The invention discloses gold vinegar pearlescent shampoo milk which comprises the raw materials with the weight mixture ratio: 8-11.5 parts of gold vinegar, 1.9-2.2 parts of serine, 0.9-1.2 parts of threonine, 0.9-1.2 parts of leucine, 0.9-1.2 parts of mature vinegar ferment, 1.4-1.7 parts of docosyl trimethyl ammonium chloride, 10-20 parts of AES, 3.5-7 of 6502, 0.5-1.2 parts of polysiloxane cation protein, 0.4-1.1 parts of CB Climbazole, 0.5-0.9 parts of essence, 0.1-0.4 parts of JM-115, 0.1-0.4 parts of vitamin C, 0.1-0.4 parts of vitamin B1, 0.1-0.4 parts of vitamin E and 55-65 parts of de-ionized water. The preparation method of the gold vinegar pearlescent shampoo milk is as follows: purifying gold vinegar, amino acid, functional mixed elements, emulsification, pearliztion, homogenizing, desaeration, blending of favor, and can pack. The milk of the invention fills domestic blank, not only fully excavates the efficacies of hair care, moistening hair, hair growing, relieving itching of Shanxi mature vinegar of country vinegar, but also further extracts the nutrient content of compound amino acid and ferment to prepare a shampoo and hair care product with top quality which is safer, more efficient, more natural and more environmentally and integrates the functions of shampoo, hair-care, conditioning, relieving itching and anti-losing hair into a whole.