The invention discloses gold vinegar pearlescent 
shampoo milk which comprises the raw materials with the weight mixture ratio: 8-11.5 parts of gold vinegar, 1.9-2.2 parts of 
serine, 0.9-1.2 parts of 
threonine, 0.9-1.2 parts of 
leucine, 0.9-1.2 parts of mature vinegar ferment, 1.4-1.7 parts of docosyl trimethyl 
ammonium chloride, 10-20 parts of AES, 3.5-7 of 6502, 0.5-1.2 parts of polysiloxane cation 
protein, 0.4-1.1 parts of CB 
Climbazole, 0.5-0.9 parts of essence, 0.1-0.4 parts of JM-115, 0.1-0.4 parts of 
vitamin C, 0.1-0.4 parts of 
vitamin B1, 0.1-0.4 parts of 
vitamin E and 55-65 parts of de-ionized water. The preparation method of the gold vinegar pearlescent 
shampoo milk is as follows: purifying gold vinegar, 
amino acid, functional mixed elements, emulsification, pearliztion, homogenizing, desaeration, blending of favor, and can pack. The milk of the invention fills domestic blank, not only fully excavates the efficacies of 
hair care, moistening hair, hair growing, relieving 
itching of Shanxi mature vinegar of country vinegar, but also further extracts the 
nutrient content of compound 
amino acid and ferment to prepare a 
shampoo and 
hair care product with top quality which is 
safer, more efficient, more natural and more environmentally and integrates the functions of shampoo, hair-care, conditioning, relieving 
itching and anti-losing hair into a whole.