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Inner-component for enhancing air-solid contact of catalytic cracking reaction system

A technology of reaction system and gas-solid contact, which is applied in catalytic cracking, cracking, petroleum industry, etc., can solve the problems of reaction influence, energy consumption and increased operation difficulty, so as to improve product properties, increase gas-solid contact efficiency, reduce The effect of resistance

Active Publication Date: 2008-12-17
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the disadvantage of this method is that the fast bed is always required to maintain a high dense-phase bed material level, which will lead to a corresponding increase in energy consumption and operational difficulty; Will enter the Tubular Cone Reactor, thereby affecting the reaction inside the Tubular Cone Reactor

Method used

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  • Inner-component for enhancing air-solid contact of catalytic cracking reaction system
  • Inner-component for enhancing air-solid contact of catalytic cracking reaction system
  • Inner-component for enhancing air-solid contact of catalytic cracking reaction system

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0048] This example illustrates the process of using the catalytic cracking of the present invention to produce low-olefin gasoline in a medium-sized variable-diameter riser reactor.

[0049] The total height of the pre-lift section, the first reaction zone, the second reaction zone (lower gas phase linear velocity zone) and the outlet zone of the riser reactor is 15 meters. The diameter of the pre-lift section is 0.22 meters and its height is 1.5 meters; the diameter of the first reaction zone is 0.25 meters and its height is 4 meters; the diameter of the second reaction zone is 1 meter and its height is 6.5 meters; the diameter of the exit zone is 0.25 meters , Its height is 3 meters; The vertex angle of the isosceles trapezoid of the vertical section of the first and second reaction zone junction is 45 °; The bottom angle of the isosceles trapezoid of the longitudinal section of the second reaction zone and the outlet zone junction is 60 °.

[0050] The diameter of the dist...

Embodiment 2

[0057] This example illustrates that the present invention is implemented on a variable-diameter riser reactor, and the total height of the reactor can be reduced under the premise of ensuring the reduction of olefin content in gasoline.

[0058] The total height of the pre-lift section, the first reaction zone, the second reaction zone (lower gas phase linear velocity zone) and the outlet zone of the riser reactor is 14.5 meters. The diameter of the pre-lift section is 0.22 meters, and its height is 1.5 meters; the diameter of the first reaction zone is 0.25 meters, and its height is 4 meters; the diameter of the second reaction zone is 1 meter, and its height is 6.0 meters; the diameter of the exit zone is 0.25 meters , Its height is 3 meters; The vertex angle of the isosceles trapezoid of the vertical section of the first and second reaction zone junction is 45 °; The bottom angle of the isosceles trapezoid of the longitudinal section of the second reaction zone and the outl...

Embodiment 3

[0064] This example illustrates the process of producing low-olefin gasoline by catalytic cracking when the present invention is implemented on a variable-diameter riser reactor, and water is used as the cooling medium on the shell side of the inner member in the reaction zone with a relatively low linear velocity.

[0065] The variable-diameter riser reactor used in this example is completely equivalent to the reactor in Example 1. The slight difference in operation is that the shell side of the reaction zone with a lower linear velocity uses water as the cooling medium to reduce the temperature of the reaction zone.

[0066] The catalyst used in this embodiment and the stock oil are the same as in Example 1.

[0067] The operating conditions and product distribution are listed in Table 5, and the properties of the gasoline are listed in Table 6. As can be seen from Table 5, the total liquid yield was 86.61% by weight. As can be seen from Table 6, the olefin content in gaso...

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Abstract

An internal member used to enhance the gas-solid contact of the catalytic cracking reaction system, which is composed of a distribution plate located at both ends of the low linear velocity reaction zone and a tube bundle between the distribution plates. The reaction zone is divided into a tube side and a shell side, of which two There are several holes on the first distribution plate, and the tube bundle is composed of straight tubes. The two ends of the straight tubes are respectively connected with the holes on the two distribution plates. The shape and size of the two ends of the straight tubes are exactly the same as the corresponding holes on the two distribution plates. , the height of the internal member is equal to or less than the height of the low linear velocity reaction zone. The inner member increases the resistance of the gas-solid mixture transport at the axial center of the low linear velocity reaction zone, reduces the resistance of the gas-solid mixture transport at the side wall, and makes the gas-solid mixture relatively uniform in the axial and radial directions, increasing the The gas-solid contact efficiency is improved, and the strength of secondary reactions such as catalytic cracking isomerization and hydrogen transfer in the reaction zone is enhanced; and the shell side can be used to adjust the temperature of the reaction zone, which is also conducive to the control of the reaction type, thereby improving the product nature.

Description

technical field [0001] The present invention belongs to the catalytic conversion equipment of petroleum hydrocarbons in the absence of hydrogen, and more particularly, to a gas-solid contact internal for fluidized catalytic conversion. Background technique [0002] Catalytic cracking is one of the main heavy oil lightening processes in oil refining enterprises. Through this process, large molecular heavy petroleum hydrocarbons can be cracked into small molecular high-priced petroleum products on hot catalysts, such as catalytic gasoline. The main steps are as follows: the hydrocarbon feedstock is in contact with the hot regenerated catalyst and undergoes catalytic cracking reaction at 460-560°C; the mixture of reacted oil gas and ungenerated catalyst enters the settler through the riser reactor; in the settler, the oil gas It is separated from the raw catalyst; the oil and gas enter the subsequent fractionation system; the raw catalyst is in countercurrent contact with the s...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G11/16
Inventor 龚剑洪许友好张久顺龙军
Owner CHINA PETROLEUM & CHEM CORP
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