The invention discloses a method for preparing a hollow 
antimony-based 
binary alloy composite 
nanofiber material based on electrostatic 
spinning and 
potassium storage application of the hollow 
antimony-based 
binary alloy composite 
nanofiber material. According to the method, PAN and PMMA are taken as precursors, after 
antimony trichloride, CNT, 
nickel acetate, stannous 
chloride and 
cobalt chlorideare dissolved into DMF according to a certain proportion to form a 
spinning solution, the 
spinning solution is transferred into a disposable 
injector, electrostatic spinning is carried out in electrostatic spinning equipment, and a 
nanofiber membrane is obtained. After 
vacuum drying, the 
fiber membrane is put into a tubular furnace, the temperature is increased to 230-300 DEG C at a low temperature increase rate, heat preservation is carried out for a certain time, pre-
carbonization is carried out, then the temperature is increased to 600-800 DEG C at a large temperature increase rate, 
carbonization is carried out, and a sample obtained after 
carbonization is marked as XSb (X = Ni, Sn, Co) / CNT / PC. A carbon framework provides a three-dimensional conductive network, the PMMA is pyrolyzed togenerate a hollow channel, 
alloy particles are embedded in the inner and outer surfaces of 
carbon fibers, by means of the CNT, the overall 
conductivity of the material is improved in the 
carbon fibers, and therefore the material shows excellent comprehensive electrochemical performance when used as a 
potassium ion battery electrode material.