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Fire-retardant ACS/PVC plastic alloy and manufacturing method thereof

A technology of plastic alloy and manufacturing method, which is applied in the field of polymer material synthesis, can solve the problems of difficult control, high extrusion processing temperature, high production cost, etc., and achieve excellent flame retardancy, good mechanical properties and processing performance, weather resistance and Excellent antistatic performance

Active Publication Date: 2009-12-02
ZHEJIANG OCEANKING DEVELOPMENT CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the Chinese patent CN1908060, Bai Jie proposed a method for manufacturing flame-retardant acrylonitrile-styrene copolymer resin / acrylonitrile-chlorinated polyethylene-styrene copolymer resin plastic alloy. The plastic alloy produced by this method has good comprehensive properties, but due to Using rigid acrylonitrile-styrene copolymer resin (SAN) to modify ACS resin, the extrusion processing temperature is high, it is difficult to control, and the production cost is high

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] Add 40 parts of PVC6840 pellets, 6 parts of decabromodiphenyl ether, 2 parts of antimony trioxide, 0.5 parts of methyl tin mercaptide, 0.6 parts of antioxidant 1076, and 3 parts of ACR401 into a high-speed mixer (generally at a speed of 800 RPM above, the same below), stir and heat up to 60°C, mix at high speed for 10 minutes and cool down, then add 100 parts of general-purpose mid-stroke ACS resin pellets, stir and heat up to 50°C, mix at high speed for 10 minutes, discharge and cool to At room temperature, the above-mentioned mixture is added to the hopper of a twin-screw extruder for extrusion and granulation. The temperature settings for the 11 zones of the extruder are:

[0039] Extruder temperature range 1 2 3 4 5 6 7 8 9 10 11

[0040] Temperature setting 150 152 152 152 154 154 156 156 158 158 160

[0041] The physical properties of the prepared granular flame-retardant ACS / PVC plastic alloy are as follows:

[0042] Tensile strength 36.8MPa

[0043] Izod imp...

Embodiment 2

[0048] Add 40 parts of PVC9026 pellets, 6 parts of decabromodiphenyl ether, 2 parts of antimony trioxide, 0.5 parts of methyl tin mercaptide, 0.6 parts of antioxidant 1076, and 3 parts of ACR401 into a high-speed mixer and stir to raise the temperature to 60 ℃, mix at high speed for 10 minutes and cool down, then add 100 parts of general-purpose mid-stroke ACS resin pellets, stir and heat up to 50°C, mix at high speed for 10 minutes, discharge and cool to room temperature, and add the above-mentioned mixture to the hopper of the twin-screw extruder Perform extrusion granulation. The temperature settings for the 11 zones of the extruder are:

[0049] Extruder temperature range 1 2 3 4 5 6 7 8 9 10 11

[0050] Temperature setting 150 150 150 152 152 152 152 154 154 154 155

[0051] The performance indicators of the white granular flame-retardant ACS / PVC plastic alloy tested are:

[0052] Tensile strength 34.3MPa

[0053] Izod impact strength 9.4kJ / m 2

[0054] Heat distort...

Embodiment 3

[0058] 30 parts of PVC6840 pellets, 7.5 parts of decabromodiphenyl ether, 2.5 parts of antimony trioxide, 0.5 parts of methyl tin mercaptide, 0.6 parts of antioxidant 1076, 3 parts of ACR401, 10 parts of resin type chlorinated polyethylene CPE135A Add it into a high-speed mixer and stir to raise the temperature to 70°C, mix at high speed for 8 minutes and then cool down, then add 100 parts of general-purpose mid-stroke ACS resin pellets, stir and heat up to 50°C, mix at high speed for 10 minutes, discharge and cool to room temperature, The above-mentioned mixture is put into the hopper of a twin-screw extruder for extrusion and granulation. The temperature settings for the 11 zones of the extruder are:

[0059] Extruder temperature range 1 2 3 4 5 6 7 8 9 10 11

[0060] Temperature setting 150 150 150 152 152 153 154 155 155 156 158

[0061] The performance indicators of the white granular flame-retardant ACS / PVC plastic alloy tested are:

[0062] Tensile strength 33.7MPa ...

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Abstract

The invention relates to a fire-retardant ACS / PVC plastic alloy and a manufacturing method thereof. The alloy uses ACS resin and PVC resin as base materials; and compound fire retardant, stabilizer, compatilizer, processing aid, antioxidant and lubricant are added into the base materials in proportion by weight, then the materials are mixed at high speed, and the mixture is blended, extruded and granulated in a double-screw extruder to form the alloy. The prepared fire-retardant ACS / PVC plastic alloy has the advantages of good fire-retardant property, weather resisting property, electrostatic resistance, mechanical property and processing property, can be widely applied in the fields of electron, electrical appliances, communication, instruments, building materials, automobile parts and the like, and is an engineering plastic alloy with good development prospect.

Description

technical field [0001] The invention relates to the technical field of polymer material synthesis, in particular to a flame-retardant ACS / PVC plastic alloy and a manufacturing method thereof. Background technique [0002] ABS resin usually refers to acrylonitrile-polybutadiene-styrene copolymer, which has the characteristics of impact resistance, oil resistance, low temperature resistance, mechanical strength and excellent electrical properties, and is widely used in construction, automobiles, electronics, electrical appliances and Medical equipment and other fields. However, the flame retardant performance of ABS resin is not ideal. Generally, the oxygen index of general-purpose ABS resin is only about 18%, which cannot meet the requirements of flame retardant grade in many applications. [0003] With the development of PVC resin processing technology and the in-depth study of ABS resin modification, it has become a common method to modify ABS resin with PVC resin to impro...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L33/20C08L27/06C08L23/28C08L25/12C08K13/02
Inventor 傅建永沈曙光周文斌徐小武邱琪浩
Owner ZHEJIANG OCEANKING DEVELOPMENT CO LTD
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