Spiral coil type diffusion dialysis membrane assembly and preparation method thereof
A technology for diffusion dialysis and membrane modules, applied in the field of spiral separation membrane modules and their preparation, can solve the problems of low mass transfer efficiency and bulky equipment, and achieve the effects of increasing mass transfer coefficient, optimizing performance and increasing average concentration difference
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Embodiment 1
[0024] Example 1: Preparation process of a spiral-wound diffusion dialysis membrane module with an effective membrane area of 0.5 square meters
[0025] figure 1 It is a schematic diagram of the overall structure of the spiral-wound diffusion dialysis membrane module of the present invention; figure 2 A schematic diagram of the center pipe and side flow pipe of the spiral-wound diffusion dialysis membrane module is given. Between the two central tubes 1 and 7, an ion exchange membrane 3 and two flow channel spacers 4 and 5 are sandwiched, so that the two flow channel spacers 4 and 5 are respectively arranged on both sides of the ion exchange membrane 3, and the central tube is maintained 1 and 7 as the boundary, the lengths of the ion exchange membranes at both ends are equal, and the ion exchange membrane 3, the flow channel separation net 4, 5 and the central tube 1 and 7 are bonded and fixed; the ion exchange membrane 3 and the flow channel separation net 4 and 5 close...
Embodiment 2
[0037] Example 2: The preparation process of the spiral-wound diffusion dialysis membrane module with an effective membrane area of 10 square meters
[0038] The rolling method adopted in this example is the same as that in Example 1, adopting the DF120 type dialysis negative membrane with a size of 14000×800mm, the central tube and the side flow tube are all polyvinyl chloride plastic tubes with a semicircular cross-section, and the inner diameter It is Φ25mm, and the end is bonded with polyvinyl chloride pipe fittings to convert it into a circular cross section. The flow channel partition is made of polyethylene material, and the effective membrane area of the spiral-wound diffusion dialysis membrane module is 10m 2 , The external dimension is 1000×Φ200mm.
[0039] If the spiral-wound diffusion dialysis membrane module produced in this example is connected in series and parallel, it can be more suitable for the production process of industrial waste acid recovery, and it...
Embodiment 3
[0040] Example 3: Recovery of Industrial Titanium White Waste Acid by Spiral Wound Diffusion Dialysis Membrane Module
[0041] Use as attached Figure 7 The waste acid recovery performance testing device of the spiral-wound diffusion dialysis membrane module shown in , uses the spiral-wound diffusion dialysis membrane module 18 in Example 1 to carry out the waste acid recovery process test, simulates industrial titanium dioxide waste acid solution, and prepares H 2 SO 4 / FeSO 4 Feed liquid samples, the concentrations are shown in Table 1:
[0042] Table 1 FeSO 4 / H 2 SO 4 Concentration of Feed Liquid Sample
[0043]
[0044] Inject waste acid and tap water of equal volume into waste acid head tank 17 and water head tank 16 respectively, adjust the flow rate of acid and water, maintain the flow ratio of waste acid and tap water to be about 0.9-1.2, keep the liquid level, and after being stabilized, Determination of sulfuric acid and ferrous sulfate concentration in resi...
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