, packaging, medical products, and safety equipment. Specifically...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C08L23/06B29C43/00B29C71/00
CPCC08L23/06B29C43/003C08K2003/2237C08L2207/066C08K2201/005B29C71/0081B29C70/882B29C35/12B29K2033/00B29K2509/02C08L23/04C04B35/495C04B2235/3251C04B2235/3215C04B2235/3284C04B2235/3213C04B2235/3298C04B2235/3201C04B2235/3227C08K3/34C08K3/24B29K2995/0006B29C43/006B29K2105/16B29K2223/0616B29K2995/0005B29K2995/0013B29C43/58B29C2043/5808B29C2043/5816Y02P20/52C08L23/00C08L2203/20B82Y40/00B29C67/243B29C70/58B29C59/10Y10S502/525B01J23/002C01P2002/34C04B35/462B29K2023/0633B29K2509/00B82Y30/00C04B35/465C04B35/4682
Inventor ZAZOUM, BOUCHAIB
Owner PRINCE MOHAMMAD BIN FAHD UNIV