The invention discloses a device and method for non-distillation-free and non-chromogenic detection of trace amounts of easily-released cyanide and total cyanide in an aqueous solution. The device includes a peristaltic pump, an alkali solution pump tube, an acid solution pump tube, an aqueous solution pump tube, a washing device, and a detection device. The method includes filtering the sample solution, mixing it with an acidic solution, mixing it fully in the mixing tube, and transporting it to the photolysis device for photolysis, so that the different forms of cyanide are converted into simple hydrogen cyanide, and the sulfide is converted into hydrogen sulfide. The alkali chamber of the membrane diffusion separator flows through the low-pressure enrichment column, and the cyanide retained in the low-pressure enrichment column is washed by the eluent in the injection pump, enters the ampere pool, and is detected by DC amperometry. The operating conditions of the present invention are mild , high selectivity, long service life of hydrophobic membrane, safety and environmental protection, high recovery rate and no human error, it can measure easily released cyanide or total cyanide in wastewater within 10 minutes.