TaVIn1-xMxSBrF1-yIy:Rez'Ag0.1 optical storage luminescent material and preparation method thereof

A technology of tavin1-xmxsbrf1-yiy and luminescent materials, which is applied in the field of optical storage luminescent materials, can solve problems such as blurred images, unreadable images, and bulky volume, so as to improve the convenience of use, improve luminous performance, and increase the range of flexibility Effect

Inactive Publication Date: 2008-05-28
TIANJIN UNIVERSITY OF TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the excitation wavelength peak of this kind of optical storage luminescent material must be near the wavelength emitted by these lasers, otherwise it will cause blurred images, poor gray scale, and even unreadable images
In addition, the relatively expensive and bulky defects of this type of laser are accompanied by people's higher and higher requirements for ease of use. People hope to replace the yttrium aluminum garnet used in the short-wave band with the existing cheap and compact semiconductor lasers. Neodymium-doped (Nd:YAG) lasers, argon-ion lasers, or helium-neon lasers

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] Take TaVIn 0.9 Al 0.1 SBrF 0.9 I 0.1 :Eu 0.06 , Au 0.1 As an example, according to the stoichiometric ratio, the TaF 5 , In 2 S 3 , V 2 S 3 , Au 2 S 3 , S, NH 4 F, NH4 Br, NH 4 I, Al 2 o 3 , Eu 2 o 3 Mix and add ethanol to fully grind, then heat the raw material at 60°C for drying; adopt solid state reaction, surround the ground raw material with activated carbon powder and burn for 3 hours in a reducing atmosphere at a high temperature of 800°C. Cool to room temperature; grind the sample and sieve it, wash it twice with ethanol, heat the sample at 60°C for drying; mix the dried sample with methyl methacrylate solution of 1 / 2 the mass of the sample, and dry at 120°C for 2 After hours, grind the sample and sieve it, wash it twice with ethanol, heat the sample at 60°C for drying, and then screen-coat it.

Embodiment 2

[0034] Take TaVIn 0.9 Y 0.1 SBr F 0.9 I 0.1 :Pr 0.04 , Au 0.1 As an example, according to the stoichiometric ratio, the TaF 5 , In 2 S 3 , V 2 S 3 , Au 2 S 3 , S, NH 4 F, NH 4 Br, NH 4 I, Y 2 o 3 , Pr 2 o 3 Mix and add ethanol to fully grind, then heat the raw material at 50°C for drying; use solid-state reaction, surround the ground raw material with activated carbon powder and burn for 3 hours in a reducing atmosphere at a high temperature of 800°C. Cool to room temperature; grind the sample and sieve it, wash it twice with ethanol, heat the sample at 60°C for drying; mix the dried sample with methyl methacrylate solution of 1 / 2 the mass of the sample, and dry at 120°C for 2 After hours, grind the sample and sieve it, wash it twice with ethanol, heat the sample at 60°C for drying, and then screen-coat it.

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PUM

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Abstract

The invention belongs to luminous materials for optical storage, in particular relating to a luminous material for optical storage of TaVIn1-xMxSBrF1-yIy: Rez, Au0.1, which is employed to detect diagnostic images of X-ray of medical treatment and is coactivated by rare earth and cadmium ion which are coated on the surface of polymer with industrial nondestructive inspection. The invention also provides a process for preparing the luminous material for optical storage. The novel luminous material for optical storage of the invention is matched with an adjustable broad band of which the wavelength is between 650 nanometers and 1000 nanometers, and the adjustable broad band suits all semiconductor lasers in the wave band, wherein the semiconductor lasers are taken as driving light sources matched with the adjustable broad band, thereby greatly improving utilization convenience of a x-ray image plate which is produced by employing the sample to coat and increasing elastic range of choosing the matching driving light sources. In particular, the luminous property of the invention is further promoted by coating the surface via the polymer.

Description

【Technical field】 [0001] The invention belongs to optical storage luminescent materials, in particular to TaVIn, which can be used to detect medical X-ray diagnostic images and industrial non-destructive flaw detection. 1-x m x SBrF 1-y I y : Re z , Au 0.1 Optical storage luminescent material and its preparation method. 【Background technique】 [0002] At present, BaFx:Re is an excellent light-storage luminescent material, and is widely used in medical X-ray diagnostic imaging and industrial non-destructive testing image detection. At present, Japanese Patent Application Laid-Open Specification 2001-011439 discloses doping monovalent metal ions in barium fluoride halide europium (BaFX:Eu, X is a halogen or a combination of halogens); Europium (BaFX: Eu, x is a halogen or a combination of halogens) is doped with divalent metal ions; Japanese Patent 2001-144128 discloses the use of barium europium fluoride halides (BaFx: Eu, X is a halogen or a combination of halogens) c...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K11/85
Inventor 张晓松李岚李江勇张艳芳董冬青奚群
Owner TIANJIN UNIVERSITY OF TECHNOLOGY
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