Water-scraped without set-off intaglio ink
A gravure printing ink and smearing technology, applied in ink, printing, printing devices, etc., can solve problems such as dark color, poor ink stability, and poor metal texture of printed products
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Embodiment A1
[0055] 10.1 parts of tower oil fatty acid, 6.8 parts of linoleic acid, 7.8 parts of glycerol, 3.4 parts of pentaerythritol, 5.7 parts of phthalic anhydride and an appropriate amount of xylene were heated to 200°C under the protection of nitrogen, and kept at a temperature of 200°C. In esterification, the acid value of the system is measured during the reaction, and when the acid value reaches 4, the temperature is lowered to obtain o-phenylalkyd resin, and the oil degree of the resin is 55%. Get a total of 32 parts of above-mentioned resins, add 45 parts of dodecane solvents, 10 parts of dipropylene glycol dimethyl ether solvents are warming up to about 80 ℃, drip 7 parts of toluene diisocyanate (TDI) and be incubated for 2 hours to a viscoelastic ratio of 4, Add 0.05 part of dibutyltin dilaurate and 0.5 part of methanol, and after holding for 1 hour, adjust the product with about 4-5 parts of solvent to a viscosity of 12 Pa.S / 40°C and a viscoelasticity ratio of 6. That is, ve...
Embodiment A2-A11
[0057] The preparation method is the same as that in Example 1, and the reaction materials and dosage ratios are shown in Table 1.
[0058] Table 1
[0059] Numbering A2 A3 A4 A5 A6 A7 A8 A9 A10 A11 Phthalic anhydride 10 5 7 15 8 isophthalic acid 12 5 9 maleic anhydride 14 5 Pentaerythritol 12. 7 4 8 9 5 4 glycerin 9 2 5 17 10 5 Trimethylolpropane 10 5 3 14 11 Diethylene glycol 15 20 linoleic acid 15 10 15 28 soy oleic acid 10 20 16 10 25 23 dehydrated ricinoleic acid 5 15 13 6 tower oil fatty acid 8 7 eleostearic acid 15 5 TDI 8 11 9 3 7 HDI 7 5 12 IPDI 7 12 13 Tridecane 49.72 44.64 Dodecane 30.9 30 25 40 22....
Embodiment B1
[0063]Add 30 parts of tung oil, 25 parts of sesame oil, 10 parts of glycerol, and 4 parts of pentaerythritol to the reaction kettle, add 0.05 part of catalyst lithium hydroxide when the temperature reaches 160 ° C, and under the protection of nitrogen, transesterification reaction occurs at 240 ° C, and the detection After the alcoholysis is qualified (the reaction product: 95% ethanol = 1:5, the solution is clear and transparent), 25 parts of isophthalic acid, 0.02 part of catalyst zinc oxide and an appropriate amount of methyl isobutyl ketone medium solvent are added, and the ester is kept at 230 ° C. The reaction was stopped when the acid value reached 15, and the viscosity was adjusted to 6.2 Pa.S / 40°C with a dodecane solvent (about 6 parts) to obtain iso-benzyl alkyd resin B1 with an oil degree of 62%.
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