Toner and double-component developer
A two-component developer and toner technology, applied in the directions of developers, instruments, optics, etc., can solve the problems that it is difficult to control the state of the release agent, and it is difficult to satisfy low-temperature fixability and developability at the same time
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[0090] In the above-mentioned production methods (1) to (6), polymer units having various molecular weights and degrees of crosslinking can be used as the vinyl polymer unit and the polyester unit.
[0091] As the binder resin contained in the toner of the present invention, a mixture of the above-mentioned polyester resin and hybrid resin can be used.
[0092]As the binder resin contained in the toner of the present invention, a mixture of the above-mentioned polyester resin and vinyl polymer can be used.
[0093] As the binder resin contained in the toner of the present invention, a mixture of the above-mentioned hybrid resin and vinyl polymer can be used.
[0094] The glass transition temperature of the binder resin contained in the toner of the present invention is preferably 40 to 90°C, more preferably 45 to 85°C. In addition, the acid value of the binder resin is preferably 1 to 40 mgKOH / g.
[0095] In the toner of the present invention, a known charge control agent ca...
Embodiment
[0252] The present invention is illustrated by the following specific examples, but the invention is not limited to these examples.
manufacture example
[0254] 2.0 mol of styrene, 0.21 mol of 2-ethylhexyl acrylate, 0.14 mol of fumaric acid, 0.03 mol of dimer of α-methylstyrene and 0.05 mol of dicumyl peroxide are used as vinyl polymer units The material was added to the dropping funnel. Then polyoxypropylene (2.2)-2,2-bis(4-hydroxyphenyl)propane 7.0mol, polyoxyethylene (2.2)-2,2-bis(4-hydroxyphenyl)propane 3.0mol, p-benzene 3.0 mol of dicarboxylic acid, 1.9 mol of trimellitic anhydride, 5.0 mol of fumaric acid, and 0.2 g of dibutyltin oxide were charged into a 4-liter glass four-hole flask as materials for the polyester unit. A thermometer, a stirring bar, a condenser, and a nitrogen introduction tube were installed on the four-hole flask, and placed in a mantle-type resistance heater. Then, after the gas in the flask was replaced with nitrogen, the temperature was slowly raised while stirring, and the stirring was continued at a temperature of 145° C., and the monomer of the ethylene polymer unit and the polymerization initi...
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