White light glass and preparation method thereof

A technology of glass and white light, which is applied in the field of white light glass and its preparation, can solve the problems of uneven color of white light, change of white light color temperature, and difficult control of thickness, etc., and achieve the effects of easy adjustment of color temperature, strong glass forming ability, and high introduction concentration

Inactive Publication Date: 2010-10-13
EAST CHINA UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, since the existing LEDs basically use rare earth as the luminescent center, their luminescence is a linear spectrum, and the luminous wavelength will shift during use, so that the color temperature of the compounded white light will change.
At the same time, since the light-emitting matrix for LEDs is generally phosphor powder, it needs to be deposited on the LED chip as a thin film during the packaging process, and the thickness is not easy to control, resulting in uneven white light color.
Moreover, the packaging process requires the use of epoxy resin, which inevitably produces aging problems

Method used

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  • White light glass and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] Formulation design:

[0029] Phosphate system is used. The components are designed as follows:

[0030] The glass composition (mol%) of table 1 embodiment 1

[0031] P 2 o 5

SrO

SnO 2

MnO

75

25

1.5

2.0

[0032] Batch preparation:

[0033] High-purity (99.9%) ammonium dihydrogen phosphate (NH 4 h 2 PO 4 ), strontium carbonate (SrCO 3 ), manganese carbonate (MnCO 3 ) and tin oxide for the introduction of P 2 o 5 , SrO, MnO and SnO 2 The raw materials, according to the composition shown in Table 1, formula calculation and batch preparation. The batch preparation method is the same as the conventional glass batch preparation method. The ingredients need to be mixed thoroughly.

[0034] Glass melting:

[0035] Put the uniformly mixed batch materials into the corundum crucible, and melt the glass in the electric furnace. The melting atmosphere is air, the melting temperature is 1250°C, and the melting tim...

Embodiment 2-6

[0045] In each of the following examples, the preparation method of the glass is the same as in Example 1, and the results of the fluorescence performance test and color coordinate calculation of the different glass compositions used are listed in Table 3 and Table 4 respectively.

[0046] The glass composition (mol%) of table 3 embodiment 2-6

[0047] serial number

P 2 o 5

SrO

BaO

CaO

SnO 2

MnO

2

70

30

2.0

2.0

3

65

35

1.0

2.0

4

75

25

2.5

2.0

[0048] serial number

P 2 o 5

SrO

BaO

CaO

SnO 2

MnO

5

60

40

1.5

1.0

6

75

25

1.5

4.0

[0049] Fluorescence properties and density test results of the glass of table 4 embodiment 2-6

[0050]

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Abstract

The invention relates to a white light glass and a preparation method thereof, in particular to a white light glass with tin oxide and manganese oxide as light emitting centers and a preparation method thereof. White light illumination plays an important role in daily production and living, but the existing white light illumination has low efficiency, complicated process and difficult miniaturization. Under the condition, the research on the white light glass is taken seriously because the white light glass has the advantages of simple preparation, high luminous efficiency, easy color temperature regulation and the like. Currently, the researches focus on the white light glass doped with rare earth, but rare earth light emission can generate quenching at high concentration, and the lighting peak position can shift along with the use time so as to cause color temperature change. The white light glass with the tin oxide and the manganese oxide as the light emitting centers can make up the shortcomings. The tin oxide and the manganese oxide belong to network intermediates, can be introduced at high concentration, and have higher luminous intensity and conversion efficiency. Simultaneously, the tin oxide and the manganese oxide adopt wide spectrum lighting, and the compounded white light color temperature basically does not change along with time.

Description

technical field [0001] The present invention relates to white light materials and their preparation, especially to SnO 2 White light glass with MnO as luminescent center and preparation method thereof. Background technique [0002] In recent years, with the continuous increase of energy consumption, the energy crisis and environmental pollution have become more and more serious. While searching for new alternative energy sources, certain breakthroughs must be made in energy conservation and emission reduction, which makes it necessary to adjust the existing energy consumption structure so as to achieve the goal of energy conservation and emission reduction. Lighting plays an indispensable role in human production and life, but it also consumes a lot of energy, so the improvement of lighting methods is imminent. For now, incandescent and fluorescent lamps are the main ways of lighting. Since the incandescent lamp emits light by heating the tungsten filament to the incandes...

Claims

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Application Information

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IPC IPC(8): C03C3/16C03C4/12
Inventor 沈策严祁祺杨云霞陈国荣
Owner EAST CHINA UNIV OF SCI & TECH
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