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Method and system for producing gasoline and propylene by integrating heavy oil catalytic cracking with oxygen-containing compound conversion

A heavy oil catalysis and catalytic cracking technology, used in the production of hydrocarbons from oxygen-containing organic compounds, chemical instruments and methods, and bulk chemical production, etc. To solve the problems of small quantity, etc., to achieve the effect of flexible product plan, improving gasoline quality and increasing yield

Inactive Publication Date: 2010-12-29
SHANGHAI INST OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0023] It can be seen from the prior art that methanol or other oxygen-containing compounds and petroleum hydrocarbons enter the catalytic cracking reactor at the same time, which is limited by the catalyst activity and selectivity, and the conversion rate of methanol and the selectivity of olefins are not high enough.
Due to the generally small processing volume and scattered production areas of my country's methanol production facilities, the new methanol-to-hydrocarbon process cannot form economies of scale

Method used

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  • Method and system for producing gasoline and propylene by integrating heavy oil catalytic cracking with oxygen-containing compound conversion
  • Method and system for producing gasoline and propylene by integrating heavy oil catalytic cracking with oxygen-containing compound conversion
  • Method and system for producing gasoline and propylene by integrating heavy oil catalytic cracking with oxygen-containing compound conversion

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Embodiment 1

[0073] image 3 Schematic of the plant for the production of gasoline and propylene with integrated oxygenate conversion for heavy oil catalytic cracking. combine image 3 An embodiment of the integrated process of the heavy oil catalytic cracking and methanol conversion reactor of the present invention for only converting methanol is illustrated.

[0074] The operation of the original heavy oil catalytic cracking reaction regeneration system remains unchanged, as shown in Comparative Example 1.

[0075] The fresh raw material 201 of the oxygen-containing compound in the present invention is crude methanol (commercially available, containing 20% ​​water by weight), and after being heated up to 200°C by the heat exchanger 202, it enters the fixed-bed conversion reactor group 203 and contacts with the special catalyst A, and the methanol The ratio of feed amount to catalytic cracking raw oil is 0.85, and the reactor group is a combination of 2-5 fixed bed reactors, so that whe...

Embodiment 2

[0081] image 3 Schematic of the plant for the production of gasoline and propylene with integrated oxygenate conversion for heavy oil catalytic cracking. combine image 3 It shows that according to the integrated process technology of the present invention, the methanol conversion reactor converts methanol, partially catalytic cracking rich gas and desulfurized dry gas integrated working conditions.

[0082] The operation of the original heavy oil catalytic cracking reaction regeneration system remains unchanged, as shown in Comparative Example 1.

[0083] The fresh raw material 201 for oxygenated compounds in the present invention is crude methanol (commercially available, containing 20% ​​water by weight), and after being heated up to 300°C by the heat exchanger 202, it enters the fixed bed conversion reactor group 203 and contacts with the special catalyst B, and the methanol The ratio of feed amount to catalytic cracking raw oil is 0.5, and the reactor group is a combin...

Embodiment 3

[0090] image 3 Schematic of the plant for the production of gasoline and propylene with integrated oxygenate conversion for heavy oil catalytic cracking. combine image 3 It shows that according to the integrated process technology of the present invention, the methanol conversion reactor converts methanol, partially catalytic cracking rich gas and desulfurized dry gas integrated working conditions.

[0091] The operation of the original heavy oil catalytic cracking reaction regeneration system remains unchanged, as shown in the ratio of Example 1.

[0092]The fresh raw material 201 of the oxygen-containing compound in the present invention is crude methanol (commercially available, containing 20% ​​water by weight), and after being heated to 300°C by the heat exchanger 202, it enters the fixed-bed conversion reactor group 203 and contacts with the special catalyst C, and the methanol The ratio of feed amount to catalytic cracking raw oil is 0.5, and the reactor group is a ...

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Abstract

The invention discloses a method and a system for producing gasoline and propylene by integrating heavy oil catalytic cracking with oxygen-containing compound conversion. The oil-gas separation part of the conventional heavy oil catalytic cracking device is integrated with a fixed bed reactor group for oxygen-containing compound catalytic conversion. The propylene and the gasoline are prepared from part of rich gas components in an oil-gas separator on the top of a catalytic cracking fractionating tower in an oil refinery and dry gas, light olefin components and organic oxygen-containing compounds from other crude oil secondary processing devices serving as raw materials under the action of a special catalyst, so that raw materials for catalytic cracking processing are expanded, the propylene yield of a catalytic cracking process is improved and the yield and quality of the gasoline can be improved. The invention provides a method and a device for increasing the yield of catalytic cracking gasoline and the propylene. The yield of catalytic cracking light olefin and the ratio of olefin products can be flexibly adjusted by only integrating the heavy oil catalytic cracking device with an oxygen-containing compound device; and the method and the system have the advantages of simple process, mature technology, small investment and easy implementation.

Description

technical field [0001] The present invention relates to a method and device for producing gasoline and propylene by catalytic cracking of heavy oil integrated with oxygen-containing compounds, more specifically, integrating oxygen-containing compounds in the product separation part of existing heavy oil catalytic cracking devices and other crude oil secondary processing devices The fixed-bed reactor group of catalytic conversion expands the raw materials of catalytic cracking, improves the yield of propylene and the quality and yield of gasoline, and flexibly adjusts the yield of catalytic cracking light olefins and the method and device of the ratio of olefin products. Background technique [0002] With the rapid development of my country's economy and the improvement of people's quality of life, the demand for plastic products such as high-grade clean gasoline and polyolefins has also increased rapidly. The main raw materials for these two types of products are refined gaso...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G57/00C10G70/00C10G3/00C07C11/06C07C1/20B01J29/40
CPCY02P20/52Y02P30/20Y02P30/40
Inventor 王磊李书珍
Owner SHANGHAI INST OF TECH
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