Method and device for concentrating and reclaiming low-concentration industrial waste acid water
A technology of industrial waste acid and recovery method, which is applied in chemical instruments and methods, water/sewage multi-stage treatment, heating water/sewage treatment, etc., can solve the problems of large lime consumption, secondary pollution, and large energy consumption, and achieve Reduce operating costs, create economic benefits, and achieve high concentration efficiency
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Embodiment 1
[0013] Example 1. See figure 1 :
[0014] A method for concentrating and recovering low-concentration waste acid water, comprising the steps of:
[0015] (1) Pretreatment of waste acid water: first use the aeration method to separate out the difficult-to-remove substances dissolved in the wastewater, and then remove the macromolecular substances in the water through a high-efficiency fiber filter;
[0016] (2) Osmotic distillation: the waste acid water treated in step (1) enters the osmotic distillation membrane module, and on one side of the osmotic distillation membrane module is the waste acid water treated in step (1). The other side is an aqueous solution containing a removal agent. The removal agent is an inorganic salt solution with a relatively low osmotic activity. In this example, magnesium chloride is selected with a concentration of 34%. Carry out osmotic distillation dehydration at 20°C, and after osmotic distillation dehydration and concentration The concentrat...
Embodiment 2
[0022] The basic content is the same as in Example 1, the difference is that the removal agent is magnesium sulfate, the concentration is 25%, and the osmotic distillation dehydration is carried out at 25°C; the concentration of waste hydrochloric acid is increased from 2% to 17% after osmotic distillation dehydration concentration, and the osmotic distillation The modular design of the distillation membrane module system, the number of membrane modules is designed according to the amount of water to be treated, that is, when the processing capacity increases, the processing capacity can be improved by adding membrane modules, the addition of membrane modules is simple, and the equipment occupies less land. Size, flexible installation; while the traditional enrichment equipment occupies a large area, once the equipment is confirmed, the processing capacity is fixed, and the processing capacity can only be increased by adding new equipment, which requires a large investment. The...
Embodiment 3
[0024] The basic content is the same as in Example 1, the difference is that the removal agent is calcium chloride, and the concentration is 32%, and dehydration is carried out at 27° C.; the concentration of waste hydrochloric acid is increased from 5% to 21% after concentration through osmotic distillation dehydration. The modular design of the osmotic distillation membrane module system, the number of membrane modules is designed according to the amount of water to be treated, that is, when the processing capacity increases, the processing capacity can be improved by adding membrane modules, the addition of membrane modules is simple, and the equipment occupies less land. According to The size of the site allows flexible installation; while traditional enrichment equipment occupies a large area, once the equipment is confirmed, the processing capacity is fixed, and the processing capacity can only be increased by adding new equipment, which requires a large investment. The c...
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