Calcium remover for aluminum-silicon alloy and preparation method thereof

A technology of decalcifying agent and silicon alloy, which is applied in the field of metal materials, can solve the problems of environmental pollution, large amount of addition, reduction, etc., and achieve the effects of simple preparation process, promotion of precipitation, and good process stability

Inactive Publication Date: 2011-04-13
SHANDONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, a large amount of chlorine gas is released during the chlorination process, causing serious environmental pollution.
There is a literature (Internal Combustion Engine Parts, 2005; 5:24) that use

Method used

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  • Calcium remover for aluminum-silicon alloy and preparation method thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] (1) Press AlF first 3 60%, Ni-Si-B master alloy 35%, carbon powder 5% mass ratio to weigh raw materials;

[0019] (2) Ni-Si-B master alloy is subjected to rapid solidification argon atomization treatment to obtain a granular Ni-Si-B master alloy with a particle size of 0.5 mm;

[0020] (3) AlF 3 Powder, 0.5mm granular Ni-Si-B master alloy and carbon powder are uniformly mixed, and the mixed powder is compacted by a briquetting machine to prepare an aluminum-silicon alloy calcium remover.

[0021] The Ni-Si-B master alloy in the step (1) is composed of nickel, silicon and boron, and the mass percent of each component is: nickel 55, silicon 40, boron 5. An aluminum-silicon alloy calcium remover is obtained according to the above proportioning ratio, and its chemical composition (mass percentage) is: aluminum 19.20, fluorine 40.80, nickel 19.25, silicon 14.00, boron 1.75, and the rest is carbon.

Embodiment 2

[0023] (1) Press AlF first 3 50%, Ni-Si-B master alloy 40%, carbon powder 10% mass ratio to take raw materials;

[0024] (2) Ni-Si-B master alloy is subjected to rapid solidification argon atomization treatment to obtain a granular Ni-Si-B master alloy with a particle size of 0.4mm;

[0025] (3) AlF 3 Powder, 0.4mm granular Ni-Si-B master alloy and carbon powder are uniformly mixed, and the mixed powder is compacted by a briquetting machine to prepare an aluminum-silicon alloy calcium remover.

[0026] The Ni-Si-B master alloy in the step (1) is composed of nickel, silicon and boron, and the mass percentages of each component are: 60 nickel, 30 silicon and 10 boron. Obtain a kind of aluminum-silicon alloy calcium remover of optimal composition according to above-mentioned proportion, and its chemical composition (mass percentage) is: aluminum 16, fluorine 34, nickel 24, silicon 12, boron 4, and the rest is carbon.

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Abstract

The invention belongs to the field of metal material, which is a calcium remover for aluminum-silicon alloy and a preparation method thereof. The calcium remover comprises aluminum and fluorine; the calcium remover is characterized by further comprising nickel, silicon, boron and carbon, the mass percentage of each element is as follows: 11.0-21.0% of the aluminum, 24.0-44.0% of the fluorine, 5.0-30.0% of the nickel, 7.0-35.0% of the silicon, 0.1-5.0% of the boron and 5.0-20.0% of the carbon. The preparation method comprises the following steps: weighing each material according to the mass percentage, 35-65% of AlF3, 20-50% of master alloy Ni-Si-B and 5-20% of carbon powder; performing rapid solidification processing of argon aerosol to the master alloy Ni-Si-B, obtaining granular master alloy Ni-Si-B; uniformly mixing the AlF3 powder, the granular Ni-Si-B powder and the carbon powder, using a briquetting machine to press the powder, and preparing into lumpish calcium remover. The calcium remover for the aluminum-silicon alloy of the invention is highly efficient and environmentally friendly, simple in preparation process, good in process stability, low in cost and the like; when the adding amount is 0.2%, the calcium content in the industrial aluminum-silicon piston alloy is reduced lower than 20 ppm, and the calcium remover for the aluminum-silicon alloy is a novel modification agent similar to eutectic Al-Si alloy.

Description

technical field [0001] The invention belongs to the field of metal materials, in particular to an aluminum-silicon alloy decalcifier and a preparation method thereof. Background technique [0002] Eutectic and hypereutectic aluminum-silicon alloys have the advantages of small thermal expansion coefficient, good volume stability, good wear resistance, high strength, and good process performance, and have become the most widely used piston materials at home and abroad. In order to improve the mechanical properties of aluminum-silicon alloys, it must be modified. At present, the most widely used modification in the industry is the modification of phosphorus. Calcium (Ca), silver-white light metal, soft, density 1.54g / cm 3 , chemically active, almost all metal oxides can be reduced when heated. Calcium is one of the main impurities in industrial aluminum-silicon alloys, which is mainly introduced from the raw material industrial crystalline silicon. Researches at home and abr...

Claims

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Application Information

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IPC IPC(8): C22C1/06C22C21/02
Inventor 武玉英刘相法丁同明
Owner SHANDONG UNIV
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