Polyactic acid/polycarbonate alloy material, and preparation method and application thereof

A technology of alloy materials and polycarbonate, which is applied in the field of polymer processing, can solve the problems of limiting the wide application of alloy materials, slow crystallization rate, and increased processing costs, and achieve good dimensional stability, accelerated crystallization rate, and reduced processing costs Effect

Active Publication Date: 2011-04-20
SHANGHAI ZHONGLEI NEW MATERIAL SCI CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0012] However, people's research mostly focuses on improving the compatibility, hydrolysis resistance, and electrical conductivity of polylactic acid / polycarbonate alloys, while ignoring an important issue, that is, although polylactic acid itself has crystallization properties, it does not crystallize. The rate is very slow, which will lead to slow cooling rate of the material during the forming process, long forming cycle, increased processing cost, poor dimensional stability, low thermal deformation temperature, etc., which will greatly limit the wide application of the alloy material

Method used

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  • Polyactic acid/polycarbonate alloy material, and preparation method and application thereof
  • Polyactic acid/polycarbonate alloy material, and preparation method and application thereof

Examples

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Effect test

Embodiment 1-10 and comparative example 3-7

[0052] According to the formula quantity in Table 1 and Table 2, polycarbonate, polylactic acid, liquid crystal polymer, flame retardant, toughening agent, inorganic filler, antioxidant are pre-mixed evenly, and then added to the twin-screw extruder from the main feeding port. Melt blending is carried out in the machine, the temperature of the first zone is 210°C, the temperature of the second zone is 225°C, the temperature of the third zone is 230°C, the temperature of the fourth zone is 240°C, the temperature of the fifth zone is 245°C, and the temperature of the sixth zone is 245°C. The temperature in the seventh zone is 245°C, the temperature in the eighth zone is 245°C, the temperature in the ninth zone is 245°C, the screw speed is 250 rpm, and the residence time is 2 minutes. After extrusion, it is cooled, dried and pelletized to obtain a high-quality High performance, environmentally friendly polylactic acid / polycarbonate alloy. The performance test results of the alloy...

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Abstract

The invention discloses a polyactic acid/polycarbonate alloy material, and a preparation method and application thereof. The polyactic acid/polycarbonate alloy material comprises the following raw materials in part by weight: 10 to 90 parts of polycarbonate, 10 to 90 parts of polyactic acid, 1 to 20 parts of liquid crystal high polymer and 1 to 25 parts of flexibilizer. The polyactic acid/polycarbonate alloy material is prepared by adding the raw materials into a double-screw extruder to be melted and blended. The polyactic acid/polycarbonate alloy material provided by the invention has environmentally-friendly characteristics and excellent physical and mechanical properties, and greatly improves impact strength, bending modulus and heat distortion temperature. The liquid crystal high polymer is added to promote the quick crystallization of the polyactic acid, so that the prepared polyactic acid/polycarbonate alloy can be formed quickly, the forming cycle is reduced from 80 seconds to50 seconds, processing cost is reduced, flowability and fire resistance are improved, and the polyactic acid/polycarbonate alloy material is applicable in the fields of office automation (OA) equipment, communication equipment, automobile parts, domestic appliances and the like.

Description

technical field [0001] The invention relates to a polylactic acid / polycarbonate alloy material, its preparation method and its application. The polylactic acid / polycarbonate alloy material has high performance and is environmentally friendly, and can be used in office automation (OA) equipment, communication equipment, Auto parts, household appliances and other fields belong to the field of polymer processing technology. Background technique [0002] Polycarbonate has the advantages of excellent heat resistance, outstanding impact performance, wide service temperature, good dimensional stability, etc. It has been widely used in various industrial sectors, especially in automobile manufacturing and electronic and electrical industries. However, polycarbonate has the following disadvantages at the same time: high melt viscosity, difficult processing and molding, especially large-scale products, prone to stress cracking, and poor solvent resistance, which limits its application...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/04C08L69/00C08L101/12B29B9/06B29C47/92B29C48/92
CPCB29C48/04B29C48/92B29C2948/92561B29C2948/9259B29C2948/92704B29C2948/92885B29C2948/92895
Inventor 刘春艳南胜松南红霞刘艺
Owner SHANGHAI ZHONGLEI NEW MATERIAL SCI CO LTD
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