Method for biochemically treating electroplating wastewater
A technology for electroplating wastewater and biochemical treatment, which is used in metallurgical wastewater treatment, chemical instruments and methods, and multi-stage water/sewage treatment. It can solve the problems of further optimization of treatment efficiency and long treatment reaction time. Small amount of sludge, good effect
Inactive Publication Date: 2011-06-01
ZHEJIANG GONGSHANG UNIVERSITY
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Problems solved by technology
In the patent (CN1557999) biochemical treatment of electroplating wastewater, the BM functional bacteria group composed of Desulfovibrio, Desulfococcus, and Desulfurium Cyclobacterium is used to treat electroplating wastewater twice. The disadvantage is that the treatment reaction time is long and the treatment efficiency needs to be further improved. optimization
Method used
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Embodiment 1
[0035] Example 1: Zhejiang Jiafeng Electromechanical Co., Ltd. Electroplating Wastewater Treatment Project
[0036] Waste water volume: 300t / d
[0037] Raw water index:
[0038] pH
CODCr(mg / L)
Cr 6+ (mg / L)
Ni(mg / L)
Zn(mg / L)
10.7
237
96.0
12.4
22.8
[0039] The comprehensive electroplating wastewater enters the biochemical reaction pool after passing through the regulating tank, and 35L / h of the functional bacteria are added. After the wastewater stays for 1 hour, it enters the complexation tower, adjusts the pH value of the wastewater to 8-9, and stays for 1 hour. The result of the effluent is:
[0040] Pollutant index
Embodiment 2
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The invention provides a method for biochemically treating electroplating wastewater. The method comprises the following steps: after the electroplating wastewater is homogenized and averaged by quantity, adjusting the electroplating wastewater to corresponding acidity according to the concentration of Cr<6+>; biochemically treating the electroplating wastewater by a BM optimized strain; adjusting the pH of the electroplating wastewater to between 8 and 9, and treating in a complex breaking tower for 1 to 2 hours; ensuring that the complex breaking tower flows out after complex heavy metals are converted into ionic state; and ensuring that the electroplating wastewater enters an aeration tank and a coagulating basin for further coagulation and impurity removal; and finally performing mud-water separation. The BM optimized strain is acclimatized and cultured by using BM functional coenobium as a raw material strain, wherein the BM functional coenobium is used as the raw material strain, is supplied with a Postgate's C type culture medium once every three days, is introduced with nitrogen for 15 minutes every day, and is cultured at a constant temperature of 35 DEG C in a biochemical incubator; and the strain is acclimatized and cultured by adding heavy metal solution with certain concentration and adopting a ph1-pH7 gradient type culture medium, so that the BM optimized strain has the capability of treating heavy metal wastewater with pH of 1.
Description
technical field [0001] The invention belongs to the technical field of environmental protection and relates to waste water treatment and resource recycling technologies, in particular to a new process for treating electroplating waste water combined with biochemical method and complexation breaking. Background technique [0002] Electroplating is the process of plating various metals on the surface of metal or other materials by chemical and electrochemical methods. Electroplating technology is widely used in machine manufacturing, light industry, electronics and other industries. The composition of electroplating wastewater is very complex, containing harmful substances such as heavy metal ions, organic compounds and inorganic compounds. At present, domestic electroplating plants emit 4 billion m 3 Waste water did not meet the national discharge standards. Once harmful substances enter the environment, they will definitely cause serious harm to the ecology. [0003] The...
Claims
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IPC IPC(8): C02F9/14C02F1/66C02F3/34C02F103/16
Inventor 孙培德赵开方郭茂新宋英琦
Owner ZHEJIANG GONGSHANG UNIVERSITY
