Method for surface modification of super-high molecular-weight polyethylene fiber surface

A polyethylene fiber, ultra-high molecular weight technology, applied in natural fibers, fiber processing, textiles and papermaking, etc., to achieve the effect of remarkable bonding performance, low monomer consumption and low cost

Inactive Publication Date: 2007-08-29
CHINA PETROLEUM & CHEM CORP +1
View PDF2 Cites 14 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] In view of the deficiencies in the prior art, the technical problem to be solved in the present invention is to design a method for surface modification of ultra-high molecular weight polyethylene fibers, which can effectively improve the surface bonding performance of ultra-high molecular weight polyethylene fibers while maintaining UHMWPE The original strength of the fiber has the characteristics of simple process, no pollution, no special requirements for equipment conditions, low cost, and easy industrial application

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Soak the UHMWPE fiber in a ferric chloride solution with a mass concentration of 20% for 60 minutes, then take it out and place it in a vacuum device containing a pyrrole solution with a purity of 99%, and treat it at a temperature of 25°C and a vacuum of 730mmHg. After 0.5 hours, ultra-high molecular weight polyethylene fibers with improved or improved surface bonding properties can be prepared.

Embodiment 2

[0026] Soak the UHMWPE fiber in a ferric chloride solution with a mass concentration of 30% for 30 minutes, then take it out and place it in a vacuum device containing a pyrrole solution with a purity of 99%, and treat it at a temperature of 55°C and a vacuum of 730mmHg. After 0.5 hours, ultra-high molecular weight polyethylene fibers with improved or improved surface bonding properties can be prepared.

Embodiment 3

[0028] Soak the UHMWPE fiber in a ferric chloride solution with a mass concentration of 30% for 30 minutes, then take it out and place it in a vacuum device containing a pyrrole solution with a purity of 99%, and treat it at a temperature of 55°C and a vacuum of 700mmHg. After 0.5 hours, ultra-high molecular weight polyethylene fibers with improved or improved surface bonding properties can be prepared.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention relates to an ultrahigh molecular weight polythene fiber surface modifying method, comprising: 1. placing ultrahigh molecular weight polythene fiber in organic iron sulfonate solution to soak for 15-60 min, where the organic iron sulfonate solution is iron trichloride solution with mass concentration of 18-60%, or one of the iron toluenesulfonate solution, ferric tri(dodecanesulfonate), iron 2-acylamido-2-demthyl-1-propanesulfonate, or iron morphine propanesulfonate solution with mass concentration of 5-40%, and the organic iron sulfonate solvent is normal butyl alchohol or water; 2. placing the soaked polythene fiber in vacuum device with vacuum of 650-730mmHg in the proportion of 100-120 ml of intrinsic conducting polymer monomer per kg of fiber to process at 25-85deg.C for 0.5-8 h, and making it, where the intrinsic condcuting polymer monomer is pyrrole or thiophene with purity not lower than 99%. And the method can effectively surface adhesiveness of ultrahigh molecular weight polythene (UHMWPE) fiber and besides, keep the original strength of UHMWPE and the process is simple.

Description

technical field [0001] The invention relates to a fiber surface modification technology, specifically a method for surface modification of ultra-high molecular weight polyethylene fibers aimed at improving the surface bonding performance of ultra-high molecular weight polyethylene fibers. The international patent classification number is proposed to be Int.C1 D01M 15 / 00 (2006.01). Background technique [0002] Ultra-high molecular weight polyethylene (UHMWPE) fiber, as a new type of high-performance fiber, has excellent properties unmatched by other high-performance fibers, for example, it has high specific strength and specific modulus, and has chemical resistance and weather resistance , high energy absorption, low temperature resistance, electrical insulation, X-ray penetration and certain water resistance, etc., so it is widely used in military, aerospace and navigation engineering, high-performance lightweight composite materials and high-end leisure sports products, et...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): D06M13/256D06M101/02
Inventor 肖长发宋俊安树林贾广霞金欣
Owner CHINA PETROLEUM & CHEM CORP
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap