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Highly functional polyethylene fiber, woven/knitted fabric comprising same, and glove thereof

A polyethylene fiber and polyethylene technology, applied in the direction of gloves, fabrics, fiber chemical characteristics, etc., can solve the problems of decreased operability, inability to increase the drawing speed, uneven filaments, etc., and achieve high thermal insulation and cutting resistance , Improving process passability and improving productivity

Active Publication Date: 2011-04-27
TOYOBO MC CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, since the elastic modulus of the fiber is too high, not only does it feel hard, but also the highest index value can only be obtained as 3.8 in the cut resistance measurement using the cut resistance performance test (Japanese: クープテスター).
In addition, there is also a problem of reduced operability, that is, since the strength and elastic modulus are increased to improve the cut resistance, the thermal conductivity is also increased, and when meat workers, etc. handle fresh food, their hands will become cold or On the contrary, meat and other food materials are thawed and softened by the heat of hands, so that they cannot be cut at will, etc.
In addition, there are also the following problems: due to the use of high-molecular-weight polyethylene resin, the drawing speed cannot be increased, and thus the productivity cannot be improved; Wire breakage occurs during processing

Method used

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  • Highly functional polyethylene fiber, woven/knitted fabric comprising same, and glove thereof
  • Highly functional polyethylene fiber, woven/knitted fabric comprising same, and glove thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0084] Add 20ppm of 2,5-dimethyl-2,5-di(tert-butyl peroxide base) hexane as a crosslinking agent, using a twin-screw extruder for kneading. This cross-linked polyethylene was extruded at 300° C. from a spinneret having a diameter of 0.8 mm and a number of holes of 10H at a rate of 0.6 g / min per hole discharge. The extruded fibers were passed through a 60 mm-long heat pipe heated to 270° C., quenched with air kept at 20° C., and wound at a speed of 90 m / min to obtain undrawn yarns. The maximum drawing speed (drawing speed at break) of the obtained undrawn yarn at 100° C. and a draw ratio of 15 times was confirmed to be 600 m / min. This undrawn yarn was heated to 100° C., and drawn yarn was obtained at a drawing speed of 300 m / min and a draw ratio of 18 times.

[0085] The obtained fiber was used as a sheath yarn, and a 155 dtex spandex fiber ("Espa (registered trademark)" manufactured by Toyobo Co., Ltd.) was used as a core yarn to obtain a single covered yarn. Using the obta...

Embodiment 2

[0087] The experiment was carried out in the same manner as in Example 1 except that the crosslinking amount described in Table 1 was used to obtain drawn yarns at a draw ratio of 16 times.

Embodiment 3

[0089] The amount of cross-linking agent added was set at 5 ppm, the unstretched yarn was heated to 20°C, moved at 10m / min to perform 2-fold stretching, and then heated to 100°C, and 16-fold stretching was performed. The experiment was carried out in the same manner as in Example 1, except that the stretched yarn was obtained. It should be noted that the maximum drawing speed of the undrawn yarn obtained in Example 3 was 580 m / min at 100° C. and a draw ratio of 15 times.

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Abstract

A highly functional polyethylene fiber which combines high heat-insulating properties with cut resistance and is excellent in productivity and suitability for passing through post-processing; and a coated elastic yarn including the fiber, a woven / knitted fabric, and a glove. The polyethylene fiber comprises polyethylene which is constituted of repeating units of substantially ethylene and which, in the fiber state, has a weight-average molecular weight (Mw) of 50,000-300,000 and a ratio of the weight-average molecular weight to the number-average molecular weight (Mn), Mw / Mn, of 4.0 or lower. The polyethylene fiber has a gel content of 100-10,000 ppm or a zero-shear viscosity in a molten state at 190 C of 8,000-300,000 (Pas).

Description

technical field [0001] The present invention relates to a polyethylene fiber having high productivity, excellent heat retention and abrasion resistance, and excellent process passability during post-processing, a knitted fabric using the fiber, and a cut-resistant glove. Background technique [0002] Currently, natural fiber cotton or organic fiber is generally used as a cut-resistant material, and gloves woven from these fibers are mostly used in fields requiring cut resistance. [0003] Therefore, as a function of imparting cut resistance, woven fabrics, knitted fabrics, etc. made of spun yarns of high-strength fibers such as aramid fibers have been devised. However, it is still unsatisfactory from the standpoint of shedding or durability. In addition, as another method, attempts have been made to improve cut resistance by combining metal fibers with organic fibers or natural fibers, but the incorporation of metal fibers has the problem of hardening the texture and affect...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F6/04A41D19/00A41D31/00D03D15/56
CPCA41D31/0055D01F1/10D01F6/04D10B2501/041D02G3/442A41D19/01505D10B2331/04D02G3/32A41D31/24Y10T428/249921D02G3/36A41D19/00
Inventor 福岛靖宪小田胜二增田实
Owner TOYOBO MC CORP
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