The invention belongs to the technical field of 
metallurgy of iron and steel, and particularly relates to a 
calcium treatment process of rod wire 
alloy steel. The invention adopts a converter 
smelting-LF (
ladle furnace) refining-RH refining-square billet 
continuous casting production technique. The 
calcium treatment process is implemented in a way that: after the LF refining finishes, feeding an iron 
calcium wire, silico-calcium wire or 
solid calcium wire into 
molten steel at the linear speed of 50-250m / min to control the 
mass percent of calcium aluminum in the 
molten steel at 0.08-0.16%; after the soft blow, carrying out RH treatment; after the RH treatment finishes, carrying out 
calcium carbonate treatment, and feeding the iron calcium wire, silico-calcium wire or 
solid calcium wire into 
molten steel at the linear speed of 50-250m / min to control the 
mass percent of calcium aluminum in the molten steel at 0.04-0.08%; and carrying out soft blow, and 
casting. When the treatment process is used for producing high-quality steel, the inclusion level can not deteriorate, the 
castability of the molten steel is good, the number of 
continuous casting furnaces is increased, the 
calcium content of the molten steel is low but does not influence the 
casting performance, and the treatment process plastifies the inclusions and improves the mechanical properties of steel.