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Modified starch slurry used for heat-sensitive chaine low temperature starching and preparation method thereof

A modified starch, heat-sensitive technology, applied in textiles and papermaking, fiber treatment, plant fiber, etc., can solve the problems of decreased adhesion performance, temperature sensitivity of slurry, poor flow, etc., to achieve good fluidity and thermal stability, resistance The effect of strong gel and high adhesive performance

Inactive Publication Date: 2009-02-18
ANHUI UNIVERSITY OF TECHNOLOGY AND SCIENCE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] Modified starch sizing, such as oxidized starch, phosphate starch and acetate starch, is currently used on cotton sizing machines for sizing heat-insensitive warp yarns (such as pure cotton warp yarns, synthetic fiber warp yarns, cotton / synthetic fiber blended warp yarns, etc.) , urethane starch, carboxymethyl starch and compound modified starch, etc., although the properties of the size film, the water dispersion properties of the size, the adhesion to the fiber, the viscosity stability, etc. have been significantly improved, and can be better applied to the warp yarn In cotton-type high-temperature sizing, there are still problems such as the sensitivity of the size to temperature. When the temperature is lowered, there will be problems such as poor flow, poor viscosity stability of the size, and a sharp drop in adhesion performance. Therefore, they must be used at a higher temperature. It is used at high temperature (usually above 95°C), and it cannot be used in the sizing of temperature-sensitive warp yarns.

Method used

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  • Modified starch slurry used for heat-sensitive chaine low temperature starching and preparation method thereof
  • Modified starch slurry used for heat-sensitive chaine low temperature starching and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] The raw corn starch was subjected to acidolysis and viscosity reduction treatment. The raw corn starch is mixed with water to form a starch suspension with a concentration of 40%, heated to 50° C. under stirring, and dilute hydrochloric acid is added and stirred to react to the required starch viscosity. After the reaction, neutralize to pH 7 with dilute NaOH solution, wash, filter and dry to obtain acid-thinned starch.

[0020] Make starch suspension with the starch and water after acidolysis and viscosity reduction in the ratio of 1:1.5, adjust the pH of the system to 10 with NaOH solution with a concentration of 3%, and then add dropwise at 24°C and pH 9-10 For vinyl acetate with 5% starch mass, the dropping speed is controlled within 0.5 h, and the reaction is continued for 1 h after the dropping is completed, and then adjusted to pH 7 with dilute hydrochloric acid. Acetate starch is obtained after suction filtration, washing, drying and crushing.

[0021] Dissolv...

Embodiment 2

[0024] The acetate starch obtained in Example 1 was made into a starch suspension with water at a ratio of 1:1.5, and 8% urea and 2% ammonium chloride were added to the starch mass, stirred at room temperature for 1 hour and then filtered, then in Pre-dry at 50°C until the water content is 10%, then react at 110°C for 2 hours, wash the product thoroughly, filter, and dry to obtain acetate-carbamate modified starch slurry.

[0025] The degree of substitution of the acetate group in the product is DS a =0.039, the degree of substitution of the carbamate group is DS n = 0.032. See Table 1, Table 2 and Table 3 for the viscosity and stability of hot paste, the adhesion performance to viscose and wool fiber, and the sizing performance to wool warp yarn.

Embodiment 3

[0027] Mix the acetic acid-modified starch obtained in Example 1 with water at a ratio of 1:1.5 to form a starch suspension, add 5% sodium dihydrogen phosphate, 5% disodium hydrogen phosphate and 8% urea to the starch quality, and stir at room temperature Suction filtration after 1h, pre-dry the starch filter cake at 50°C until the water content is 10%, grind it and react it at 150°C for 2h, then wash the product fully, filter, and dry to obtain acetate-phosphorylation - Urethanized multiple esterified modified starch size.

[0028] The degree of substitution of the acetate atom group in the product is DSa =0.043, the substitution degree of phosphate ester atomic group is DS p =0.044, the degree of substitution of the carbamate group is DS n = 0.034. See Table 1 and Table 2 for the viscosity and stability of the hot paste, and the adhesion properties to viscose and wool fibers, respectively.

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Abstract

The invention discloses modified starch slurry used for sizing heat-sensitive chaine at low temperature and a preparation method thereof. The modified starch slurry is modified starch slurry processed with multiple esterification. In the multiple esterification of the starch, esterification through acetic acid is indispensable, but not enough, and esterification through phosphoric acid or esterification through carbamic acid is necessary to remodify the starch which is esterified by acetic acid. With the technical proposal, even when sizing under 60-80 DEG C, the slurry has good fluidity, good thermal stability and strong anti-gel property, and the product has strong adhesiveness to wool, viscoce and dyed yarn fiber and can meet the requirement on sizing heat-sensitive chaine like wool, viscoce and dyed yarn fiber at low temperature on a cotton sizing machine. The sized yarn can be woven through a common shuttle loom and meet the weaving requirement of a high speed weaving machine.

Description

technical field [0001] The invention belongs to the modified starch size used in textile warp yarn sizing and its preparation method, in particular to the modified starch size suitable for low-temperature sizing of wool, viscose, yarn-dyed yarn and other heat-sensitive warp yarns on a cotton sizing machine and its preparation method. Background technique [0002] Warp yarn sizing is a key process in the textile production process. Its purpose is to improve the wear resistance of warp yarns, reduce warp yarn hairiness, increase warp yarn strength, and maintain warp yarn elasticity and elongation at break, so as to reduce the weaving broken end rate and improve production. Efficiency, the purpose of improving product quality. [0003] Wool, viscose and yarn dyed warp yarns all fall into the category of heat sensitive yarns. Wool fiber will seriously damage the mechanical properties of warp yarn under high temperature and high humidity, so wool yarn can only be sized at a low...

Claims

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Application Information

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IPC IPC(8): D06M15/11D06M101/12D06M101/06
Inventor 祝志峰刘志军许德生李长龙
Owner ANHUI UNIVERSITY OF TECHNOLOGY AND SCIENCE
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