MgO-SiC-C fire resistant pouring material based on forsterite and method for preparing same

A refractory castable, forsterite technology, applied in the field of MgO-SiC-C refractory castables, can solve the problems affecting the high temperature strength and erosion resistance of materials, the increase of production costs, the shortage of magnesia resources, etc., to achieve excellent anti-corrosion slag performance, low production cost, and the effect of solving the shortage of resources

Inactive Publication Date: 2009-01-07
WUHAN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The existing production and preparation method of MgO-SiC-C refractories is to use magnesia and industrial SiC as the main raw materials, and use phenolic resin as the binder (ZL 200610019553.7), which is produced by mechanical mixing and then compression molding. The advantage of the method is to replace graphite (C) with industrial SiC to ensure the corrosion resistance and thermal shock resistance of the material. The problem is that magnesia resources are becoming increasingly scarce, and the market prices of magnesia and industrial SiC are getting higher and higher. MgO-SiC -The production cost of C-quality refractories is also increasing; in addition, MgO and SiC are combined by phenolic resin, which is carbonized at high temperature, and the bonding effect is weak, which affects the high-temperature strength and erosion resistance of the material

Method used

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Examples

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Effect test

Embodiment 1

[0012] A forsterite-C based MgO-SiC-C refractory castable and a preparation method thereof. Firstly, the applicant's "MgO-SiC-C material synthesized by forsterite-C and its preparation method" (CN 200810048257.9) patent technology is used to mix 1-4mol of forsterite ore powder and 3-6mol of Mix C powder, add 4-10wt% binder of the above-mentioned mixture, stir or mix and grind for 10-30 minutes, dry after compression molding; After ~8 hours, the synthesized MgO-SiC-C material was obtained. The binding agent in this patented technology is a binding agent or a mixture of more than one of calcium lignosulfonate, sodium lignosulfonate, sulfurous acid pulp waste liquid, industrial dextrin powder, and polyvinyl alcohol.

[0013] Then the synthesized MgO-SiC-C material is processed into 10~5mm, 5~3mm, 3~1mm, 1~0mm four kinds of particles and 0.1~0mm fine powder, according to 10~15wt% of 10~5mm particles, 20~25wt% of 5~3mm particles, 20~25wt% of 3~1mm particles, 10~15wt% of 1~0mm par...

Embodiment 2

[0015] A forsterite-C based MgO-SiC-C refractory castable and a preparation method thereof. Adopted synthetic material and four kinds of granules and fine powder are the same as embodiment 1. According to 10-15wt% of 10-5mm particles, 20-25wt% of 5-3mm particles, 15-20wt% of 3-1mm particles, 10-15wt% of 1-0mm particles and 30-35wt% of 0.1-0mm particles powder, add 2-5wt% sodium tripolyphosphate, and stir evenly to prepare MgO-SiC-C refractory castable.

Embodiment 3

[0017] A MgO-SiC-C refractory castable based on forsterite-C and its preparation method, the synthetic materials and four kinds of particles and fine powders used are the same as those in Example 1. According to 10-15wt% of 10-5mm particles, 20-25wt% of 5-3mm particles, 15-20wt% of 3-1mm particles, 10-15wt% of 1-0mm particles and 30-35wt% of 0.1-0mm particles powder, add 2.5-5.5wt% sodium hexametaphosphate, stir evenly, and make MgO-SiC-C refractory castable.

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PUM

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Abstract

The invention relates to a MgO-SiC-C fireproof casting material based on forsterite-C and a preparation method thereof. In the technical proposal, forsterite and C powder are mixed according to the mol ratio of (1 to 4) to (3 to 6), and a binder of 1 to 10 percent of the mixture by weight is added. After the mixture is beaten, moulded and dried, the mixture is synthesized into MgO-SiC-C material for two to eight hours at the temperature of 1450 to 1700 DEG C under the reducing atmosphere. 10-25 weight percent of 10-5mm granule, 15-25 percent weight of 5-3mm granule, 15-25 weight percent of 3-1mm granule, 10-20 weight percent of 1-0mm granule, 25-35 weight percent of 0.1-0mm fine powder are mixed with 2-8 weight percent of the binder, and are beaten uniformly, thus getting the MgO-SiC-C fireproof casting material. The manufacturing cost of the invention is low; the process is simple; and the fireproof casting material prepared has good performance, and is widely applied.

Description

technical field [0001] The invention belongs to the technical field of MgO-SiC-C refractory castables. In particular, it relates to a forsterite-C based MgO-SiC-C refractory castable and a preparation method thereof. Background technique [0002] MgO-SiC-C composite refractory material has excellent high temperature resistance and thermal stability. It is a new type of furnace lining material for non-ferrous metal and iron and steel smelting equipment, especially suitable for the production of clean steel ladles such as low carbon steel and ultra-low carbon steel. Lining and refining furnace lining. Replacing MgO-C material with MgO-SiC-C composite refractory material can overcome the influence of C increase on molten steel due to furnace lining material, which is beneficial to the quality of steel and has a good use effect. [0003] The existing production and preparation method of MgO-SiC-C refractories is to use magnesia and industrial SiC as the main raw materials, and...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/66
Inventor 祝洪喜邓承继
Owner WUHAN UNIV OF SCI & TECH
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