Suspension bed residual oil hydrogenation-catalytic cracking combined technological process

A catalytic cracking and suspended bed technology, which is used in hydrotreating process, petroleum industry, hydrocarbon oil treatment, etc., can solve the problems of difficult long-term stable operation, easy coking, weak hydrogenation function, etc., to ensure long-term stable operation. , the effect of increasing the amount of distillation and reducing the coking rate

Active Publication Date: 2009-05-20
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Residue suspension bed hydrogenation technology uses solid powder catalyst or homogeneous catalyst, but due to high reaction temperature and high conversion rate (generally greater than 90%), the reaction process is prone to coking, and it is difficult to operate stably for a long period of time. At the same time, the hydrogenation function is relatively weak , poor product quality
At present, there is no commercial device for the suspension bed hydrogenation technology, and the main reason limiting its large-scale industrial application is that it cannot operate stably

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] This embodiment adopts the suspending bed residual oil hydrogenation-catalytic cracking combined process of the present invention, mixed with 18wt% mixed raw material (residual oil mixed with 18wt% clarified oil) to carry out the suspended bed hydrogenation treatment, raw material The properties are shown in Table 1. Add 80 μg / g of water-soluble catalyst (in terms of metal content, the composition is according to CN95118354.0 Example 3) mixed raw materials and hydrogen enter the suspension bed hydrogenation reactor for reaction, the reaction product is fractionated, and the obtained vacuum residue is recycled to Suspension bed reactor, the obtained vacuum distillate oil (final boiling point is 520°C) is subjected to catalytic cracking reaction, the oil slurry obtained by catalytic cracking is separated from solid and liquid to obtain clarified oil, and clarified oil and residual oil raw materials enter the suspended bed residue together Oil hydrogenation reactor.

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Embodiment 2~3

[0033] According to the process and method described in Example 1, the final boiling point of the vacuum distillate in Example 2 is 560° C., and the final boiling point of the vacuum distillate in Example 3 is 540° C. The suspension-bed hydrogenation catalyst uses the oil-soluble catalyst described in Example 1 of CN00110711.9, and the amount of catalyst used in the feed is 300 μg / g in terms of metal. Example 2 The catalytic cracking heavy cycle oil is mixed with clarified oil and residual oil raw materials, and then enters the suspension bed hydrogenation unit. Example 3 Mix 50% of catalytic cracking heavy cycle oil with clarified oil and residual oil raw materials, and enter the suspension bed hydrogenation unit. The specific conditions and results are shown in Table 3.

[0034] Table 2 Reaction conditions and results of Examples 2 to 3

[0035] Example Example 2 Example 3 Suspension bed hydrogenation process conditions and results temperature, ℃ ...

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Abstract

The invention discloses a combination process of hydrogenation-catalytic cracking used for suspension bed residual oil. The method comprises the steps as follows: residual oil and catalytic cracking decanted oil enter a suspension bed hydrogenation reaction device and carry out hydrogenation reaction with the presence of hydrogen and a catalyst; the vacuum distillate oil gained during the hydrogenation reaction enters a catalytic cracking device, the vacuum residual oil is circulated back to the suspension bed hydrogenation device, and the catalytic cracking decanted oil and heavy circular oil can wholly or partly enter the suspension bed hydrogenation device which adopts a relatively moderate operation condition. The method organically combines the suspension bed hydrogenation device with the catalytic cracking device, and therefore not only ensures the stable running of the suspension bed hydrogenation device, but also improves the impurity removal capability of the suspension bed hydrogenation device, improves the raw material quality of the catalytic cracking device, and increases the yield of the light oil products.

Description

technical field [0001] The invention relates to a processing method for lightening residue oil, in particular to a combined processing method for hydrogenation-catalytic cracking of residue oil in a suspended bed. Background technique [0002] With the heavy and inferior quality of crude oil worldwide, and the increasingly stringent environmental protection regulations, residual oil hydrogenation technology has become an important processing method for residual oil. On the one hand, hydrogenation of residual oil can directly obtain some light products, on the other hand, it can provide suitable raw materials for subsequent processes such as catalytic cracking and coking, etc. Through hydrogenation, the content of impurities such as sulfur, nitrogen, and metals in inferior residual oil And the carbon residue value is significantly reduced, so as to obtain high-quality feed for subsequent processing devices. [0003] Residue hydrogenation technology mainly includes fixed bed ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G69/04
Inventor 刘建锟杨涛胡长禄张学萍叶跃元
Owner CHINA PETROLEUM & CHEM CORP
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