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Binding agent suitable for high-order high-density interconnected laminated plates

A high-order, high-density, adhesive technology, applied in the field of electronic information, to achieve high glass transition temperature, good machinability, and excellent heat resistance

Active Publication Date: 2013-08-28
NANYA NEW MATERIAL TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In the past, the glass transition temperature of FR-4 ordinary TG (glass transition temperature) and medium TG products were all below 160°C; the Z-axis CTE value was about 50 / 290, and the PTE was about 3.2%; the heat resistance could only guarantee that T260 was greater than 30 Minutes, T288 greater than 10 minutes, TD (thermal decomposition temperature) greater than 325 ° C

Method used

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  • Binding agent suitable for high-order high-density interconnected laminated plates
  • Binding agent suitable for high-order high-density interconnected laminated plates
  • Binding agent suitable for high-order high-density interconnected laminated plates

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] 1. Proportion of glue mixing formula (by weight):

[0038] Phenol-formaldehyde epoxy resin: phenolic curing agent: dimethylimidazole: silicon micropowder: silane: propylene glycol methyl ether 115:40:0.15:10:0.28:20

[0039] 2. Glue baking: prepreg glue speed 15m / min

[0040] 3. Prepreg control parameters: gel time 120 seconds

[0041] Resin content 45.0%

[0042] Resin fluidity 21.2%

[0043] Volatile matter 0.35%

[0044] 4. Plate typesetting structure: 8 sheets of 7628 prepreg, thickness 1.6mm after lamination

[0045] 5. Platen parameters: Vacuum degree -0.085MPa

[0046] Pressure 250-500psi

[0047] Hot plate temperature 120-220℃

[0048] Curing time 60 minutes

[0049] 6. Substrate performance parameters:

[0050]

[0051]

Embodiment 2

[0053] 1. Proportion of glue mixing formula (by weight):

[0054] Phenol-formaldehyde epoxy resin: phenolic curing agent: dimethylimidazole: silicon micropowder: silane: propylene glycol methyl ether 115:40:0.18:12:0.28:22

[0055] 2. Glue baking: prepreg glue speed 12m / min

[0056] 3. Prepreg control parameters: gel time 110 seconds

[0057] Resin content 45.4%

[0058] Resin fluidity 19.8%

[0059] Volatile matter 0.32%

[0060] 4. Plate typesetting structure: 8 sheets of 7628 prepreg, thickness 1.6mm after lamination

[0061] 5. Platen parameters: Vacuum degree -0.090MPa

[0062]Pressure 265-550psi

[0063] Hot plate temperature 150-215℃

[0064] Curing time 55 minutes

[0065] 6. Substrate performance parameters:

[0066]

[0067]

Embodiment 3

[0069] 1. Proportion of glue mixing formula (by weight):

[0070] Phenol-formaldehyde epoxy resin: phenolic curing agent: dimethylimidazole: silicon micropowder: silane: propylene glycol methyl ether 115:40:0.20:9:0.28:18

[0071] 2. Glue baking: prepreg glue speed 17m / min

[0072] 3. Prepreg control parameters: gel time 130 seconds

[0073] Resin content 44.2%

[0074] Resin fluidity 20.5%

[0075] Volatile matter 0.38%

[0076] 4. Plate typesetting structure: 8 sheets of 7628 prepreg, thickness 1.6mm after lamination

[0077] 5. Platen parameters: Vacuum degree -0.090MPa

[0078] Pressure 180-550psi

[0079] Hot plate temperature 135-210℃

[0080] Curing time 65 minutes

[0081] 6. Substrate performance parameters:

[0082]

[0083]

[0084] The above-mentioned epoxy glass cloth-based copper clad board has high glass transition temperature, e...

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Abstract

The invention belongs to the technical field of electronic information, in particular to a binding agent suitable for producing high-order high-density interconnected laminated plates. The binding agent is prepared by phenol formaldehyde epoxy resin, a phenolic curing agent, 2-methylimidazole, micro silica powder, silane and propanediol methyl ether in an appropriate proportion. The binding agentis prepared by the following steps: orderly adding the propanediol methyl ether, the silane and the micro silica powder into a stirring tank to form a mixture; stirring the mixture for a certain time; orderly adding the phenol formaldehyde epoxy resin and the phenolic curing agent into the stirring tank; continuing stirring the mixture for a certain time; weighing the 2-methylimidazole; adding the propanediol methyl ether into the 2-methylimidazole for dissolving the propanediol methyl ether completely; adding the dissolved propanediol methyl ether into the stirring tank; continuing stirring the mixture to a coating prepreg; and finishing mixing glue. An epoxy glass cloth-base copper clad laminate prepared by using the binding agent of the invention has the characteristics of high glass transition temperature, high heat resistance, CAF resistance and size stability, low Z-CT value and water absorptivity, and high machinability, electrification resistance and flame resistance, and the binding agent is fully suitable for producing the high-order high-density interconnected laminated plates.

Description

technical field [0001] The invention belongs to the technical field of electronic information, and specifically relates to an adhesive suitable for producing high-order HDI (high-density interconnection laminates) epoxy glass cloth-based copper-clad boards. Background technique [0002] With the vigorous development of China's electronics industry, electronic products continue to change people's lives and integrate into every corner of various industries. The main substrate of electronic products, copper clad laminates, are widely used in communications, mobile communications, computers, instruments, digital TVs , CNC audio, satellite, radar and other products. [0003] With the demand for light, thin, short, small and digital electronic products, electronic products are developing towards miniaturization, multi-function, high performance and high reliability, which leads to the development of printed circuit boards with fine graphics, high density and high multi-layer With...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J163/04C09J11/06
Inventor 席奎东粟俊华张东包秀银
Owner NANYA NEW MATERIAL TECH CO LTD