The invention provides a monomolecular difunctional modifier and a preparation method thereof, and a modified inorganic layered material, a high-barrier water-based
coating composition and a high-barrier film applying the same. The modified inorganic layered material has the length-
diameter ratio of more than or equal to 200, the
turbidity of 1wt% water dispersion liquid of less than or equal to 150NTU and no
sedimentation after standing for more than or equal to 120 days, and the comprehensive performance of the modified inorganic layered material is obviously superior to that of a traditional step-by-step modified product; the modified inorganic layered material can construct an efficient and compact'maze 'barrier structure in a
coating under the low addition amount of 1-5wt%, so that the high-barrier film simultaneously has excellent
gas barrier property, high light
transmittance and low
haze, the
water vapor transmission rate (WVTR) of the high-barrier film is less than or equal to 0.66 g / (m.day), the
oxygen transmission rate (OTR) of the high-barrier film is less than or equal to 0.51 cc / (m.day), the light
transmittance of the high-barrier film is greater than or equal to 90.1%, and the
haze of the high-barrier film is less than or equal to 3.4%.