Method for directly producing foamed glass by using slag tapping boil slag

A technology of liquid slag discharge and foam glass, which is applied in the field of solid waste utilization and preparation of inorganic non-metallic materials, can solve the problems of high product cost, high energy consumption of ball milling, and high energy consumption, so as to reduce energy consumption and cost, and reduce three wastes ”Effects of pollution and reduction of manufacturing costs

Inactive Publication Date: 2008-11-12
XI AN JIAOTONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The main problem of this method is that the product cost is high and the energy consumption is high
The main reason for the high cost of the product is that there are processes such as purchase, transportation, and cleaning of quartz, and the hardness of quartz is high, and the energy consumption of ball milling is high.
If the quartz is re-melted and water-quenched for ball milling, although the energy consumption of ball milling is reduced, the cost of melting will be increased, and the above-mentioned process will be fired and cooled twice, resulting in a further increase in energy consumption
[0004] There have been patents on the use of power plant fly ash to prepare silicate products such as glass-ceramic and rock wool, and a beneficial attempt has been made to the use of fly ash, but these patents belong to the "outside the furnace" of fly ash In terms of utilization, there are problems of high energy consumption and high cost;

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] Example 1: For different coal qualities, add cullet with a particle size of less than 50mm or calcium oxide powder with a particle size of less than 100 mesh to the liquid slag discharge furnace through the feeding device from the feed port at the lower part of the boiler, and control the mass percentage of slag: SiO 2 : 45%, Al 2 o 3 : 30%, Fe 2 o 3 : 15%, CaO+MgO: 10%, by controlling the temperature and melting time in the boiler to ensure that the added materials are completely melted, the space temperature of the slag pool in the lower part of the boiler is controlled at 1350 ° C, after the additives are added, at this temperature Melt for more than 20 minutes, then pass the discharged slag directly through the water quenching pool below the slag outlet of the liquid slag discharge furnace for water quenching to obtain a glass body raw material with a particle size of less than 20mm for preparing foam glass, and then pass the obtained glass body raw material throu...

Embodiment 2

[0019] Example 2: For different coal qualities, add cullet with a particle size of less than 50 mm or calcium oxide powder with a particle size of less than 100 mesh to the liquid slag discharge furnace through the feeding device from the feed port at the lower part of the boiler, and control the mass percentage of slag: SiO 2 : 65%, Al 2 o 3 : 10.15%, Fe 2 o 3 : 4.85%, CaO+MgO: 12.34%, Na 2 O+K 2 O: 7.66%. After controlling the temperature and melting time in the boiler to ensure that the added materials are completely melted, the space temperature of the slag pool in the lower part of the boiler is controlled at 1400°C. After adding the additives, melt at this temperature for more than 20 minutes. Then the discharged molten slag is directly quenched through the water quenching pool below the slag discharge port of the liquid slag discharge furnace to obtain the glass body raw material with a particle size of less than 20 mm for preparing foam glass, and then the obtained...

Embodiment 3

[0020] Example 3: For different coal qualities, add cullet with a particle size of less than 50 mm or calcium oxide powder with a particle size of less than 100 mesh to the liquid slag discharge furnace through the feeding device from the feed port at the lower part of the boiler, and control the mass percentage of slag: SiO 2 : 48.27%, Al 2 o 3 : 5%, Fe 2 o 3 : 10.22%, CaO+MgO: 22.51%, Na 2 O+K 2 O: 14%. After controlling the temperature and melting time in the boiler to ensure that the added materials are completely melted, the space temperature of the slag pool in the lower part of the boiler is controlled at 1450°C. After adding the additives, melt at this temperature for more than 20 minutes. Then the discharged molten slag is directly quenched through the water quenching pool below the slag discharge port of the liquid slag discharge furnace to obtain the glass body raw material with a particle size of less than 20 mm for preparing foam glass, and then the obtained g...

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Abstract

The invention relates to a method for directly producing foam glass by utilizing slag of a slag tapping boiler, comprising the following steps that: aiming at coal quality with different compositions, according to the principle of 'lacking what repair what', through adding chunk glass and calcium oxide in the slag tapping boiler, the chemical compositions of the slag are 45 to 65 percent of SiO2, 5 to 30 percent of Al2O3, 0 to 15 percent of Fe2O3, 10 to 30 percent of CaO+MgO and 0 to 14 percent of Na2O+K2O; the obtained slag meeting the requirement directly undergoes water quench in a water quench tank under the slag tapping boiler, vitreous body materials for preparing the foam glass are obtained; the prior technology for preparing the foam glass is adopted, and the foam glass is obtained finally through milling, moulding, foaming, cooling and annealing the obtained vitreous body materials. The method fully utilizes flyash slag and simultaneously reduces the production cost of the foam glass.

Description

technical field [0001] The invention relates to a method for directly producing fly ash foam glass by using liquid slag discharged from a liquid slag removal furnace, and belongs to the field of solid waste utilization and preparation of inorganic non-metallic materials. Background technique [0002] Foam glass is a kind of porous glass material, which is composed of a large number of uniform bubble structures with a diameter of 0.1-3mm. The bubbles account for 80%-90% of the total volume, and the apparent density is 120-500kg / m 3 . Due to its superior heat insulation, sound absorption, fire prevention, moisture resistance and other properties, it is widely used in construction, petrochemical and other industries. [0003] At present, the raw materials for foam glass production in my country are all waste materials, such as waste glass, tailings, fly ash, volcanic lava, pumice, perlite, etc. There is already a mature method of producing foam glass from fly ash. The "two-s...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C11/00
Inventor 谭厚章赵鹏熊小鹤
Owner XI AN JIAOTONG UNIV
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