Production process of potassium dihydrogen phosphate

A technology of potassium dihydrogen phosphate and its production method, which is applied in chemical instruments and methods, phosphorus compounds, inorganic chemistry, etc., can solve the problems of high energy consumption, achieve the effects of saving resources, reducing production costs, and improving the production environment

Inactive Publication Date: 2009-02-04
何锡容
View PDF0 Cites 7 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is in order to overcome the deficiency of existing production technology, provides a kind of method that absorbs phosphorus pentoxide to produce potassium dihydrogen phosphate with potassium hydroxide solution and / or the mother liquor of producing potassium dihydrogen phosphate, utilizes yellow phosphorus to burn , Phosphorus pentoxide and potassium hydroxide participate in the chemical reaction to release heat to evaporate potassium hydroxide solution or produce water in the mother liquor of potassium dihydrogen phosphate, and use potassium hydroxide solution or produce water and pentoxide in the mother liquor of potassium dihydrogen phosphate Diphosphorus and potassium hydroxide react to produce potassium dihydrogen phosphate, which solves the problems of evaporating a large amount of water and high energy consumption in the existing production process of potassium dihydrogen phosphate, reduces production costs, saves resources, and reduces pollution

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Production process of potassium dihydrogen phosphate

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Add 1500kg of potassium hydroxide solution (KOH: 30%) in the circulation tank, and send it into the hydration tower with a circulation pump to spray and absorb the phosphorus pentoxide gas generated by the combustion of yellow phosphorus. The flow of yellow phosphorus is controlled at 150kg per hour. The medium vacuum degree is controlled at 66.64×10 3 pa, adjust the flow of cooling water, the temperature in the hydration tower is controlled at 85°C, after 3 hours of circulating absorption, the density of the mixture of phosphoric acid and potassium dihydrogen phosphate in the circulating tank reaches 1.62×10 3 kg / m 3 , send this mixture into reaction crystallizer with circulation pump again, add potassium hydroxide solution 1220kg (KOH: 30%) again, and control adding speed, make temperature keep on 80 ℃, record density 1.45×10 3 kg / m 3 , PH value 4.5, after cooling, crystallization, centrifugal separation, the mother liquor returns to the circulation tank to be used ...

Embodiment 2

[0027] The mother liquor centrifugally separated in the embodiment one is returned to the circulation tank, sent into the hydration tower with a circulation pump to spray and absorb the phosphorus pentoxide gas generated by the combustion of yellow phosphorus, the flow of yellow phosphorus is controlled at 120kg per hour, and the vacuum degree in the hydration tower controlled at 66.64×10 3 pa, adjust the flow of cooling water, the temperature in the hydration tower is controlled at 95°C, after 2.0 hours of circulating absorption, the density of the mixture of phosphoric acid and potassium dihydrogen phosphate in the circulating tank reaches 1.68×10 3 kg / m 3 , send this mixture into reaction crystallizer with circulation pump again, add potassium hydroxide solution 1420kg (KOH: 30%) again, and control adding speed, make temperature keep on 85 ℃, record density 1.48×10 3 kg / m 3 , PH value 4.6, after cooling, crystallization, centrifugation, the mother liquor returns to the ci...

Embodiment 3

[0031] The centrifuged mother liquor in Example 2 is returned to the circulation tank, and then 900 kg of potassium hydroxide solution (KOH: 30%) is added, and the phosphorus pentoxide gas generated by spraying and absorbing the yellow phosphorus combustion in the hydration tower is sent to the yellow phosphorus with a circulation pump. The flow rate is controlled at 150kg per hour, and the vacuum degree in the hydration tower is controlled at 84.0×10 3 pa, adjust the flow of cooling water, the temperature in the hydration tower is controlled at 90°C, after 2.5 hours of circulating absorption, the density of the mixture of phosphoric acid and potassium dihydrogen phosphate in the circulating tank reaches 1.66×10 3 kg / m 3 , send this mixture into reaction crystallizer with circulation pump again, add potassium hydroxide solution 1330kg (KOH: 30%) again, and control adding speed, make temperature keep on 80 ℃, record density 1.48 * 10 3 kg / m 3 , PH value 4.6, after cooling and...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
Densityaaaaaaaaaa
Densityaaaaaaaaaa
Login to view more

Abstract

The invention discloses a production method for potassium dihydrogen phosphate, which essentially comprises: A. yellow phosphorus and oxygen combust in a combustion chamber; B. potassium hydroxide solution and / or the mother liquor for producing potassium dihydrogen phosphate absorb phosphorous pentoxide in a hydration tower under negative pressure, compress and generate a mixture of phosphoric acid and potassium dihydrogen phosphate; C. the mixture is sent to a reaction crystallizer, potassium hydroxide solution is added to the reaction crystallizer to adjust the pH value; the mixture is cooled and crystallized to separate potassium dihydrogen phosphate; the separated mother liquor is returned to the step B to be as the absorbent of the phosphorus pentoxide. The method has the essential advantages of solving the problem of large amounts of energy consumption in the process of compressing potassium hydroxide solution and producing potassium dihydrogen phosphate mother liquor of the existing production method for potassium dihydrogen phosphate, greatly reducing production cost by 600RMB per ton, saving resources and improving production environment.

Description

Technical field: [0001] The invention relates to a production method of potassium dihydrogen phosphate, in particular to a method for producing potassium dihydrogen phosphate by absorbing phosphorus pentoxide with potassium hydroxide solution and / or mother liquor for producing potassium dihydrogen phosphate. Background technique: [0002] At present, the production method of potassium dihydrogen phosphate is to adopt the neutralization method of traditional potassium hydroxide and thermal phosphoric acid. Although the method has simple process, short production cycle, high product quality and low investment; but because the potassium raw material used is The unconcentrated 30% potassium hydroxide in the potash factory or the concentrated 48% and 50% potassium hydroxide after secondary processing in the potash factory need to evaporate a large amount of water during production, resulting in high energy consumption, heavy pollution and high cost. Other methods such as: extract...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C01B25/30
Inventor 何锡容
Owner 何锡容
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products