Watersoluble coating glue containing multiple coating modified poly-ammonium phosphate and uses on textile finishing

A technology of ammonium polyphosphate and water-based coating, which is applied in the fields of fiber treatment, plant fiber, textiles and papermaking, etc., and can solve problems related to the application of water-based flame-retardant coating glue, coatings that are not resistant to long-term blisters and moisture, There are no problems such as chemical or physical forces, and it achieves the effect of hand feeling, twist resistance and flexural resistance, peel strength maintenance, good application value and economic benefits, soft and plump hand feeling

Active Publication Date: 2009-07-29
HANGZHOU TRANSFAR FINE CHEM CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, many domestic and foreign products on the market can be applied in the field of plastics, rubber and coatings after silane modification or melamine modification, but the application of water-based flame-retardant coatings in textiles does not make the fabric obtain Very good resistance to washing or soaping, and the coating is also resistant to long-term blistering and moisture
[0004] Various methods of coating and modifying APP are mentioned in the existing published patent documents, but they are generally modified by single-layer coating, and the application fields are mainly concentrated in the fields of plastic rubber and coatings, and many of them involve improving their thermal stability. compatibility and even improve the mechanical properties of flame-retardant polymers, but it is still difficult to relate to the specific application of water-based flame-retardant coating adhesives in the textile field
In the textile field, the requirements for water resistance, blistering, and soaping are completely different from those in the fields of plastics, rubber, and coatings. The requirements for soft, dry, smooth and waxy handles are also not mentioned in the fields of plastics, rubber, and coatings. The application performance requirements in the field of textiles are not based on the general outlook of the literature that single-weight modified APP can be applied in the fields of papermaking, wood, textiles and other fields. Without strong chemical or physical forces, APP cannot Get good wash and foam resistance and durable flame retardant properties on fabrics without even a dry hand

Method used

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  • Watersoluble coating glue containing multiple coating modified poly-ammonium phosphate and uses on textile finishing
  • Watersoluble coating glue containing multiple coating modified poly-ammonium phosphate and uses on textile finishing
  • Watersoluble coating glue containing multiple coating modified poly-ammonium phosphate and uses on textile finishing

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] 100 grams of melamine-modified Type II APP (product of Changfeng Chemical Co., Ltd., Shifang City, Sichuan, CF-APP202) was added to 250 grams of 95% ethanol, stirred evenly, and 0.75 grams of γ-glycidyl etheroxypropyl trimethyl was added. Oxysilane (KH-560), then add 0.10 g of ammonia water, heat up from room temperature to 78.5°C under uniform stirring, reflux for 1.5 hours, cool down to 70°C, add dropwise 1.2 g of γ-aminopropyltriethoxysilane (KH -550), heated to 78.5°C, refluxed for 1.5 hours, cooled to 70°C, added 2.0 g of γ-glycidyl etheroxypropyl trimethoxysilane (KH-560), added 0.10 g of ammonia water, refluxed for 2.5 hours, and then cooled to At 70°C, add 2.5 grams of γ-aminopropyltriethoxysilane (KH-550) dropwise, heat to 80°C, reflux for 3.0 hours, cool down, remove the solvent, dry at 110°C for 0.5 hours, and modify by multiple coatings ammonium polyphosphate.

[0028] Figure 1-4 It is the surface morphology of ammonium polyphosphate before and after modi...

Embodiment 2

[0033] 150 grams of melamine-modified Type II APP (product of Changfeng Chemical Co., Ltd., Shifang City, Sichuan, CF-APP202), was added to 300 grams of isopropanol, stirred evenly, and 1.0 grams of γ-glycidyl etheroxypropyl trimethyl Oxysilane (KH-560), 2.0 grams of deionized water, 0.1 grams of ammonia water, heated from room temperature to 82.5°C under uniform stirring, refluxed for 0.5 hours, cooled to 75°C, added dropwise 1.5 grams of γ-aminopropyl triethoxy base silane (KH-550), heated to the boiling point, refluxed for 1.0 hours, cooled to 75°C, added 1.8 grams of γ-glycidyl etheroxypropyl trimethoxysilane (KH-560), added 0.10 grams of ammonia water, refluxed at 82.5°C for 1.5 hour, then lower the temperature to 75°C, add dropwise 2.0 g of γ-aminopropyltriethoxysilane (KH-550), heat to 84°C, reflux for 2.5 hours, lower the temperature, remove the solvent, and dry at 110°C for 0.5 hour to obtain Multiple coating modified ammonium polyphosphate products.

[0034] Take by...

Embodiment 3

[0036] 1 50 grams of melamine-modified Type II APP (product of Changfeng Chemical Co., Ltd., Shifang, Sichuan, CF-APP202), was added to 300 grams of isopropanol, stirred evenly, and 1.0 grams of γ-glycidyl etheroxypropyl was added Trimethoxysilane (KH-560), 0.1 g of ammonia water, 2.0 g of deionized water, heated from room temperature to 82.5 °C under uniform stirring, refluxed for 1 hour, cooled to 75 °C, and added dropwise 1.5 g of γ-aminopropyl triethyl Oxysilane (KH-550), heated to the boiling point of alcohol, refluxed for 1 hour, cooled to 75°C, added 1.8 grams of methacryloxypropyltrimethoxysilane (KH-570)) and 0.15 grams of ammonia water, 82.5 Reflux at ℃ for 1.5 hours, then lower the temperature to 75℃, add 2.0 g of γ-aminopropyltriethoxysilane (KH-550) dropwise, heat to 84℃, reflux for 2 hours, lower the temperature, remove the solvent, and dry at 110℃ for 0.5 Hours, multi-coated modified ammonium polyphosphate products.

[0037] Take by weighing 150 grams of multip...

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Abstract

The invention discloses an aqueous coating adhesive containing multiple coating modified ammonium polyphosphate and applications thereof on fabric finishing. The single modified ammonium polyphosphate can not acquire excellent wash-resisting, immersion-resisting and durable fire retardant performance from the fabric, and can not even obtain dry and comfortable hand feeling. The invention is characterized in that the ammonium polyphosphate, which is modified by melamine, single silane or epoxy resin, is subjected to heating and backflow in an organic alcohol-like solvent, a silane coupling agent capable of being bonded with active groups in the modified ammonium polyphosphate is then added so that the surface of the ammonium polyphosphate experiences multilayer coating and has active hydrogen; the coated ammonium polyphosphate is added with a nonionic surfactant, water, a binder and aqueous closed polyurethane, the aqueous coating adhesive containing the multiple coating modified ammonium polyphosphate is obtained by means of dispersed grinding. The invention is coated on terylene or pure cotton fabrics, thus realizing the cross-linked film forming of the ammonium polyphosphate and the aqueous closed polyurethane and the aqueous binder, and obtaining waterproof and durable environmentally-friendly fire retardant coating fabric.

Description

technical field [0001] The invention relates to the field of textile auxiliaries, in particular to a water-based coating glue containing multiple-coated modified ammonium polyphosphate and its application in fabric finishing. Background technique [0002] Ammonium polyphosphate (APP) is an environmentally friendly, halogen-free, high-efficiency and low-toxicity flame retardant. It has been launched in the flame retardant of plastics and coatings, and has certain applications in wood, paper, rubber, and textiles. However, ammonium polyphosphate has strong hydrophilicity and certain water solubility. It has migration ability in flame-retardant substrates, and it is prone to blooming, salting-out and other phenomena. The hydrolysis of ammonium phosphate (APP) leads to the decrease of flame retardancy. [0003] Currently, various technologies are used to modify or coat ammonium polyphosphate (APP), which is an effective way to reduce its water solubility and hygroscopicity, imp...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06M11/71D06M15/564D06M15/263D06M23/00D06M101/06D06M101/32
Inventor 曾军罗运军王胜鹏罗巨涛傅幼林
Owner HANGZHOU TRANSFAR FINE CHEM CO LTD
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